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Flame Atomic Absorption Spectrometric Determination of Trace Quantities of Cadmium from Water Samples
Corresponding Author(s) : Deniz Sahin Tas
Asian Journal of Chemistry,
Vol. 29 No. 7 (2017): Vol 29 Issue 7
Abstract
The influence of some surface-active agents in the medium on determination of ultra-trace quantities of Cd2+ ion by flame atomic absorption spectrometry was investigated. Sodium dodecylsulfate (SDS), cetyltrimethyl ammonium bromide (CTAB) and polyoxyethylene(10) isooctylphenyl ether (TX100) were used as anionic, cationic and non-ionic surface-active agents, respectively. To obtain the optimal concentration of surfactants, the effect of surfactant concentration on the preconcentration of cadmium was investigated by increasing sufactant concentration up to 10 × critical micellar concentration (CMC). The analytical characteristics of the method (e.g., limit of detection, linear range, preconcentration and improvement factors) were obtained. The limits of detection for cadmium are 0.7, 0.3 and 0.3 ppm in presence of SDS, CTAB and TX100, respectively. The method was applied for determination of cadmium in wastewaters.
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- P.J. Wangersky, in ed.: P.J. Wangersky, Intercomparisons and Intercalibrations, Marine Chemistry, Springer-Verlag: Berlin (2000).
- M.L. Garrido, R.M. Olivas and C. Camara, J. Anal. At. Spectrom., 13, 295 (1998); https://doi.org/10.1039/A707419K.
- FAO/WHO Joint Expert Committee on Food Additives, WHO Techical Report Snal. No. 505, p. 32 (1972).
- World Health Organization (WHO), Guidelines for Drinking-Water Quality, WHO Press: Geneva, edn 3, vol. 1 (2008).
- I. Oehme and O.S. Wolfbeis, Mikrochim. Acta, 126, 177 (1997); https://doi.org/10.1007/BF01242319.
- M. Pesavento, G. Alberti and R. Biesuz, Anal. Chim. Acta, 631, 129 (2009); https://doi.org/10.1016/j.aca.2008.10.046.
- R. Sitko, B. Zawisza and E. Malicka, Trends Analyt. Chem., 37, 22 (2012); https://doi.org/10.1016/j.trac.2012.03.016.
- X.G. Li, H. Feng, M.R. Huang, G.L. Gu and M.G. Moloney, Anal. Chem., 84, 134 (2012); https://doi.org/10.1021/ac2028886.
- M.-R. Huang, Y.-B. Ding and X.-G. Li, Analyst, 138, 3820 (2013); https://doi.org/10.1039/C3AN00346A.
- M.R. Huang, X.W. Rao, X.G. Li and Y.B. Ding, Talanta, 85, 1575 (2011); https://doi.org/10.1016/j.talanta.2011.06.049.
- X.G. Li, X.L. Ma and M.R. Huang, Talanta, 78, 498 (2009); https://doi.org/10.1016/j.talanta.2008.11.045.
- A.N. Araújo, R.C.C. Costa and J.L.F.C. Lima, Anal. Sci., 15, 991 (1999); https://doi.org/10.2116/analsci.15.991.
- I. Karadjova, G. Zachariadis, G. Boskou and J. Stratis, J. Anal. At. Spectrom., 13, 201 (1998); https://doi.org/10.1039/a707256b.
- P. Viñas, I. López-García, M. Lanzón and M. Hernández-Córdoba, J. Agric. Food Chem., 45, 3952 (1997); https://doi.org/10.1021/jf970272u.
- A Junker-Buchheit and M.J. Witzenbacher, J. Chromatogr. A, 737, 67 (1996); https://doi.org/10.1016/0021-9673(95)01337-7.
- J.S. Fritz, Analytical Solid Phase Extraction, Wiley-VCH: New York, edn 1 (1999).
- M. Ghaedi, A. Shokrollahi, K. Niknam, E. Niknam, A. Najibi and M. Soylak, J. Hazard. Mater., 168, 1022 (2009); https://doi.org/10.1016/j.jhazmat.2009.02.130.
- M. Ghaedi, A. Shokrollahi, A.H. Kianfar, A.S. Mirsadeghi, A. Pourfarokhi and M. Soylak, J. Hazard. Mater., 154, 128 (2008); https://doi.org/10.1016/j.jhazmat.2007.10.003.
- M. Ghaedi and M.R. Fathi, Fresenius Environ. Bull., 14, 1158 (2005).
- M. Soylak and M. Tuzen, J. Hazard. Mater., 152, 656 (2008); https://doi.org/10.1016/j.jhazmat.2007.07.027.
- A.N. Anthemidis, D.G. Themelis and J.A. Stratis, Talanta, 54, 37 (2001); https://doi.org/10.1016/S0039-9140(00)00620-2.
- L. Pan, Y.C. Qin, B. Hu and Z.C. Jiang, Chem. Res. Chin. Univ., 23, 399 (2007); https://doi.org/10.1016/S1005-9040(07)60086-5.
- S.Z. Mohammadi Mobarakeh, M.A. Taher and A. Mostafavi, Can. J. Anal. Sci. Spectrosc., 50, 7 (2005).
