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Synthesis, Characterization and Coordination Chemistry of N,N'-bis(3-pyridylmethyl)benzene-1,4-dicarboxamide with Palladium and Ruthenium Salts
Corresponding Author(s) : Mohammad Moneruzzaman Khandaker
Asian Journal of Chemistry,
Vol. 29 No. 7 (2017): Vol 29 Issue 7
Abstract
N,N’-bis(3-pyridylmethyl)benzene-1,4-dicarboxamide (L) is a diamide bridging ligand. Utilization of bridging ligand such as L that exhibits amide moieties has greater potential to encapsulate anion via N-H hydrogen bonding donor groups and form metal ligand interaction via its pendant group containing pyridine-N atom. The complexes derived from this ligand also capable to form metallosupramolecular assemblies with the presence of the respective moieties. N,N’-bis(3-pyridylmethyl)benzene-1,4-dicarboxamide is synthesized from reaction between terephthaloyl chloride and 3-pyridylmethylamine in basic solution. The coordination chemistry between ligand L and two metal salts, palladium chloride and ruthenium chloride were attempted. Based on the combination of spectroscopic techniques such as CHNS, FTIR, NMR, TGA and cyclic voltammetry analysis, the molecular formula of the complexes may be suggested as: [Pd2(L)Cl4] and [Ru2(L)Cl6(H2O)4·2H2O].
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- M. Abdul-Kadir, L.R. Hanton and C.J. Sumby, Dalton Trans., 41, 4497 (2012); https://doi.org/10.1039/C2DT12320G.
- S.T. Nguyen, D.L. Gin, J.T. Hupp, X. Zhang, Procd. Natl. Acad. Sci., 98, 11849 (2001); https://doi.org/10.1073/pnas.201373898.
- R.A. Begum, D. Powell and K. Bowman-James, Inorg. Chem., 45, 964 (2006); https://doi.org/10.1021/ic051775h.
- A. Togni and L.M. Venanzi, Int. Ed. Engl., 33, 497 (1994); https://doi.org/10.1002/anie.199404971.
- W.-M. Dai, Y. Li, Y. Zhang, K. Wah Lai and J. Wu, Tetrahedron Lett., 45, 1999 (2004); https://doi.org/10.1016/j.tetlet.2003.12.142.
- C.J. Sumby, J. Coord. Chem., 255, 1937 (2011); https://doi.org/10.1016/j.ccr.2011.03.015.
- C.J. Sumby and L.R. Hanton, Tetrahedron, 65, 4681 (2009); https://doi.org/10.1016/j.tet.2009.04.031.
- F.A. Chavez, M.M. Olmstead and P.K. Mascharak, Inorg. Chim. Acta, 35, 1410 (1996); https://doi.org/10.1021/ic9512136.
- D.S. Marlin, M.M. Olmstead and P.K. Mascharak, Inorg. Chem., 40, 7003 (2001); https://doi.org/10.1021/ic010523n.
- M. Pitucha, J. Rzymowska, A. Olender and L. Grzybowska-Szatkowska, J. Serb. Chem. Soc., 77, 1 (2012); https://doi.org/10.2298/JSC110212157P.
- S. Vuoti, Acta Univ. Oul. A, 496 (2007).
- H. Turkmen and B. Cetinkaya, J. Organomet. Chem., 691, 3749 (2006); https://doi.org/10.1016/j.jorganchem.2006.05.020.
- O. Belda and C. Moberg, Coord. Chem. Rev., 249, 727 (2005); https://doi.org/10.1016/j.ccr.2004.08.025.
- E. Eskelinen, P. Da Costa and M. Haukka, J. Electrochem. Chem., 579, 257 (2005); https://doi.org/10.1016/j.jelechem.2005.02.014.
References
M. Abdul-Kadir, L.R. Hanton and C.J. Sumby, Dalton Trans., 41, 4497 (2012); https://doi.org/10.1039/C2DT12320G.
S.T. Nguyen, D.L. Gin, J.T. Hupp, X. Zhang, Procd. Natl. Acad. Sci., 98, 11849 (2001); https://doi.org/10.1073/pnas.201373898.
R.A. Begum, D. Powell and K. Bowman-James, Inorg. Chem., 45, 964 (2006); https://doi.org/10.1021/ic051775h.
A. Togni and L.M. Venanzi, Int. Ed. Engl., 33, 497 (1994); https://doi.org/10.1002/anie.199404971.
W.-M. Dai, Y. Li, Y. Zhang, K. Wah Lai and J. Wu, Tetrahedron Lett., 45, 1999 (2004); https://doi.org/10.1016/j.tetlet.2003.12.142.
C.J. Sumby, J. Coord. Chem., 255, 1937 (2011); https://doi.org/10.1016/j.ccr.2011.03.015.
C.J. Sumby and L.R. Hanton, Tetrahedron, 65, 4681 (2009); https://doi.org/10.1016/j.tet.2009.04.031.
F.A. Chavez, M.M. Olmstead and P.K. Mascharak, Inorg. Chim. Acta, 35, 1410 (1996); https://doi.org/10.1021/ic9512136.
D.S. Marlin, M.M. Olmstead and P.K. Mascharak, Inorg. Chem., 40, 7003 (2001); https://doi.org/10.1021/ic010523n.
M. Pitucha, J. Rzymowska, A. Olender and L. Grzybowska-Szatkowska, J. Serb. Chem. Soc., 77, 1 (2012); https://doi.org/10.2298/JSC110212157P.
S. Vuoti, Acta Univ. Oul. A, 496 (2007).
H. Turkmen and B. Cetinkaya, J. Organomet. Chem., 691, 3749 (2006); https://doi.org/10.1016/j.jorganchem.2006.05.020.
O. Belda and C. Moberg, Coord. Chem. Rev., 249, 727 (2005); https://doi.org/10.1016/j.ccr.2004.08.025.
E. Eskelinen, P. Da Costa and M. Haukka, J. Electrochem. Chem., 579, 257 (2005); https://doi.org/10.1016/j.jelechem.2005.02.014.