Synthesis, Structural, Spectroscopic and Electrochemical Properties of Novel S- and S,O-Substituted 1,4-Naphthoquinones
Corresponding Author(s) : Cemil Ibis
Asian Journal of Chemistry,
Vol. 22 No. 8 (2010): Vol 22 Issue 8
Abstract
New S- and S,O-substituted 1,4-naphthoquinone compounds
3, 4 and 5 were synthesized from the reaction of 2,3-dichloro-1,4-naphthoquinone (1) with 2-mercaptobenzylalcohol (2) in ethanol with sodium carbonate for 2 h at room temperature. The structures of novel compounds were characterized by using micro analysis, FT-IR, UV/Vis, 1H NMR, 13C NMR, mass spectra, cyclic voltammetry and fluorescence spectropho-tometer. The crystal structure of 3 was determined by X-ray diffraction method. The compound 3 was crystallized in the triclinic crystal system (space group P-1) with the unit cell parameters a = 7.9433(10) Å, b = 8.1707(11) Å, c =10.5705(11) Å, a = 91.173(6)°, b = 93.564(6)°, g = 106.115(6)°.
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