Synthesis and Structure of Iron(III) Complex with N,N,O-Donor Aroylhydrazones: The Chloride Anion as Hydrogen Bond Acceptor Forming Infinite Chains
Asian Journal of Chemistry,
Vol. 23 No. 5 (2011): Vol 23 Issue 5
Abstract
A new iron(III) complex, [FeL2](Cl)·(CH3OH)0.5 with acyclic tridentate 5-bromo-salicylaldehyde-6-chloro-2-pyridyl hydrazone (HL) has been synthesized and structurally characterized. The crystal structure consists of chains of alternating [FeL2]+ cations and Cl– anions, linked together by N–H···Cl–···H–N hydrogen bonds. Two tridentate monoanionic meridionally spanning ligands form a distorted octahedral N4O2 coordination sphere around the metal ion.
Keywords
Synthesis
Structure
Iron(III)
Complex
Aroylhydrazones.
Liu*, H., Gao, F., & Niu, D. (2011). Synthesis and Structure of Iron(III) Complex with N,N,O-Donor Aroylhydrazones: The Chloride Anion as Hydrogen Bond Acceptor Forming Infinite Chains. Asian Journal of Chemistry, 23(5), 2014–2016. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10361
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