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Vol. 22 No. 2 (2010): Vol 22 Issue 2

Acetalization of Carbonyl Compounds Catalyzed by Bismuth Triflate Under Solvent-Free Conditions

HAMID ALIYAN
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran
RAZIEH FAZAELI
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran
AHMAD REZA MASSAH
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran
AHMAD REZA MOMENI
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran
HAMID JAVAHERIAN NAGHASH
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran
BEHZAD MOEINIFARD
Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza, Isfahan-86145-311, Iran

Corresponding Author(s) : HAMID ALIYAN

aliyan@iaush.ac.ir; hamidaliyan@yahoo.com

Asian Journal of Chemistry, Vol. 22 No. 2 (2010): Vol 22 Issue 2

Abstract

Carbonyl compounds were converted to the corresponding 1,3-dioxolanes and 1,3-dioxanes with ethylene glycol and 1,3-propandiol in the presence of bismuth triflate under solvent-free conditions. In addition, high chemoselective protection of aldehydes in the presence of ketones has been achieved.

Keywords

Acetalization Bismuth triflate 1,3-Dioxolane 1,3-Dioxane Solvent-free
(1)
ALIYAN, H.; FAZAELI, R.; REZA MASSAH, A.; REZA MOMENI, A.; JAVAHERIAN NAGHASH, H.; MOEINIFARD, B. Acetalization of Carbonyl Compounds Catalyzed by Bismuth Triflate Under Solvent-Free Conditions. ajc 2010, 22, 873-876.
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