Copyright (c) 2025 KOFFI PIERRE DIT ADAMA N'GORAN, Naminata Sangare, Kakou Charles Kinimo, N’guessan Louis Berenger Kouassi, Lemeyonouin Aliou Guillaume Pohan, Donourou Diabate, Koffi Marcellin Yao, Albert Trokourey

This work is licensed under a Creative Commons Attribution 4.0 International License.
Sustainable Fabrication of Magnetic Biochar from Corncob Waste for Efficient Removal of Indigo Carmine from Textile Effluent
Corresponding Author(s) : Koffi Pierre Dit Adama N’goran
Asian Journal of Chemistry,
Vol. 37 No. 12 (2025): Vol 37 Issue 12, 2025
Abstract
This work aimed to remove indigo carmine from water using an iron oxide–corncob biochar (α-Fe2O3-C) composite synthesized hydrothermally and characterized by SEM, XRD, FTIR and TGA techniques. The composite averaging 20.63 nm, contained carboxylic, hydroxyl, phenolic and alcoholic groups. Adsorption analysis showed higher efficiencies for α-Fe2O3-C than for raw biochar in both aqueous solutions (88.58-96.66% versus 71.94-79.93%) and real effluent (48.01-61.90% versus 31.74-43.66%). The Langmuir model best described adsorption on biochar, while the Freundlich model fitted the best for the magnetic based biochar composite. Maximum capacities (Qmax) were 4.76 mg/g (biochar) and 12.72 mg/g (α-Fe2O3-C). Overall, the composite significantly improved indigo carmine removal and shows potential for treating dye-contaminated industrial effluents.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- M. Ismail, K. Akhtar, M.I. Khan, T. Kamal, M.A. Khan, A. M. Asiri, J. Seo and S.B. Khan, Curr. Pharm. Des., 25, 3645 (2019); https://doi.org/10.2174/1381612825666191021142026
- R. Al-Tohamy, S.S. Ali, F. Li, K.M. Okasha, Y.A.-G. Mahmoud, T. Elsamahy, H. Jiao, Y. Fu and J. Sun, Ecotoxicol. Environ. Saf., 231, 113160 (2022); https://doi.org/10.1016/j.ecoenv.2021.113160
- T.S. Algarni and A.M. Al-Mohaimeed, J. King Saud Univ. Sci., 34, 102339 (2022); https://doi.org/10.1016/j.jksus.2022.102339
- M.F. Chowdhury, S. Khandaker, F. Sarker, A. Islam, T.M. Rahman and M.R. Awual, J. Mol. Liq., 318, 114061 (2020); https://doi.org/10.1016/j.molliq.2020.114061
- A.N. Babu, D.S. Reddy, P. Sharma, G.S. Kumar, K. Ravindhranath and G.V.K. Mohan, Mater. Today Proc., 17, 198 (2019); https://doi.org/10.1016/j.matpr.2019.06.419
- S. Ben Salah, M. Missaoui, A. Attia, G. Lesage, M. Heran and R. Ben Amar, Front. Membr. Sci. Technol., 3, 1348992. (2024); https://doi.org/10.3389/frmst.2024.1348992
- S.N. Eroi, A.S. Ello, D. Diabaté and D.B. Ossonon, S. Afr. J. Chem. Eng., 3, 53 (2021); https://doi.org/10.1016/j.sajce.2021.03.009
- S. Somma, E. Reverchon and L. Baldino, ChemEngineering, 5, 47 (2021); https://doi.org/10.3390/chemengineering5030047
- M. Munoz, J. Nieto-Sandoval, S. Álvarez-Torrellas, E. Sanz-Santos, B. Calderón, Z.M. de Pedro, M. Larriba, A. Fullana, J. García and J.A. Casas, Sep. Purif. Technol., 257, 117974 (2021); https://doi.org/10.1016/j.seppur.2020.117974
