Synthesis of 2-(t-Butyl)dimethyl-silyloxy-2-cyclopropyl- 1-ethyl-triphenylphosphonium iodide and Its Crystal Structure

Wei Wang1; Yong-Miao Shen2

Issue

Vol. 23 No. 5 (2011): Vol 23 Issue 5

Issue Published : January 13, 2011

Synthesis of 2-(t-Butyl)dimethyl-silyloxy-2-cyclopropyl- 1-ethyl-triphenylphosphonium iodide and Its Crystal Structure

Wei Wang1

1Yancheng Institute of Technology, School of Chemical and Biological Engineering, Yancheng 224003, P.R. China 2Department of Chemistry & Chemical Engineering, Shaoxing University, Shaoxing 312000, P.R. China *Corresponding author: Tel/Fax: +86 575 88345682; E-mail: shenyongmiao@usx.edu.cn

Yong-Miao Shen2

Asian Journal of Chemistry, Vol. 23 No. 5 (2011): Vol 23 Issue 5
Article Published : January 30, 2011

Abstract

Compound of 2-(

t-butyl)dimethyl-silyloxy-2-cyclopropyl-1-ethyl-triphenylphosphonium iodide (C29H38IOPSi) has been synthesized through1/n with unit cell parameters:a = 90º, b = 95.5280(10) º, g = 90º, v = 3009.56(7) Å3, z = 4, Dc = 1.299 Mg/m3,-1. The final R and wR are 0.0444 and 0.1178, respectively for 5312 observed reflectionss(I).

five steps and the structure was determined by X-ray diffraction. The crystal is monoclinic, space group P2

a = 13.6074(2) Å, b = 13.0416(2) Å, c = 17.0381(2) Å.

Mr = 588.55, F(000) = 1208 and μ = 1.175 mm

with I > 2

Keywords

Calcipotriol Triphenylphosphine Bromoacetylcyclopropane Crystal structure.

Wang1, W., & Shen2, Y.-M. (2011). Synthesis of 2-(t-Butyl)dimethyl-silyloxy-2-cyclopropyl- 1-ethyl-triphenylphosphonium iodide and Its Crystal Structure. Asian Journal of Chemistry, 23(5), 2227–2228. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/10336

Issue

Vol. 23 No. 5 (2011): Vol 23 Issue 5

Synthesis of 2-(t-Butyl)dimethyl-silyloxy-2-cyclopropyl- 1-ethyl-triphenylphosphonium iodide and Its Crystal Structure

Abstract

Keywords

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