Deoxygenation of Propionic Acid in Gas Phase over Cobalt Molybdenum Catalyst

Hossein Bayahia

doi:10.14233/ajchem.2016.20107

Issue

Vol. 28 No. 12 (2016): Vol 28 Issue 12

Issue Published : September 1, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Deoxygenation of Propionic Acid in Gas Phase over Cobalt Molybdenum Catalyst

https://doi.org/10.14233/ajchem.2016.20107

Hossein Bayahia

Department of Chemistry, Faculty of Science, Albaha University, P.O. Box 1988, Albaha 65431, Saudi Arabia

Corresponding Author(s) : Hossein Bayahia

hbayahia@bu.edu.sa

Asian Journal of Chemistry, Vol. 28 No. 12 (2016): Vol 28 Issue 12
Article Published : September 2, 2016

Abstract

The gas-phase deoxygenation of propionic acid was investigated in the presence of Co-Mo catalysts in N₂ or H₂ flow at 200-400 °C. In the presence of N₂, the main product was 3-pentanone with other deoxygenates and some light gases e.g., ethane and ethene. Using H₂ flow, the catalyst was active for decarboxylation and decarbonylation of acid and the yields of ethane and ethene. The decarboxylation and decarbonylation reactions increased with increasing temperature. Cobalt-molybdenum supported on alumina showed better performance than bulk catalyst, especially at 400 °C in the presence of N₂ for the ketonization of propionic acid to form 3-pentanone as the main product. Bulk and supported catalysts were characterized by surface area porosity (BET), thermogravimetric analysis and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) of pyridine adsorption.

Keywords

Deoxygenation Propionic acid Gas-phase Cobalt-molybdenum catalyst

Bayahia, H. (2016). Deoxygenation of Propionic Acid in Gas Phase over Cobalt Molybdenum Catalyst. Asian Journal of Chemistry, 28(12), 2745–2748. https://doi.org/10.14233/ajchem.2016.20107

Download Citation

References

A. Corma, S. Iborra and A. Velty, Chem. Rev., 107, 2411 (2007); doi:10.1021/cr050989d.
E.L. Kunkes, D.A. Simonetti, R.M. West, J.C. Serrano-Ruiz, C.A. Gartner and J.A. Dumesic, Science, 322, 417 (2008); doi:10.1126/science.1159210.
H. Bayahia, E. Kozhevnikova and I. Kozhevnikov, Chem. Commun., 49, 3842 (2013); doi:10.1039/c3cc41161c.
H. Bayahia, E. Kozhevnikova and I. Kozhevnikov, Appl. Catal. B, 165, 253 (2015); doi:10.1016/j.apcatb.2014.10.028.
P.T. Do, M. Chiappero, L.L. Lobban and D. Resasco, Catal. Lett., 130, 9 (2009); doi:10.1007/s10562-009-9900-7.
M. Arend, T. Nonnen, W.F. Hoelderich, J. Fischer and J. Groos, Appl. Catal. A, 399, 198 (2011); doi:10.1016/j.apcata.2011.04.004.
H. Bernas, K. Eränen, I. Simakova, A.-R. Leino, K. Kordás, J. Myllyoja, P. Mäki-Arvela, T. Salmi and D.Y. Murzin, Fuel, 89, 2033 (2010); doi:10.1016/j.fuel.2009.11.006.
J.G. Immer, M.J. Kelly and H.H. Lamb, Appl. Catal. A, 375, 134 (2010); doi:10.1016/j.apcata.2009.12.028.
M. Arend, T. Nonnen, W.F. Hoelderich, J. Fischer and J. Groos, Appl. Catal. A, 399, 198 (2011); doi:10.1016/j.apcata.2011.04.004.
M.A. Alotaibi, E.F. Kozhevnikova and I.V. Kozhevnikov, Appl. Catal. A, 447, 32 (2013).
G. Ertl, H. Knozinger, F. Schüth and J. Weitkamp, Handbook of Heterogeneous Catalysis, Wiley-VCH, edn 2, vol. 8 (2008).
X.-H. Wang, M.-H. Zhang, W. Li and K.-Y. Tao, Catal. Today, 131, 111 (2008); doi:10.1016/j.cattod.2007.10.070.
Y. Wang, J. Huang, X. Xia and X. Peng, J. Saudi Chem. Soc., (2016); doi:10.1016/j.jscs.2016.01.006.
R. Kojima and K. Aika, Appl. Catal. A, 215, 149 (2001); doi:10.1016/S0926-860X(01)00529-4.
A.M. de Jong, V.H.J.S. de Beer, J.A.R. van Veen and J.W.H. Niemantsverdriet, J. Phys. Chem., 100, 17722 (1996); doi:10.1021/jp962207d.
J.H. Ashley and P.C.H. Mitchell, J. Chem. Soc. A, 2821 (1968); doi:10.1039/J19680002821.
L. Cedeño, D. Hernandez, T. Klimova and J. Ramirez, Appl. Catal. A, 241, 39 (2003); doi:10.1016/S0926-860X(02)00429-5.
M. de Boer, E.P. Koch, R.J. Blaauw, E.R. Stobbe, A.N.J.M. Hoffmann, L.A. Boot, A.J. van Dillen and J.W. Geus, Solid State Ion., 63-65, 736 (1993); doi:10.1016/0167-2738(93)90188-9.
F F. Al-Wadaani, E.F. Kozhevnikova and I.V. Kozhevnikov, Appl. Catal. A, 363, 153 (2009); doi:10.1016/j.apcata.2009.05.010.
A.M. Alsalme, P.V. Wiper, Y.Z. Khimyak, E.F. Kozhevnikova and I.V. Kozhevnikov, J. Catal., 276, 181 (2010); doi:10.1016/j.jcat.2010.09.014.
F. Al-Wadaani, E.F. Kozhevnikova and I.V. Kozhevnikov, J. Catal., 257, 199 (2008); doi:10.1016/j.jcat.2008.04.025.
A. Aouissi, A.W. Apblett, Z.A. Al-Othman and A. Al-Amro, Transition Met. Chem., 35, 927 (2010); doi:10.1007/s11243-010-9413-7.
C.S. Song, C.S. Hsu and I. Mochida, Chemistry for Diesel, Applied Energy Technology series, p. 140 (2000).

