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Vol. 23 No. 5 (2011): Vol 23 Issue 5

Synthesis and Crystal Structure of Nickel Complex Assembled from Pyridine-Carboxylate Ligand

Min Yang1
1College of Chemical Engineering, Qingdao University of Science & Technology, Shandong 266042, P.R. China 2Department of Chemistry, Dezhou University, Shandong 253023, P.R. China *Corresponding author: E-mail: zhubaoyong@yahoo.cn
Xiuling Zhang1
1College of Chemical Engineering, Qingdao University of Science & Technology, Shandong 266042, P.R. China 2Department of Chemistry, Dezhou University, Shandong 253023, P.R. China *Corresponding author: E-mail: zhubaoyong@yahoo.cn
Baoyong Zhu2
1College of Chemical Engineering, Qingdao University of Science & Technology, Shandong 266042, P.R. China 2Department of Chemistry, Dezhou University, Shandong 253023, P.R. China *Corresponding author: E-mail: zhubaoyong@yahoo.cn

Asian Journal of Chemistry, Vol. 23 No. 5 (2011): Vol 23 Issue 5

Abstract

The pyridine carboxylato-bridged coordination polymer [Ni(3,3-pbc)2(H2O)2]n (3,3-pbc=3-pyrid-3-ylbenzoic acid) has been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single crystal X-ray analyses reveal that the carboxylate groups of 3,3-pbc ligand adopt one coordinated mode: bis-monodentate (μ2-h1:h1) and bidentate chelating (μ1-h1:h1) fashion. Hydrogen bonding interactions are found in compound which further extend and stabilize the coordination motifs.

Keywords

Coordination polymer Hydrothermal synthesis Crystal structure Pyridine-carboxylate ligand.
Yang1, M., Zhang1, X., & Zhu2, B. (2011). Synthesis and Crystal Structure of Nickel Complex Assembled from Pyridine-Carboxylate Ligand. Asian Journal of Chemistry, 23(5), 2131–2133. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10366
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