A homologous series of Schiff base esters, 4-(methylthio)benzylidene-4'-n-alkanoyloxyanilines possessing even number of carbon atoms at the alkanoyloxy chain (Cn-1H2n-1COO-, n = 2 to 18) was synthesized. The structure of the 4-(methylthio)benzylidene-4'-n-alkanoyloxyanilines was confirmed by elemental analysis and spectroscopic techniques including FT-IR, 1H and 13C NMR and EI-MS. Mesomorphic properties were evaluated by differential scanning calorimetry and polarizing optical microscopy techniques. Whilst n-butanoyloxy to n-octanoyloxy derivatives exhibited monotropic nematic phase, n-ethanoyloxy and n-decanoyloxy to n-octadecanoyloxy derivatives were non-mesogenic compounds. The mesomorphic properties of the present series were compared with other structurally related series to establish the chemical structure-mesomorphic property relationship.
Ha, S.-T., Lee, T.-L., Yeap, G.-Y., Lin, H.-C., M. Ito, M., & T. Subramaniam, R. (2011). Synthesis and Mesomorphic Properties of 4-(Methylthio)benzylidene-4’-n-alkanoyloxyanilines. Asian Journal of Chemistry, 23(10), 4609–4612. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10908