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Photocatalytic Properties of Micro-Crystalline Polyoxometalate Synthesized Using Microemulsion Method
Corresponding Author(s) : A. Arokia Nepolean Raj
Asian Journal of Chemistry,
Vol. 29 No. 9 (2017): Vol 29 Issue 9
Abstract
In present study, a photocatalytic degradation of rhodamine-B by micro-crystalline polyoxometalates (POM) is investigated. The polyoxometalates catalyst is synthesized using microemulsion method and characterized by FT-IR, XRD and SEM. Photocatalytic degradation experiment is carried out in a setup by UV light irradiation in presence of catalyst and the degradation progress is evaluated using UV-visible spectrophotometer.
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- W. Guo, H. Lv, Z. Chen, K.P. Sullivan, S.M. Lauinger, Y. Chi, J.M. Sumliner, T. Lian and C.L. Hill, J. Mater. Chem. A Mater. Energy Sustain., 4, 5952 (2016); https://doi.org/10.1039/C6TA00011H.
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- D.-L. Long, E. Burkholder and L. Cronin, Chem. Soc. Rev., 36, 105 (2007); https://doi.org/10.1039/B502666K.
- Y. Wang and I.A. Weinstock, Chem. Soc. Rev., 41, 7479 (2012); https://doi.org/10.1039/c2cs35126a.
- M.T. Pope and A. Muller, Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity, Kluwer Academic Publishers: Dordrecht, Netherlands (1994).
- M.T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag, New York (1983).
- R.R. Crichton, Biological Inorganic Chemistry, Elsevier, Amsterdam, vol. 1, p. 271 (2008).
- M. Dahal and G.L. Lawrance, Inorg. React. Mech., 5, 117 (2003).
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- J.H. Schulman, W. Stoeckenius and L.M. Prince, J. Phys. Chem., 63, 1677 (1959); https://doi.org/10.1021/j150580a027.
- D.L. Long and L. Cronin, Chem. Eur. J., 12, 3698 (2006); https://doi.org/10.1002/chem.200501002.
- L.C.W. Baker and T.J.R. Weakley, J. Inorg. Nucl. Chem., 28, 447 (1966); https://doi.org/10.1016/0022-1902(66)80324-X.
- M.A. Lopez Quintela, Curr. Opin. Colloid Interface Sci., 8, 137 (2003); https://doi.org/10.1016/S1359-0294(03)00019-0.
- A.A. Nepolean Raj and T. Jeyabalan, J. Chem. Chem. Sci., 4, 43 (2014).
- S. Lin, Y. Zhen, S.-M. Wang and Y.-M. Dai, J. Mol. Catal. A, 156, 113 (2000); https://doi.org/10.1016/S1381-1169(99)00414-8.
- M.P. Pileni, Nat. Mater., 2, 145 (2003); https://doi.org/10.1038/nmat817.
- L.Y. Feng, Y.H. Wang, Y.J. Qi, C.W. Hu, Y. Xu and E.B.J. Wang, Mol. Str., 645, 231 (2003); https://doi.org/10.1016/S0022-2860(02)00582-3.
- S.-S. Wang and G.-Y. Yang, Chem. Rev., 115, 4895 (2015); https://doi.org/10.1021/cr500390v.
- Y.H. Guo and C.W. Hu, J. Mol. Catal. A, 262, 136 (2007); https://doi.org/10.1016/j.molcata.2006.08.039.
- E. Papaconstantinou, Chem. Soc. Rev., 18, 1 (1989); https://doi.org/10.1039/cs9891800001.
- M. Bonchio, M. Carraro, G. Scorrano, E. Fontananova and E. Drioli, Adv. Synth. Catal., 345, 1119 (2003); https://doi.org/10.1002/adsc.200303076.
- S. Farhadi, M. Afshari, M. Maleki and Z. Babazadeh, Tetrahedron Lett., 46, 8483 (2005); https://doi.org/10.1016/j.tetlet.2005.10.019.
- A. Troupis, A. Hiskia and E. Papaconstantinou, Angew. Chem. Int. Ed., 41, 1911 (2002); https://doi.org/10.1002/1521-3773(20020603)41:11<1911::AIDANIE1911>3.0.CO;2-0.
- C. Chen, J. Zhao, P. Lei, J. Zhao and N. Serpone, Chem. Eur. J., 10, 1956 (2004); https://doi.org/10.1002/chem.200305453.
- A. Hiskia and E. Papaconstantinou, Inorg. Chem., 31, 163 (1992); https://doi.org/10.1021/ic00028a007.
