Synthesis of 1,5-Benzodiazepines Catalyzed by Zinc Triflate in Solvent-Free Medium
Corresponding Author(s) : P. Leelavathi
rameshteja_2001@yahoo.co.in
Asian Journal of Chemistry,
Vol. 23 No. 4 (2011): Vol 23 Issue 4
Abstract
The o-phenylenediamines were smoothly reacted with different ketones to afford the corresponding 1,5-benzodiazepine derivatives in excellent yields. All the reactions were carried out in presence of air and moisture stable zinc triflate (10 % mol) catalyst in solvent-free medium at room temperature.
Keywords
Benzodiazepine
o-Phenylenediamines
Zinc triflate
Ketones
(1)
Ramesh Kumar, S.; Venkateshwarulu, Y.; Leelavathi, P. Synthesis of 1,5-Benzodiazepines Catalyzed by Zinc Triflate in Solvent-Free Medium. ajc 2010, 23, 1611-1614.
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