Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(μ-S)3(CuNCS)3] and 4,4'-Bipyridine
Asian Journal of Chemistry,
Vol. 23 No. 5 (2011): Vol 23 Issue 5
Abstract
A cluster-based 3D polymer {[WO(μ-S)3Cu3(NCS)(4,4'-bipy)2.5]·2.5(aniline)}n (1) was isolated by reactions of [Et4N]2[WO(μ-S)3(CuNCS)3] with bidentate nitrogen donor ligand 4,4'-bipy in an aniline solution. Compound 1 contains a 3-fold interpenetrated network in which each incomplete cubane-like [WO(μ-S)3Cu3] core acts as a tetrahedral four-connecting node to interconnect four other equivalent ones via single and double 4,4'-bipy bridges.
Keywords
Crystal structure
4
4'-Bipyridine
W/Cu/S cluster
Three-fold interpenetration
Supramolecular cluster.
Wei*, Z., & Long, L. (2011). Synthesis and Crystal Structure of a 3-Fold Interpenetrated Supramolecular Cluster Based on The Incomplete Cubane-Like Precursor [Et4N]2[WO(μ-S)3(CuNCS)3] and 4,4’-Bipyridine. Asian Journal of Chemistry, 23(5), 2134–2136. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10367
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