Synthesis and Characterization of Novel Bis-Arsenic Complexes

L. Arabuli; D. Matoga; N. Lekishvili

Issue

Vol. 23 No. 7 (2011): Vol 23 Issue 7

Issue Published : March 11, 2011

Synthesis and Characterization of Novel Bis-Arsenic Complexes

L. Arabuli

Iv. Javakhishvili Tbilisi State University, 3, Ilia Chavchavadze ave., 0128 Tbilisi, Georgia

D. Matoga

The Jagiellonian Univerity, R. Ingardena 3, 30-060 Krakow, Poland

N. Lekishvili

Iv. Javakhishvili Tbilisi State University, 3, Ilia Chavchavadze ave., 0128 Tbilisi, Georgia

Corresponding Author(s) : L. Arabuli

lyly.arabuli@tsu.ge; lekino@gmail.com

Asian Journal of Chemistry, Vol. 23 No. 7 (2011): Vol 23 Issue 7
Article Published : March 23, 2011

Abstract

p-Phenylenebis[diethyl(iso-propyl)arsonium] tetra-N-thiocyanatocobaltate(II) cationic-anionic complex have been synthesized and studied. The X-ray structure of ⁺[(i-Pr)₂(Et)₄As₂(Ph)]⁺ [Co(NCS)₄]^2- have been determined. Crystals belong to the tetragonal system, space group P-42(1)m) with a = 14.4930(14)Å, b = 14.4930(14)Å, c = 8.7090(19)Å; α = 90°, β = 90°, γ = 90°. The structures were refined to an R value of 0.063 from 4082 observed reflections. The As atom is coordinated tetrahedraly to the substituents as well as the anion has a tetrahedral configuration. The synthesis and IR spectral characterization of the complex compounds are described.

Keywords

bis-Arsenic complex Tetrahedral configuration Crystal structure Spectral analysis. Spectral analysis

Arabuli, L., Matoga, D., & Lekishvili, N. (2011). Synthesis and Characterization of Novel Bis-Arsenic Complexes. Asian Journal of Chemistry, 23(7), 2999–3002. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10602

Issue

Vol. 23 No. 7 (2011): Vol 23 Issue 7

Synthesis and Characterization of Novel Bis-Arsenic Complexes

Corresponding Author(s) : L. Arabuli

Abstract

Keywords

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