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Vol. 23 No. 8 (2011): Vol 23 Issue 8

Synthesis and Characterization of Dioxomolybdenum(VI) Complexes with 1,10-Phenanthroline and 2,2'-Bipyridyl

R.R. Khojasteh
Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran
Sajedeh Lotfalian Saremi
Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran
M. Ahmadzadeh
Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran

Corresponding Author(s) : Sajedeh Lotfalian Saremi

sajedehsaremi@gmail.com

Asian Journal of Chemistry, Vol. 23 No. 8 (2011): Vol 23 Issue 8

Abstract

Two new dioxomolybdenum(VI) complexes [MoO2L2]2+ [(L = phen(I), bipy(II)] with heterocyclic amines 1,10-phenanthroline and 2,2'-bipyridyl ligands have been synthesized and characterized. Compounds I (93 % yield) and compound II (92 % yield) were obtained from the reactions of MoO2(acac)2 [acac = acetylacetonato] with 1 equivalent of phen and bipy. Elemental analysis and 1H, 13CNMR, IR spectral data indicated that both structures compounds were six-coordinate and suggest that they have nearly octahedral symmetry.

Keywords

2,2′-Bipyridyl Dioxomolylbdenum(VI) 1,10-Phenanthroline Structures
Khojasteh, R., Lotfalian Saremi, S., & Ahmadzadeh, M. (2011). Synthesis and Characterization of Dioxomolybdenum(VI) Complexes with 1,10-Phenanthroline and 2,2’-Bipyridyl. Asian Journal of Chemistry, 23(8), 3769–3770. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10720
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