Study of Catalytic Activity of Silica Supported Schiff Base Complexes

J.M. Deshmukh; L.H. Mahind; S.A. Waghmode; S.P. Dagade

doi:10.14233/ajchem.2017.20509

Issue

Vol. 29 No. 7 (2017): Vol 29 Issue 7

Issue Published : May 13, 2017

This work is licensed under a Creative Commons Attribution 4.0 International License.

Study of Catalytic Activity of Silica Supported Schiff Base Complexes

https://doi.org/10.14233/ajchem.2017.20509

J.M. Deshmukh

Department of Chemistry, Yashwantrao Mohite College, Pune-411 038, India

L.H. Mahind

Department of Chemistry, Yashwantrao Mohite College, Pune-411 038, India

S.A. Waghmode

Department of Chemistry, Aabasaheb Garware College, Pune-411 004, India

S.P. Dagade

Department of Chemistry, Yashwantrao Mohite College, Pune-411 038, India

Corresponding Author(s) : S.P. Dagade

dagade@rediffmail.com

Asian Journal of Chemistry, Vol. 29 No. 7 (2017): Vol 29 Issue 7
Article Published : May 13, 2017

Abstract

The catalytic activity of silica supported Schiff base metal complexes have been studied for the oxidation of benzyl alcohol, using hydrogen peroxide, which gave benzaldehyde as a major product. Silica supported Schiff base complexes gave better results compared to unsupported Schiff base complexes. Schiff base metal complexes such as Cr(VI), Mo(VI) and W(VI) have played significant role to enhance their conversion and selectivity. Among these Cr(VI) showed better conversion.

Keywords

Benzyl alcohol Hydrogen peroxide Oxidation Schiff base metal complex

Deshmukh, J., Mahind, L., Waghmode, S., & Dagade, S. (2017). Study of Catalytic Activity of Silica Supported Schiff Base Complexes. Asian Journal of Chemistry, 29(7), 1455–1458. https://doi.org/10.14233/ajchem.2017.20509

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References

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References

A.M. Abu-Dief and I.M.A. Mohamed, Beni-Suef Univ. J. Basic Appl. Sci., 4, 119 (2015); https://doi.org/10.1016/j.bjbas.2015.05.004.

P. Pfeiffer, E. Breith, E. Lübbe and T. Tsumaki, Liebigs Ann. Chem., 503, 84 (1993); https://doi.org/10.1002/jlac.19335030106.

T.A. Alsalim, J.S. Hadi, O.N. Ali, H.S. Abbo and S.J.J. Titinchi, Chem. Centr. J., 7, 3 (2013); https://doi.org/10.1186/1752-153X-7-3.

R. Irie, K. Noda, Y. Ito, N. Matsumoto and T. Katsuki, Tetrahedron Lett., 31, 7345 (1990); https://doi.org/10.1016/S0040-4039(00)88562-7.

E.N. Jacobsen, Comprehensive Organometallic Chemistry II, vol. 12, p. 1097 (1995).

N.S. Venkataramanan, G. Kuppuraj and S. Rajagopal, Coord. Chem. Rev., 249, 1249 (2005); https://doi.org/10.1016/j.ccr.2005.01.023.

B.M. Choudary, T. Ramani, H. Maheswaran, L. Prashant, K.V.S. Ranganath and K.V. Kumar, Adv. Synth. Catal., 348, 493 (2006); https://doi.org/10.1002/adsc.200505427.

S. Mohebbi, F. Nikpour and S. Raiati, J. Mol. Catal. Chem., 256, 265 (2006); https://doi.org/10.1016/j.molcata.2006.04.041.

P. Cozzi, Chem. Soc. Rev., 33, 410 (2004); https://doi.org/10.1039/B307853C.

A. Haikarainen, J. Sipila, P. Pietikäinen, A. Pajunen and I. Mutikainen, J. Chem. Soc., Dalton Trans., 991 (2001); https://doi.org/10.1039/b008167l.

W. Zhang, J.L. Loebach, S.R. Wilson and E.N. Jacobsen, J. Am. Chem. Soc., 112, 2801 (1990); https://doi.org/10.1021/ja00163a052.

M. Silva, C. Freire, B. de Castro and J.L. Figueiredo, J. Mol. Catal. Chem., 258, 327 (2006); https://doi.org/10.1016/j.molcata.2006.05.070.

C.T. Dalton, K.M. Ryan, V.M. Wall, C. Bousquet and D.G. Gilheany, Top. Catal., 5, 75 (1998); https://doi.org/10.1023/A:1019102003494.

W. Adam, K.J. Roschmann, C.R. Saha-Möller and D. Seebach, J. Am. Chem. Soc., 124, 5068 (2002); https://doi.org/10.1021/ja0177206.

E.N. Jacobsen and M.H. Wu, in eds.: A. Pfaltz, E.N. Jacobsen and H. Yamamoto, Comprehensive Asymmetric Catalysis, Springer-Verlag, Berlin, vol. 2, p. 649 (1999).

N.H. Khan, S. Agrawal, R.I. Kureshy, S.H.R. Abdi, V.J. Mayani and R.V. Jasra, Tetrahedron Asymm., 17, 2659 (2006); https://doi.org/10.1016/j.tetasy.2006.09.024.

N. Raman, R. Jeyamurugan, M. Subbulakshmi, R. Boominathan and C. Yuvarajan, Chem. Pap., 64, 318 (2010); https://doi.org/10.2478/s11696-010-0003-0.

T. Shamspur, I. Sheikhshoaie and M.H. Mashhadizadeh, J. Anal. At. Spectrom., 20, 476 (2005); https://doi.org/10.1039/B416097E.

S. Priyarega, M.M. Tamizh, R. Karvembu, R. Prabhakaran and K. Natarajan, J. Chem. Sci., 123, 319 (2011); https://doi.org/10.1007/s12039-011-0087-2.

M.R. Ganjali, T. Poursaberi, M. Hosseini, M. Salavati-Niasary, M. Yousefi and M. Shamsipur, Anal. Sci., 18, 289 (2002); https://doi.org/10.2116/analsci.18.289.

M. Tumer, E. Akgun, S. Toroglu, A. Kayraldiz and L. Donbak, J. Coord. Chem., 61, 2935 (2008); https://doi.org/10.1080/00958970801989902.

S.P. Dagade, V.B. Mane, A.A. Jape, S.A. Waghmode, V.V. Dhapte and L.H. Mahind, Int. J. Chem. Anal. Sci., 3, 1672 (2012).

Issue

Vol. 29 No. 7 (2017): Vol 29 Issue 7

Study of Catalytic Activity of Silica Supported Schiff Base Complexes

Corresponding Author(s) : S.P. Dagade

Abstract

Keywords

Full Article

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References

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