Electrocatalytic Epoxidation of Olefins Using Iron(III) Tetraphenylporphyrin Chloride

M. Khorasni-Motlagh; M. Noroozifar; A.-N. Torabi

Issue

Vol. 22 No. 2 (2010): Vol 22 Issue 2

Issue Published : November 13, 2009

Electrocatalytic Epoxidation of Olefins Using Iron(III) Tetraphenylporphyrin Chloride

M. Khorasni-Motlagh

Department of Chemistry, University of Sistan & Baluchestan, P.O. Box: 98155-147, Zahedan, Iran

M. Noroozifar

Department of Chemistry, University of Sistan & Baluchestan, P.O. Box: 98155-147, Zahedan, Iran

A.-N. Torabi

Department of Chemistry, University of Sistan & Baluchestan, P.O. Box: 98155-147, Zahedan, Iran

Corresponding Author(s) : M. Khorasni-Motlagh

mkhorasani@chem.usb.ac.ir

Asian Journal of Chemistry, Vol. 22 No. 2 (2010): Vol 22 Issue 2
Article Published : March 30, 2010

Abstract

Electrocatalytic epoxidation of olefins by using iron-porphyrin complex, iron(III) tetraphenylporphyrin chloride, as a mediator in an acetone aqueous Na₂SO₄ two phase system was performed successfully in an one-compartment cylindrical cell under constant potential condition. The epoxidation reactions have been monitored by gas chromatographic analysis. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.

Keywords

Electrocatalytic reaction Epoxidation Olefin Iron-porphyrin

Khorasni-Motlagh, M., Noroozifar, M., & Torabi, A.-N. (2010). Electrocatalytic Epoxidation of Olefins Using Iron(III) Tetraphenylporphyrin Chloride. Asian Journal of Chemistry, 22(2), 1125–1130. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/11237

Issue

Vol. 22 No. 2 (2010): Vol 22 Issue 2

Electrocatalytic Epoxidation of Olefins Using Iron(III) Tetraphenylporphyrin Chloride

Corresponding Author(s) : M. Khorasni-Motlagh

Abstract

Keywords

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