Synthesis and Characterization of Iron(II) Carbonyl Complexes Related to Cluster-Free Hydrogenase
Corresponding Author(s) : Zhenhong Wei
weizh@ncu.edu.cn
Asian Journal of Chemistry,
Vol. 23 No. 10 (2011): Vol 23 Issue 10
Abstract
Reactions of [Fe(CO)4I2] with one equivalent of PyCH2NHC2H4SNa (L1 – Na+) and PyCH2NH2 (L2) in THF separately gave rise to complexes [Fe(CO)2(L1)I] (1) and [Fe(CO)2(L2)I2] (2). Both the complexes show two strong carbonyl absorptions at 2027, 1974 cm-1 (1) and 2036, 1989 cm-1 (2), which are very close to that of cluster-free hydrogenase (Hmd).
Keywords
[Fe]-Hydrogenase
Iron carbonyl
2-Aminomethylpyridine
N-(2-Mercaptoethyl)- picolylamine
Long, L., & Wei, Z. (2011). Synthesis and Characterization of Iron(II) Carbonyl Complexes Related to Cluster-Free Hydrogenase. Asian Journal of Chemistry, 23(10), 4461–4463. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10879
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