- D. Afzali, M. Taher, A. Mostafavi and S. Mobarakeh, Talanta, 65, 476 (2005); https://doi.org/10.1016/j.talanta.2004.06.027).
- M.A. Taher, B.K. Puri and R.K. Bansal, Microchem. J., 58, 21 (1998); https://doi.org/10.1006/mchj.1997.1502.
- A. Shokrollahi, M. Ghaedi, O. Hossaini, N. Khanjari and M. Soylak, J. Hazard. Mater., 160, 435 (2008); https://doi.org/10.1016/j.jhazmat.2008.03.016
References
P.J. Wangersky, in ed.: P.J. Wangersky, Intercomparisons and Intercalibrations, Marine Chemistry, Springer-Verlag: Berlin (2000).
M.L. Garrido, R.M. Olivas and C. Camara, J. Anal. At. Spectrom., 13, 295 (1998); https://doi.org/10.1039/A707419K.
FAO/WHO Joint Expert Committee on Food Additives, WHO Techical Report Snal. No. 505, p. 32 (1972).
World Health Organization (WHO), Guidelines for Drinking-Water Quality, WHO Press: Geneva, edn 3, vol. 1 (2008).
I. Oehme and O.S. Wolfbeis, Mikrochim. Acta, 126, 177 (1997); https://doi.org/10.1007/BF01242319.
M. Pesavento, G. Alberti and R. Biesuz, Anal. Chim. Acta, 631, 129 (2009); https://doi.org/10.1016/j.aca.2008.10.046.
R. Sitko, B. Zawisza and E. Malicka, Trends Analyt. Chem., 37, 22 (2012); https://doi.org/10.1016/j.trac.2012.03.016.
X.G. Li, H. Feng, M.R. Huang, G.L. Gu and M.G. Moloney, Anal. Chem., 84, 134 (2012); https://doi.org/10.1021/ac2028886.
M.-R. Huang, Y.-B. Ding and X.-G. Li, Analyst, 138, 3820 (2013); https://doi.org/10.1039/C3AN00346A.
M.R. Huang, X.W. Rao, X.G. Li and Y.B. Ding, Talanta, 85, 1575 (2011); https://doi.org/10.1016/j.talanta.2011.06.049.
X.G. Li, X.L. Ma and M.R. Huang, Talanta, 78, 498 (2009); https://doi.org/10.1016/j.talanta.2008.11.045.
A.N. Araújo, R.C.C. Costa and J.L.F.C. Lima, Anal. Sci., 15, 991 (1999); https://doi.org/10.2116/analsci.15.991.
I. Karadjova, G. Zachariadis, G. Boskou and J. Stratis, J. Anal. At. Spectrom., 13, 201 (1998); https://doi.org/10.1039/a707256b.
P. Viñas, I. López-García, M. Lanzón and M. Hernández-Córdoba, J. Agric. Food Chem., 45, 3952 (1997); https://doi.org/10.1021/jf970272u.
A Junker-Buchheit and M.J. Witzenbacher, J. Chromatogr. A, 737, 67 (1996); https://doi.org/10.1016/0021-9673(95)01337-7.
J.S. Fritz, Analytical Solid Phase Extraction, Wiley-VCH: New York, edn 1 (1999).
M. Ghaedi, A. Shokrollahi, K. Niknam, E. Niknam, A. Najibi and M. Soylak, J. Hazard. Mater., 168, 1022 (2009); https://doi.org/10.1016/j.jhazmat.2009.02.130.
M. Ghaedi, A. Shokrollahi, A.H. Kianfar, A.S. Mirsadeghi, A. Pourfarokhi and M. Soylak, J. Hazard. Mater., 154, 128 (2008); https://doi.org/10.1016/j.jhazmat.2007.10.003.
M. Ghaedi and M.R. Fathi, Fresenius Environ. Bull., 14, 1158 (2005).
M. Soylak and M. Tuzen, J. Hazard. Mater., 152, 656 (2008); https://doi.org/10.1016/j.jhazmat.2007.07.027.
A.N. Anthemidis, D.G. Themelis and J.A. Stratis, Talanta, 54, 37 (2001); https://doi.org/10.1016/S0039-9140(00)00620-2.
L. Pan, Y.C. Qin, B. Hu and Z.C. Jiang, Chem. Res. Chin. Univ., 23, 399 (2007); https://doi.org/10.1016/S1005-9040(07)60086-5.
S.Z. Mohammadi Mobarakeh, M.A. Taher and A. Mostafavi, Can. J. Anal. Sci. Spectrosc., 50, 7 (2005).
D. Afzali, M. Taher, A. Mostafavi and S. Mobarakeh, Talanta, 65, 476 (2005); https://doi.org/10.1016/j.talanta.2004.06.027).
M.A. Taher, B.K. Puri and R.K. Bansal, Microchem. J., 58, 21 (1998); https://doi.org/10.1006/mchj.1997.1502.
A. Shokrollahi, M. Ghaedi, O. Hossaini, N. Khanjari and M. Soylak, J. Hazard. Mater., 160, 435 (2008); https://doi.org/10.1016/j.jhazmat.2008.03.016