Spectroscopic, Structural and Solution Studies of New Tl(I) Complex with 3-Nitrobenzylidene-4-aminobenzoic Acid
Asian Journal of Chemistry,
Vol. 23 No. 5 (2011): Vol 23 Issue 5
Abstract
A new thallium(I) complex with a Schiff base ligand, [Tl(L)](1) [L– = 3-nitrobenzylidene-4-aminobenzoic acid], has been synthesized and characterized. The carboxylic groups of the ligand 3-nitrobenzylidene-4-aminobenzoic acid in the new Tl(I) complex is chelated via oxygen atom of acidic group. The formation and stoichiometry of the Tl+-L complex in DMF solution was investigated by spectrophotometric and conductometric method. The UV spectra of Tl(I) compelex shows that the thallium-oxygen bonds have considerable covalent character.
Keywords
Thallium(I)
Schiff base
Slow evaporation
Solution chemistry
Conductivity.
Rahimi*, R., & Esk, M. (2011). Spectroscopic, Structural and Solution Studies of New Tl(I) Complex with 3-Nitrobenzylidene-4-aminobenzoic Acid. Asian Journal of Chemistry, 23(5), 1929–1931. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10377
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