References

A. Corma, S. Iborra and A. Velty, Chem. Rev., 107, 2411 (2007); doi:10.1021/cr050989d.

E.L. Kunkes, D.A. Simonetti, R.M. West, J.C. Serrano-Ruiz, C.A. Gartner and J.A. Dumesic, Science, 322, 417 (2008); doi:10.1126/science.1159210.

H. Bayahia, E. Kozhevnikova and I. Kozhevnikov, Chem. Commun., 49, 3842 (2013); doi:10.1039/c3cc41161c.

H. Bayahia, E. Kozhevnikova and I. Kozhevnikov, Appl. Catal. B, 165, 253 (2015); doi:10.1016/j.apcatb.2014.10.028.

P.T. Do, M. Chiappero, L.L. Lobban and D. Resasco, Catal. Lett., 130, 9 (2009); doi:10.1007/s10562-009-9900-7.

M. Arend, T. Nonnen, W.F. Hoelderich, J. Fischer and J. Groos, Appl. Catal. A, 399, 198 (2011); doi:10.1016/j.apcata.2011.04.004.

H. Bernas, K. Eränen, I. Simakova, A.-R. Leino, K. Kordás, J. Myllyoja, P. Mäki-Arvela, T. Salmi and D.Y. Murzin, Fuel, 89, 2033 (2010); doi:10.1016/j.fuel.2009.11.006.

J.G. Immer, M.J. Kelly and H.H. Lamb, Appl. Catal. A, 375, 134 (2010); doi:10.1016/j.apcata.2009.12.028.

M. Arend, T. Nonnen, W.F. Hoelderich, J. Fischer and J. Groos, Appl. Catal. A, 399, 198 (2011); doi:10.1016/j.apcata.2011.04.004.

M.A. Alotaibi, E.F. Kozhevnikova and I.V. Kozhevnikov, Appl. Catal. A, 447, 32 (2013).

G. Ertl, H. Knozinger, F. Schüth and J. Weitkamp, Handbook of Heterogeneous Catalysis, Wiley-VCH, edn 2, vol. 8 (2008).

X.-H. Wang, M.-H. Zhang, W. Li and K.-Y. Tao, Catal. Today, 131, 111 (2008); doi:10.1016/j.cattod.2007.10.070.

Y. Wang, J. Huang, X. Xia and X. Peng, J. Saudi Chem. Soc., (2016); doi:10.1016/j.jscs.2016.01.006.

R. Kojima and K. Aika, Appl. Catal. A, 215, 149 (2001); doi:10.1016/S0926-860X(01)00529-4.

A.M. de Jong, V.H.J.S. de Beer, J.A.R. van Veen and J.W.H. Niemantsverdriet, J. Phys. Chem., 100, 17722 (1996); doi:10.1021/jp962207d.

J.H. Ashley and P.C.H. Mitchell, J. Chem. Soc. A, 2821 (1968); doi:10.1039/J19680002821.

L. Cedeño, D. Hernandez, T. Klimova and J. Ramirez, Appl. Catal. A, 241, 39 (2003); doi:10.1016/S0926-860X(02)00429-5.

M. de Boer, E.P. Koch, R.J. Blaauw, E.R. Stobbe, A.N.J.M. Hoffmann, L.A. Boot, A.J. van Dillen and J.W. Geus, Solid State Ion., 63-65, 736 (1993); doi:10.1016/0167-2738(93)90188-9.

F F. Al-Wadaani, E.F. Kozhevnikova and I.V. Kozhevnikov, Appl. Catal. A, 363, 153 (2009); doi:10.1016/j.apcata.2009.05.010.

A.M. Alsalme, P.V. Wiper, Y.Z. Khimyak, E.F. Kozhevnikova and I.V. Kozhevnikov, J. Catal., 276, 181 (2010); doi:10.1016/j.jcat.2010.09.014.

F. Al-Wadaani, E.F. Kozhevnikova and I.V. Kozhevnikov, J. Catal., 257, 199 (2008); doi:10.1016/j.jcat.2008.04.025.

A. Aouissi, A.W. Apblett, Z.A. Al-Othman and A. Al-Amro, Transition Met. Chem., 35, 927 (2010); doi:10.1007/s11243-010-9413-7.

C.S. Song, C.S. Hsu and I. Mochida, Chemistry for Diesel, Applied Energy Technology series, p. 140 (2000).

Issue

Vol. 28 No. 12 (2016): Vol 28 Issue 12

Deoxygenation of Propionic Acid in Gas Phase over Cobalt Molybdenum Catalyst

Corresponding Author(s) : Hossein Bayahia

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents