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Synthesis and Characterization of Some Homonuclear Bimetallic Complexes with Macrocyclic Ligands: A Photoelectron Spectroscopic Study
Corresponding Author(s) : Abhishek Kumar
Asian Journal of Chemistry,
Vol. 29 No. 7 (2017): Vol 29 Issue 7
Abstract
We have synthesized bimetallic macrocyclic complexes through chemical condensation method by using pyridine-2,6-dicarboxaldehyde with 1,2-bis(2-aminoethoxy) ethane where L is the macrocyclic ligand. The synthesized complexes were characterized by elemental analysis, IR, XPS data, NMR and UV-visible spectroscopy.
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- R.M. Izatt, J.S. Bradshaw, S.A. Nielsen, J.D. Lamb, J.J. Christensen and D. Sen, Chem. Rev., 85, 271 (1985); https://doi.org/10.1021/cr00068a003.
- K.B. Mertes, J.M. Lehnin and G. Wilkinsion, Comprehensive Coordination Chemistry, Pergamon, Oxford, p. 915 (1987).
- G.W. Gokel, W.M. Leevy and M.E. Weber, Chem. Rev., 104, 2723 (2004); https://doi.org/10.1021/cr020080k.
- D.H. Busch, Acc. Chem. Res., 11, 392 (1978); https://doi.org/10.1021/ar50130a005.
- J.S. Trommel and L.G. Marzilli, Inorg. Chem., 40, 4374 (2001); https://doi.org/10.1021/ic010232e.
- X. Lu, Z. Geng, Y. Wang, B. Lv and J. Kang, Synth. React. Inorg. Met.-Org. Chem., 32, 843 (2002); https://doi.org/10.1081/SIM-120005606.
- M.S. Niasari and F. Davar, Inorg. Chem. Commun., 9, 175 (2006); https://doi.org/10.1016/j.inoche.2005.10.028.
- C.M. Che and W.K. Cheng, J. Chem. Soc. Commun., 1443 (1986); https://doi.org/10.1039/c39860001443.
- L. Casella, M. Gullotti, L. De Gioia, E. Monzani and F. Chillemi, J. Chem. Soc., Dalton Trans., 2945 (1991); https://doi.org/10.1039/dt9910002945.
- Md. Mahbubul Alam, J. Bangladesh Acad. Sci., 35, 61 (2011).
- S. Srivastava and A. Kalam, Synth. React. Inorg. Met.-Org. Chem., 34, 1529 (2004); https://doi.org/10.1081/SIM-200026581.
- A. Kumar, S. Malviya and S. Srivastava, Asian J. Res. Chem, 9, 277 (2016); https://doi.org/10.5958/0974-4150.2016.00045.6.
- A. Kumar, S. Malviya, R.K. Kushwaha, R. Kumar and S. Srivastava, Int. J. Chem. Phys. Sci., 5, 35 (2016).
- H. Keypour, M. Rezaeivala, L. Valencia and P. Perez-Lourido, Polyhedron, 27, 3172 (2008); https://doi.org/10.1016/j.poly.2008.07.012.
- H. Keypour, M. Rezaeivala, L. Valencia, S. Salehzadeh, P. Perez-Lourido and H.R. Khavasi, Polyhedron, 28, 3533 (2009); https://doi.org/10.1016/j.poly.2009.05.083.
- S. Srivastava, Polyhedron, 4, 1925 (1985); https://doi.org/10.1016/S0277-5387(00)86712-1.
References
R.M. Izatt, J.S. Bradshaw, S.A. Nielsen, J.D. Lamb, J.J. Christensen and D. Sen, Chem. Rev., 85, 271 (1985); https://doi.org/10.1021/cr00068a003.
K.B. Mertes, J.M. Lehnin and G. Wilkinsion, Comprehensive Coordination Chemistry, Pergamon, Oxford, p. 915 (1987).
G.W. Gokel, W.M. Leevy and M.E. Weber, Chem. Rev., 104, 2723 (2004); https://doi.org/10.1021/cr020080k.
D.H. Busch, Acc. Chem. Res., 11, 392 (1978); https://doi.org/10.1021/ar50130a005.
J.S. Trommel and L.G. Marzilli, Inorg. Chem., 40, 4374 (2001); https://doi.org/10.1021/ic010232e.
X. Lu, Z. Geng, Y. Wang, B. Lv and J. Kang, Synth. React. Inorg. Met.-Org. Chem., 32, 843 (2002); https://doi.org/10.1081/SIM-120005606.
M.S. Niasari and F. Davar, Inorg. Chem. Commun., 9, 175 (2006); https://doi.org/10.1016/j.inoche.2005.10.028.
C.M. Che and W.K. Cheng, J. Chem. Soc. Commun., 1443 (1986); https://doi.org/10.1039/c39860001443.
L. Casella, M. Gullotti, L. De Gioia, E. Monzani and F. Chillemi, J. Chem. Soc., Dalton Trans., 2945 (1991); https://doi.org/10.1039/dt9910002945.
Md. Mahbubul Alam, J. Bangladesh Acad. Sci., 35, 61 (2011).
S. Srivastava and A. Kalam, Synth. React. Inorg. Met.-Org. Chem., 34, 1529 (2004); https://doi.org/10.1081/SIM-200026581.
A. Kumar, S. Malviya and S. Srivastava, Asian J. Res. Chem, 9, 277 (2016); https://doi.org/10.5958/0974-4150.2016.00045.6.
A. Kumar, S. Malviya, R.K. Kushwaha, R. Kumar and S. Srivastava, Int. J. Chem. Phys. Sci., 5, 35 (2016).
H. Keypour, M. Rezaeivala, L. Valencia and P. Perez-Lourido, Polyhedron, 27, 3172 (2008); https://doi.org/10.1016/j.poly.2008.07.012.
H. Keypour, M. Rezaeivala, L. Valencia, S. Salehzadeh, P. Perez-Lourido and H.R. Khavasi, Polyhedron, 28, 3533 (2009); https://doi.org/10.1016/j.poly.2009.05.083.
S. Srivastava, Polyhedron, 4, 1925 (1985); https://doi.org/10.1016/S0277-5387(00)86712-1.