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Vol. 29 No. 8 (2017): Vol 29 Issue 8

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Synchrotron X-Ray Diffraction Study of BaPb1-xSnxO3 Solid Solution

https://doi.org/10.14233/ajchem.2017.20587
A.K. Prodjosantoso
Department of Chemistry, Yogyakarta State University, Yogyakarta, DIY 55281, Indonesia
M. Zaini
Department of Chemistry, Yogyakarta State University, Yogyakarta, DIY 55281, Indonesia

Corresponding Author(s) : A.K. Prodjosantoso

prodjosantoso@uny.ac.id

Asian Journal of Chemistry, Vol. 29 No. 8 (2017): Vol 29 Issue 8

Abstract

The structures of BaPb1-xSnxO3 (x = 0, 0.025, 0.05 and 0.075) have been established from high resolution synchrotron X-ray powder diffraction. These solid solutions are all isostructural and the structures have been refined in the orthorombic space group, Imma. In all cases the BaO octahedral layers are separated by Pb/SnO6 layers. As expected on size arguments, the cell parameters decrease as the amounts of Sn increases due the size effects of the dopant cation.

Keywords

Barium plumbate Synchrotron XRD Rietveld Rietica
Prodjosantoso, A., & Zaini, M. (2017). Synchrotron X-Ray Diffraction Study of BaPb1-xSnxO3 Solid Solution. Asian Journal of Chemistry, 29(8), 1718–1722. https://doi.org/10.14233/ajchem.2017.20587
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