Vibrational Spectroscopic Studies on the Td-type N,N'- dimethylethylenediamine(II)tetracyanometallate(II) Benzene Clathrates
Corresponding Author(s) : Celal Bayrak
cbayrak@hacettepe.edu.tr
Asian Journal of Chemistry,
Vol. 22 No. 5 (2010): Vol 22 Issue 5
Abstract
FT-IR spectra of Mn(DMEDA)M(CN)4·C6H6 (M = Zn, Cd or Hg; DMEDA = N,N'- dimethylethylenediamine) and FT-IR and FT-Raman spectra of Cd(DMEDA)M(CN)4·C6H6 (M = Cd or Hg) are reported. All the vibrational modes of coordinated DMEDA are characterized. The spectral features suggest that these compounds are similar in structure to the Hofmann-Tdtype clathrates.
Keywords
Benzene
Inclusion compounds
Hofmann-Tdtype clathrates
Infrared spectra
N,N'-Dimethylethyl-enediamine
Raman spectra
(1)
Bayrak, C. Vibrational Spectroscopic Studies on the Td-Type N,N’- dimethylethylenediamine(II)tetracyanometallate(II) Benzene Clathrates. ajc 2010, 22, 3734-3740.
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