Anchored Montmorillonite Diphenyl Phosphino Palladium(II) Chloride Mediated Hydrogenation of Maleic Anhydride and Its Related Geometric Isomers: A Kinetic Study
Corresponding Author(s) : P.K. Saiprakash
hemay2@yahoo.com
Asian Journal of Chemistry,
Vol. 22 No. 4 (2010): Vol 22 Issue 4
Abstract
A kinetic study of hydrogenation of maleic anhydride and few related geometrical isomers has been carried out with anchored montmorillonite diphenyl phosphino palladium(II) chloride as the catalyst in the temperature range of 288-306 K. Reaction kinetics indicated first order dependence on [H2]. A mechanism consistent with the experimental data has been proposed. The activation and thermodynamic parameters have been evaluated.
Keywords
Hydrogenation
Maleic anhydride
Maleic acid
Fumaric acid
Methyl maleate
Methyl fumarate
Ethyl maleate
Ethyl fumarate
Hemasri, Y., Jaya Prakash Rao, Y., Rajanna, K., & Saiprakash, P. (2010). Anchored Montmorillonite Diphenyl Phosphino Palladium(II) Chloride Mediated Hydrogenation of Maleic Anhydride and Its Related Geometric Isomers: A Kinetic Study. Asian Journal of Chemistry, 22(4), 2565–2574. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/11444
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