Hydrogenolysis of Glycerol using Fe-Fe/Al2O3 Complex Catalyst

Sunder Lal; Ramswaroop Singh Thakur

doi:10.14233/ajchem.2016.19950

Issue

Vol. 28 No. 12 (2016): Vol 28 Issue 12

Issue Published : September 1, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Hydrogenolysis of Glycerol using Fe-Fe/Al2O3 Complex Catalyst

https://doi.org/10.14233/ajchem.2016.19950

Sunder Lal

Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal-462 003, India

Ramswaroop Singh Thakur

Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal-462 003, India

Corresponding Author(s) : Sunder Lal

sunderlalin@gmail.com

Asian Journal of Chemistry, Vol. 28 No. 12 (2016): Vol 28 Issue 12
Article Published : September 2, 2016

Abstract

Macrocyclic complex catalyst Fe-FeL₁ complex of L₁ (L₁ = C₂₄H₂₆O₂N₄_.) was synthesized and studied in the hydrogenolysis reaction of glycerol reaction in a high pressure batch reactor. The catalyst was well characterized i.e. FTIR, XRD, TGA and BET surface area. The study of hydrogenolysis was found that the selectivity of 1,2-propane diol 80 % at 220 °C temperature and 0.35 MPa pressure in presence of hydrogen gas and Fe-Fe/Al2O3 and 30 % glycerol concentration in water gives 1,2-propane diol as the only product and conversion was 36 % at 220 °C. It is further seen that if the concentration of glycerol in water is increased beyond 40 % there is a decrease in the total conversion and carbon is produced as coke during the reaction.

Keywords

Complex catalysts Hydrogenolysis Bimetallic complex Fe-FeL1/Al2O3

Lal, S., & Thakur, R. S. (2016). Hydrogenolysis of Glycerol using Fe-Fe/Al2O3 Complex Catalyst. Asian Journal of Chemistry, 28(12), 2596–2600. https://doi.org/10.14233/ajchem.2016.19950

Download Citation

References

R. Connor and H. Adkins, J. Am. Chem. Soc., 54, 4678 (1932); doi:10.1021/ja01351a026.
W.E. Kaufmann and R. Adams, J. Am. Chem. Soc., 45, 3029 (1923); doi:10.1021/ja01665a033.
R.D. Cortright, R.M. Watwe and J.A. Dumesic, J. Mol. Catal. Chem., 163, 91 (2000); doi:10.1016/S1381-1169(00)00402-7.
S. Wang and H. Liu, Catal. Lett., 117, 62 (2007); doi:10.1007/s10562-007-9106-9.
J. Chaminand, L. Djakovitch, P. Gallezot, P. Marion, C. Pinel and C. Rosier, Green Chem., 6, 359 (2004); doi:10.1039/b407378a.
A. Perosa and P. Tundo, Ind. Eng. Chem. Res., 44, 8535 (2005); doi:10.1021/ie0489251.
X. Guo, Y. Li, R. Shi, Q. Liu, E. Zhan and W. Shen, Appl. Catal. A, 371, 108 (2009); doi:10.1016/j.apcata.2009.09.037.
M. Balaraju, V. Rekha, P.S.S. Prasad, B.L.A.P. Devi, R.B.N. Prasad and N. Lingaiah, Appl. Catal. A, 354, 82 (2009); doi:10.1016/j.apcata.2008.11.010.
Y. Shinmi, S. Koso, T. Kubota, Y. Nakagawa and K. Tomishige, Appl. Catal. B, 94, 318 (2010); doi:10.1016/j.apcatb.2009.11.021.
M.A. Dasari, P.-P. Kiatsimkul, W.R. Sutterlin and G.J. Suppes, Appl. Catal. A, 281, 225 (2005); doi:10.1016/j.apcata.2004.11.033.
Y. Kusunoki, T. Miyazawa, K. Kunimori and K. Tomishige, Catal. Commun., 6, 645 (2005); doi:10.1016/j.catcom.2005.06.006.
T. Miyazawa, S. Koso, K. Kunimori and K. Tomishige, Appl. Catal. A, 318, 244 (2007); doi:10.1016/j.apcata.2006.11.006.
T. Miyazawa, Y. Kusunoki, K. Kunimori and K. Tomishige, J. Catal., 240, 213 (2006); doi:10.1016/j.jcat.2006.03.023.
D. Roy, B. Subramaniam and R.V. Chaudhari, Catal. Today, 156, 31 (2010); doi:10.1016/j.cattod.2010.01.007.
K.A. Anand, K.S. Anisia, A.K. Agarwal and A. Kumar, Can. J. Chem. Eng., 88, 208 (2010); doi:10.1002/cjce.20273.
C.W. Chiu, M.A. Dasari, W.R. Sutterlin and G.J. Suppes, Ind. Eng. Chem. Res., 45, 791 (2006); doi:10.1021/ie050915s.
G. Zhou, T. Cheng, W. Li, Y. Bi and K. Zhen, React. Kinet. Catal. Lett., 79, 295 (2003); doi:10.1023/A:1024590203256.
P. Fouilloux, Appl. Catal., 8, 1 (1983); doi:10.1016/0166-9834(83)80051-7.
D.G. Lahr and B.H. Shanks, Ind. Eng. Chem. Res., 42, 5467 (2003); doi:10.1021/ie030468l.
L. Ma, D. He and Z. Li, Catal. Commun., 9, 2489 (2008); doi:10.1016/j.catcom.2008.07.009.
S. Koso, N. Ueda, Y. Shinmi, K. Okumura, T. Kizuka and K. Tomishige, J. Catal., 267, 89 (2009); doi:10.1016/j.jcat.2009.07.010.

