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Vol. 22 No. 10 (2010): Vol 22 Issue 10

Synthesis and Magnetic Property of a Nickel(II) Complex: [Ni(C14H14N8O2)]4(ClO4)8(H2O)8(CH3OH)0.5

Jian-Hong Bi
Deparment of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, P.R. China
Wen-Tao Bi
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China.
Hong-Liang Wang
Zhejiang Huahai Pharmaceuticals Co. Ltd., Linhai-317024, P.R. China.
Nai-Liang Hu
School of Chemistry and Chemical Engineering, Anhui University, Hefei-230039, P.R. China.

Corresponding Author(s) : Jian-Hong Bi

bi010101@126.com

Asian Journal of Chemistry, Vol. 22 No. 10 (2010): Vol 22 Issue 10

Abstract

A new self-assembled Schiff base of nickel(II) complex with the molecular formula [NiL]4(ClO4)8(H2O)8(CH3OH)0.5 {L = (6Z,15Z)-N1',N2'-bis(amino(pyridin-2-yl)methylene)- oxalohydrazide} has been synthesized and characterized by IR spectra, elemental analysis and TG measurement. The magnetic properties investigation shows that there is weak antiferromagnetic interactions between the Ni(II) ions of the complex.

Keywords

Schiff base Nickel(II) complex Magnetic property
(1)
Bi, J.-H.; Bi, W.-T.; Wang, H.-L.; Hu, N.-L. Synthesis and Magnetic Property of a Nickel(II) Complex: [Ni(C14H14N8O2)]4(ClO4)8(H2O)8(CH3OH)0.5. ajc 2010, 22, 8258-8260.
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