Electrochemical Synthesis of Silver Nanoparticles in the Presence of Poly(N-vinylpyrrolidone) and the Study of Phase-Transfer
Corresponding Author(s) : Qiuhong Li
Asian Journal of Chemistry,
Vol. 22 No. 8 (2010): Vol 22 Issue 8
Abstract
Poly(N-vinylpyrrolidone)-protected spherical shape silver nano-particles with diameter about 30-100 nm were prepared by electrochemical method using the rotating glassy carbon as working electrode. The result showed that the electrode rotation rate had a great effect on the silver colloids. UV-Vis absorption spectra, X-ray diffraction and scanning electron microscopy (SEM) were employed to characterize the silver nanoparticles. Moreover, based on the decrease of the solubility of poly(N-vinylpyrrolidone) in water with the temperature increase, the obtained silver nanoparticles were transferred from aqueous phase to organic phase successfully by phasetransfer method, which improved the catalytic activity of silver nanoparticles.
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