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Vol. 22 No. 10 (2010): Vol 22 Issue 10

Self-Association Study from Electrochemical Behaviours of {Mo154} and {Mo72Fe30} in Aqueous Solution

Xiangfeng Jia
School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan, Shandong, P.R. China
Shuaiqin Yu
Institute of Ocean Materials and Engineering, Shanghai Maritime University, Shanghai 200135, P.R. China.
Yongshan Ma
School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan, Shandong, P.R. China
Peigang Li
School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan, Shandong, P.R. China
Huixue Ren
School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan, Shandong, P.R. China

Corresponding Author(s) : Xiangfeng Jia

jiaxf@sdjzu.edu.cn

Asian Journal of Chemistry, Vol. 22 No. 10 (2010): Vol 22 Issue 10

Abstract

The electrochemical behaviours of the nanoscale inorganic polyoxomolybdate anions ({Mo154} and {Mo72Fe30}) and their aggregations in aqueous solution are examined by cyclic voltammetry. By comparison, it is found that the cyclic voltammograms of the single macro anions ({Mo154} and {Mo72Fe30}) and those of their aggregations are similar. From the electrochemical point of view, it is concluded that the self-assembly of this kind of macro anions is driven by physical force.

Keywords

Nanoscale polyoxomolybdate Cyclic voltammograms Second organized structure Vesicle supermolecule Inorganic polymer
(1)
Jia, X.; Yu, S.; Ma, Y.; Li, P.; Ren, H. Self-Association Study from Electrochemical Behaviours of {Mo154} and {Mo72Fe30} in Aqueous Solution. ajc 2010, 22, 8033-8040.
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