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Vol. 29 No. 7 (2017): Vol 29 Issue 7

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Mesoporous COK-12 Supported Co3O4 Composites for Adsorption of Methylene Blue from Aqueous Solution

https://doi.org/10.14233/ajchem.2017.20616
Yadagiri Jyothi
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500 007, India; Catalysis Laboratory, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500 007, India
Reshma
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500 007, India
Kondeboina Murali
Catalysis Laboratory, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500 007, India
B. Shankar
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500 007, India
Kamaraju Seetha Ram Rao
Catalysis Laboratory, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500 007, India
Burri David Raju
Catalysis Laboratory, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500 007, India
Puppala Veera Somaiah
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500 007, India

Corresponding Author(s) : Puppala Veera Somaiah

vs_puppala@rediffmail.com; profvspuppala@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 7 (2017): Vol 29 Issue 7

Abstract

A simple batch adsorption experiment has been accomplished for the removal of methylene blue using Co3O4/COK-12 catalysts prepared by impregnation method with varying Co loadings (5-20 wt %). The as prepared catalysts were characterized by X-ray diffraction analysis, Fourier transform-infrared spectroscopy and nitrogen adsorption-desorption techniques to examine the morphology and the meso structure of the obtained composites. The effects of various experimental parameters, such as contact time, adsorbate dose, metal loading were investigated. Among the series 10 wt % Co3O4/COK-12 exhibited maximum adsorption capacity of about 27 mg/g. It was observed that the methylene blue adsorption represents pseudo-second order kinetics model as an appropriate model to represent the present data.

Keywords

Methylene blue Co3O4/COK-12 Mesoporous structure Amount adsorbed Adsorption
Jyothi, Y., Reshma, ., Murali, K., Shankar, B., Ram Rao, K. S., Raju, B. D., & Somaiah, P. V. (2017). Mesoporous COK-12 Supported Co3O4 Composites for Adsorption of Methylene Blue from Aqueous Solution. Asian Journal of Chemistry, 29(7), 1612–1616. https://doi.org/10.14233/ajchem.2017.20616
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