References

R. Connor and H. Adkins, J. Am. Chem. Soc., 54, 4678 (1932); doi:10.1021/ja01351a026.

W.E. Kaufmann and R. Adams, J. Am. Chem. Soc., 45, 3029 (1923); doi:10.1021/ja01665a033.

R.D. Cortright, R.M. Watwe and J.A. Dumesic, J. Mol. Catal. Chem., 163, 91 (2000); doi:10.1016/S1381-1169(00)00402-7.

S. Wang and H. Liu, Catal. Lett., 117, 62 (2007); doi:10.1007/s10562-007-9106-9.

J. Chaminand, L. Djakovitch, P. Gallezot, P. Marion, C. Pinel and C. Rosier, Green Chem., 6, 359 (2004); doi:10.1039/b407378a.

A. Perosa and P. Tundo, Ind. Eng. Chem. Res., 44, 8535 (2005); doi:10.1021/ie0489251.

X. Guo, Y. Li, R. Shi, Q. Liu, E. Zhan and W. Shen, Appl. Catal. A, 371, 108 (2009); doi:10.1016/j.apcata.2009.09.037.

M. Balaraju, V. Rekha, P.S.S. Prasad, B.L.A.P. Devi, R.B.N. Prasad and N. Lingaiah, Appl. Catal. A, 354, 82 (2009); doi:10.1016/j.apcata.2008.11.010.

Y. Shinmi, S. Koso, T. Kubota, Y. Nakagawa and K. Tomishige, Appl. Catal. B, 94, 318 (2010); doi:10.1016/j.apcatb.2009.11.021.

M.A. Dasari, P.-P. Kiatsimkul, W.R. Sutterlin and G.J. Suppes, Appl. Catal. A, 281, 225 (2005); doi:10.1016/j.apcata.2004.11.033.

Y. Kusunoki, T. Miyazawa, K. Kunimori and K. Tomishige, Catal. Commun., 6, 645 (2005); doi:10.1016/j.catcom.2005.06.006.

T. Miyazawa, S. Koso, K. Kunimori and K. Tomishige, Appl. Catal. A, 318, 244 (2007); doi:10.1016/j.apcata.2006.11.006.

T. Miyazawa, Y. Kusunoki, K. Kunimori and K. Tomishige, J. Catal., 240, 213 (2006); doi:10.1016/j.jcat.2006.03.023.

D. Roy, B. Subramaniam and R.V. Chaudhari, Catal. Today, 156, 31 (2010); doi:10.1016/j.cattod.2010.01.007.

K.A. Anand, K.S. Anisia, A.K. Agarwal and A. Kumar, Can. J. Chem. Eng., 88, 208 (2010); doi:10.1002/cjce.20273.

C.W. Chiu, M.A. Dasari, W.R. Sutterlin and G.J. Suppes, Ind. Eng. Chem. Res., 45, 791 (2006); doi:10.1021/ie050915s.

G. Zhou, T. Cheng, W. Li, Y. Bi and K. Zhen, React. Kinet. Catal. Lett., 79, 295 (2003); doi:10.1023/A:1024590203256.

P. Fouilloux, Appl. Catal., 8, 1 (1983); doi:10.1016/0166-9834(83)80051-7.

D.G. Lahr and B.H. Shanks, Ind. Eng. Chem. Res., 42, 5467 (2003); doi:10.1021/ie030468l.

L. Ma, D. He and Z. Li, Catal. Commun., 9, 2489 (2008); doi:10.1016/j.catcom.2008.07.009.

S. Koso, N. Ueda, Y. Shinmi, K. Okumura, T. Kizuka and K. Tomishige, J. Catal., 267, 89 (2009); doi:10.1016/j.jcat.2009.07.010.

Issue

Vol. 28 No. 12 (2016): Vol 28 Issue 12

Hydrogenolysis of Glycerol using Fe-Fe/Al2O3 Complex Catalyst

Corresponding Author(s) : Sunder Lal

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents