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Vol. 22 No. 10 (2010): Vol 22 Issue 10

A Novel Schiff Base Complex of Cobalt(II) Self-assembled Synthesis and Magnetic Property

Jian-Hong Bi
Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Hong-Liang Wang
Zhejiang Huahai Pharmaceuticals Co. Ltd, Linhai-317024, P.R. China
Wen-Bo Tao
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China
Nai-Liang Hu
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 22 No. 10 (2010): Vol 22 Issue 10

Abstract

A new cobalt(II) complex with the molecular formula [CoL]4(ClO4)8-(H2O)8(CH3OH)0.5 {L= (6Z,15Z)-N1',N2'-bis[amino(pyridin-2-yl)methylene]oxalohydrazide} has been synthesized by self-assembly and characterized by elemental analysis, IR spectra and TG measurement. The study of magnetic properties indicates that there is a weak antiferromagnetic interactions between the Co(II) ions in molecule of the complex.

Keywords

Self-assembly Schiff base Cobalt(II) complex Curie-Weiss law Magnetic property
(1)
Bi, J.-H.; Wang, H.-L.; Tao, W.-B.; Hu, N.-L. A Novel Schiff Base Complex of Cobalt(II) Self-Assembled Synthesis and Magnetic Property. ajc 2010, 22, 8264-8266.
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