- R. Neumann and M. Levin, J. Am. Chem. Soc., 114, 7278 (1992); https://doi.org/10.1021/ja00044a044.
References
W. Guo, H. Lv, Z. Chen, K.P. Sullivan, S.M. Lauinger, Y. Chi, J.M. Sumliner, T. Lian and C.L. Hill, J. Mater. Chem. A Mater. Energy Sustain., 4, 5952 (2016); https://doi.org/10.1039/C6TA00011H.
A. Dolbecq, E. Dumas, C.R. Mayer and P. Mialane, Chem. Rev., 110, 6009 (2010); https://doi.org/10.1021/cr1000578.
D.-L. Long, E. Burkholder and L. Cronin, Chem. Soc. Rev., 36, 105 (2007); https://doi.org/10.1039/B502666K.
Y. Wang and I.A. Weinstock, Chem. Soc. Rev., 41, 7479 (2012); https://doi.org/10.1039/c2cs35126a.
M.T. Pope and A. Muller, Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity, Kluwer Academic Publishers: Dordrecht, Netherlands (1994).
M.T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag, New York (1983).
R.R. Crichton, Biological Inorganic Chemistry, Elsevier, Amsterdam, vol. 1, p. 271 (2008).
M. Dahal and G.L. Lawrance, Inorg. React. Mech., 5, 117 (2003).
X.H. Zhang, S.Y. Xie, Z.Y. Jiang, L.C. Zhou, Z.X. Xie, R.-B. Huang and L.-S. Zheng, Chem. Commun., 2032 (2002); https://doi.org/10.1039/B205089G.
J.H. Schulman, W. Stoeckenius and L.M. Prince, J. Phys. Chem., 63, 1677 (1959); https://doi.org/10.1021/j150580a027.
D.L. Long and L. Cronin, Chem. Eur. J., 12, 3698 (2006); https://doi.org/10.1002/chem.200501002.
L.C.W. Baker and T.J.R. Weakley, J. Inorg. Nucl. Chem., 28, 447 (1966); https://doi.org/10.1016/0022-1902(66)80324-X.
M.A. Lopez Quintela, Curr. Opin. Colloid Interface Sci., 8, 137 (2003); https://doi.org/10.1016/S1359-0294(03)00019-0.
A.A. Nepolean Raj and T. Jeyabalan, J. Chem. Chem. Sci., 4, 43 (2014).
S. Lin, Y. Zhen, S.-M. Wang and Y.-M. Dai, J. Mol. Catal. A, 156, 113 (2000); https://doi.org/10.1016/S1381-1169(99)00414-8.
M.P. Pileni, Nat. Mater., 2, 145 (2003); https://doi.org/10.1038/nmat817.
L.Y. Feng, Y.H. Wang, Y.J. Qi, C.W. Hu, Y. Xu and E.B.J. Wang, Mol. Str., 645, 231 (2003); https://doi.org/10.1016/S0022-2860(02)00582-3.
S.-S. Wang and G.-Y. Yang, Chem. Rev., 115, 4895 (2015); https://doi.org/10.1021/cr500390v.
Y.H. Guo and C.W. Hu, J. Mol. Catal. A, 262, 136 (2007); https://doi.org/10.1016/j.molcata.2006.08.039.
E. Papaconstantinou, Chem. Soc. Rev., 18, 1 (1989); https://doi.org/10.1039/cs9891800001.
M. Bonchio, M. Carraro, G. Scorrano, E. Fontananova and E. Drioli, Adv. Synth. Catal., 345, 1119 (2003); https://doi.org/10.1002/adsc.200303076.
S. Farhadi, M. Afshari, M. Maleki and Z. Babazadeh, Tetrahedron Lett., 46, 8483 (2005); https://doi.org/10.1016/j.tetlet.2005.10.019.
A. Troupis, A. Hiskia and E. Papaconstantinou, Angew. Chem. Int. Ed., 41, 1911 (2002); https://doi.org/10.1002/1521-3773(20020603)41:11<1911::AIDANIE1911>3.0.CO;2-0.
C. Chen, J. Zhao, P. Lei, J. Zhao and N. Serpone, Chem. Eur. J., 10, 1956 (2004); https://doi.org/10.1002/chem.200305453.
A. Hiskia and E. Papaconstantinou, Inorg. Chem., 31, 163 (1992); https://doi.org/10.1021/ic00028a007.
R. Neumann and M. Levin, J. Am. Chem. Soc., 114, 7278 (1992); https://doi.org/10.1021/ja00044a044.