Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(&mu;-S)3(CuNCS)3] and 4,4'-Bipyridine

Zhenhong Wei*; Li Long

Issue

Vol. 23 No. 5 (2011): Vol 23 Issue 5

Issue Published : 13 January 2011

Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(μ-S)3(CuNCS)3] and 4,4'-Bipyridine

Zhenhong Wei*

Department of Chemistry, Nanchang University, Nanchang 330031, P.R. China *Corresponding author: Tel: +86 791 3969254; E-mail: weizh@ncu.edu.cn

Li Long

Department of Chemistry, Nanchang University, Nanchang 330031, P.R. China *Corresponding author: Tel: +86 791 3969254; E-mail: weizh@ncu.edu.cn

Asian Journal of Chemistry, Vol. 23 No. 5 (2011): Vol 23 Issue 5
Article Published : 25 January 2011

Abstract

A cluster-based 3D polymer {[WO(μ-S)₃Cu₃(NCS)(4,4'-bipy)2.5]·2.5(aniline)}n (1) was isolated by reactions of [Et₄N]₂[WO(μ-S)₃(CuNCS)₃] with bidentate nitrogen donor ligand 4,4'-bipy in an aniline solution. Compound 1 contains a 3-fold interpenetrated network in which each incomplete cubane-like [WO(μ-S)₃Cu₃] core acts as a tetrahedral four-connecting node to interconnect four other equivalent ones via single and double 4,4'-bipy bridges.

Keywords

Crystal structure 4 4'-Bipyridine W/Cu/S cluster Three-fold interpenetration Supramolecular cluster.

(1)

Wei*, Z.; Long, L. Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(Μ-S)3(CuNCS)3] and 4,4’-Bipyridine. ajc 2011, 23, 2134-2136.

Issue

Vol. 23 No. 5 (2011): Vol 23 Issue 5

Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(μ-S)3(CuNCS)3] and 4,4'-Bipyridine

Abstract

Keywords

Full Article

Download Citation

Table Of Contents