Cooxidation of Aromatic Anils and Oxalic Acid by Chromic Acid in Aqueous Acetic Acid Medium
Corresponding Author(s) : R. SRINIVASAN
srinivasan.ramanujam@yahoo.co.in
Asian Journal of Chemistry,
Vol. 21 No. 9 (2009): Vol 21 Issue 9
Abstract
The kinetic study of the oxidation of aromatic anil and its five derivatives in presence of oxalic acid by chromic acid in aqueous acetic acid medium has been studied. The reaction involves three electron transfer due to conversion of Cr(VI) to Cr(III). The cooxidation reveals the first order kinetics for the oxidant Cr(VI), fractional orders (0.50) and (0.76) for substrate and oxalic acid, respectively. A suitable mechanism and activation parameters have been computed.
Keywords
Oxalic acid
Cooxidation
Chromic acid
Aromatic anils
SRINIVASAN, R., & MOHAMED KASIM, A. (2010). Cooxidation of Aromatic Anils and Oxalic Acid by Chromic Acid in Aqueous Acetic Acid Medium. Asian Journal of Chemistry, 21(9), 6909–6914. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/12163
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