- J. Ku, K. Wang, Q. Wang and Z. Lei, Separations, 11, 130 (2024); https://doi.org/10.3390/separations11050130
- N. Ghosh, S. Sen, G. Biswas, A. Saxena and P.K. Haldar, Water Air Soil Pollut., 234, 202 (2023); https://doi.org/10.1007/s11270-023-06217-8
- I. Ashraf, N.B. Singh and A. Agarwal, Mater. Today Proc., 72, 311 (2023); https://doi.org/10.1016/j.matpr.2022.07.404
- S. Bhukal, A. Sharma, Rishi, Divya, S. Kumar, B. Deepak, K. Pal and S. Mona, Top. Catal., 65, 1675 (2022); https://doi.org/10.1007/s11244-022-01640-3
- L.M. Mahlaule-Glory, S. Mapetla, A. Makofane, M.M. Mathipa and N.C. Hintsho-Mbita, Heliyon, 8, e10536 (2022); https://doi.org/10.1016/j.heliyon.2022.e10536
- M. Haris, A. Zavabeti, M.W. Khan, B.J. Murdoch, J. Paz-Ferreiro, N. Mahmood and N. Eshtiaghi, J. Environ. Chem. Eng., 10, 108968 (2022); https://doi.org/10.1016/j.jece.2022.108968
- Y. Qiu, X. Xu, Z. Xu, J. Liang, Y. Yu and X. Cao, Chem. Eng. J., 389, 124471 (2020); https://doi.org/10.1016/j.cej.2020.124471
- J. Xie, R. Lin, Z. Liang, Z. Zhao, C. Yang and F. Cui, J. Environ. Chem. Eng., 9, 105744 (2021); https://doi.org/10.1016/j.jece.2021.105744
- O.I. Ali, E.R. Zaki, M.S. Abdalla and S.M. Ahmed, Environ. Sci. Pollut. Res. Int., 30, 53548 (2023); https://doi.org/10.1007/s11356-023-26000-w
- Y. Zhou, S. Cao, C. Xi, X. Li, L. Zhang, G. Wang and Z. Chen, Bioresour. Technol., 292, 121951 (2019); https://doi.org/10.1016/j.biortech.2019.121951
- Y. Kanchanaroek, T. Rattanakaew, P. Kako, O. Meangbua and W. Doungjun, Sustain. Environ. Res., 35, 23 (2025); https://doi.org/10.1186/s42834-025-00261-1
- R.P. Na Talang, W. Na Sorn, S. Polruang and S. Sirivithayapakorn, Sci. Rep., 14, 14372 (2024); https://doi.org/10.1038/s41598-024-65389-3
- K.N. Aboua, Y.A. Yobouet, K.B. Yao, D.L. Goné and A. Trokourey, J. Environ. Manage., 156, 10 (2015); https://doi.org/10.1016/j.jenvman.2015.03.006
- U.Y. Kouakou, A. Dembélé, A.Y. Yobouet and A. Trokourey, Int. J. Adv. Res. Sci. Eng. Technol., 3, 2573 (2016).
- P.H.K. Ouattara, M.I. Gouli, U. Kouakou, A. Dembélé, J.Y. Aboua and A. Trokourey, Int. J. Sci. Res., 3, 933 (2014).
- K.P.A. N’goran, D. Diabaté, K.M. Yao, N.L.B. Kouassi, U.P. Gnonsoro, K.C. Kinimo and A. Trokourey, Arab. J. Geosci., 11, 498 (2018); https://doi.org/10.1007/s12517-018-3862-2
- A.F. Kokora, L.D. Kouadio, D.B. Soro, K.R. N’guettia, A. Dembélé and K.S. Traoré, Rev. Ivoir. Sci. Technol., 31, 39 (2018).
- N.L.B. Kouassi, K.P.D.A. N’goran, L.D. Blonde, D. Diabate and T. Albert, Chem. Afr., 6, 733 (2023); https://doi.org/10.1007/s42250-022-00432-2
- Y. Ma, M. Li, P. Li, L. Yang, L. Wu, F. Gao, X. Qi and Z. Zhang, Bioresour. Technol., 319, 124199 (2021); https://doi.org/10.1016/j.biortech.2020.124199
- S. Lagergren, K. Sven. Vetensk. Akad. Handl., 24, 1 (1898).
- Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); https://doi.org/10.1016/S0032-9592(98)00112-5
- S.A. Dhar, T.U. Sakib and L.N. Hilary, Biomass Convers. Biorefin., 12, 2631 (2022); https://doi.org/10.1007/s13399-020-01116-y
- J. Fito, M. Abewaa and T. Nkambule, Appl. Water Sci., 13, 78 (2023); https://doi.org/10.1007/s13201-023-01880-y
- T.D. Piluk, G. Faccio, S. Letsiou, R. Liang and M. Freire-Gormaly, Environ. Sci. Nano, 11, 3674 (2024); https://doi.org/10.1039/D4EN00489B
- V. Ranjithkumar, S. Sangeetha and S. Vairam, J. Hazard. Mater., 273, 127 (2014); https://doi.org/10.1016/j.jhazmat.2014.03.034
- J. Xu, Y. Liu, J. He, R. Zhang, B. Zuo, and X. Wang, Soft Matter, 10, 8992 (2014); https://doi.org/10.1039/C4SM01743A
- D. Flores-Cano, N.R. Checca-Huaman, I.L. Castro-Merino, C.N. Pinotti, E.C. Passamani, J.F. Litterst and J.A. Ramos-Guivar, Int. J. Mol. Sci., 23, 8279 (2022); https://doi.org/10.3390/ijms23158279
- J.A.A. Abdullah, L. Salah Eddine, B. Abderrhmane, M. Alonso-González, A. Guerrero and A. Romero, Sustain. Chem. Pharm., 17, 100280 (2020); https://doi.org/10.1016/j.scp.2020.100280
- D. Bhatia, D. Datta, A. Joshi, S. Gupta and Y. Gote, J. Mol. Liq., 276, 163 (2019); https://doi.org/10.1016/j.molliq.2018.11.127
- M. Jain, M. Yadav, T. Kohout, M. Lahtinen, V.K. Garg and M. Sillanpää, Water Resour. Ind., 20, 54 (2018); https://doi.org/10.1016/j.wri.2018.10.001
- Y. Xiong, F. Ye, C. Zhang, S. Shen, L. Su and S. Zhao, RSC Adv., 5, 5164 (2015); https://doi.org/10.1039/C4RA12468E
- E.R. Monazam, R.W. Breault and R. Siriwardane, Chem. Eng. J., 242, 204 (2014); https://doi.org/10.1016/j.cej.2013.12.040
- M. Jayashree, M. Parthibavarman and S. Prabhakaran, Ionics, 25, 3309 (2019); https://doi.org/10.1007/s11581-019-02859-z
- H. Liang, C. Zhu, S. Ji, P. Kannan and F. Chen, Biochar, 4, 3 (2022); https://doi.org/10.1007/s42773-021-00130-1
- A.A. Oyekanmi, K.K. Katibi, R.C. Omar, A. Ahmad, M. Elbidi, M.B. Alshammari and H.G. Shitu, Appl. Water Sci., 14, 13 (2024); https://doi.org/10.1007/s13201-023-02060-8
- M. El-Kammah, E. Elkhatib, S. Gouveia, C. Cameselle and E. Aboukil, Environ. Technol. Innov., 28, 102 (2022); https://doi.org/10.1016/j.eti.2022.102713
- R.K. do Nascimento, B.S. Damasceno, A.N. de Melo, P.H.M. de Farias, J.V.F.L. Cavalcanti, D.C.S. Sales, E.H.L. Falcão and A.C.V. de Araújo, Cellulose, 30, 2483 (2023); https://doi.org/10.1007/s10570-022-04978-9
- A.N. Odogu, D. Kouotou, L.P. Keilah, A.T. Godwin, N.R. Lekene, J.N. Nsami and J.M. Ketcha, Arab. J. Chem., 13, pp5241 (2020); https://doi.org/10.1016/j.arabjc.2020.03.002
- G. Davies and J. McGregor, ACS Omega, 6, 33000 (2021); https://doi.org/10.1021/acsomega.1c05116
- R. Paz, H. Viltres, N.K. Gupta and C. Leyva, J. Mol. Liq., 337, 116578 (2021); https://doi.org/10.1016/j.molliq.2021.116578
- P. Sirajudheen, P. Karthikeyan, P. Ramkumar, P. Nisheetha and S. Meenakshi, J. Mol. Liq., 327, 114829 (2021); https://doi.org/10.1016/j.molliq.2020.114829
- D. Channei, K. Chansaenpak, P. Jannoey, W. Khanitchaidecha, H. Sintuya, A. Nakarukg and S. Phanichphant, Desalination Water Treat., 225, 340 (2021).
- S. Hashemian and M. Hidarian, Orient. J. Chem., 30, 1753 (2014); https://doi.org/10.13005/ojc/300434
References
M. Ismail, K. Akhtar, M.I. Khan, T. Kamal, M.A. Khan, A. M. Asiri, J. Seo and S.B. Khan, Curr. Pharm. Des., 25, 3645 (2019); https://doi.org/10.2174/1381612825666191021142026
R. Al-Tohamy, S.S. Ali, F. Li, K.M. Okasha, Y.A.-G. Mahmoud, T. Elsamahy, H. Jiao, Y. Fu and J. Sun, Ecotoxicol. Environ. Saf., 231, 113160 (2022); https://doi.org/10.1016/j.ecoenv.2021.113160
T.S. Algarni and A.M. Al-Mohaimeed, J. King Saud Univ. Sci., 34, 102339 (2022); https://doi.org/10.1016/j.jksus.2022.102339
M.F. Chowdhury, S. Khandaker, F. Sarker, A. Islam, T.M. Rahman and M.R. Awual, J. Mol. Liq., 318, 114061 (2020); https://doi.org/10.1016/j.molliq.2020.114061
A.N. Babu, D.S. Reddy, P. Sharma, G.S. Kumar, K. Ravindhranath and G.V.K. Mohan, Mater. Today Proc., 17, 198 (2019); https://doi.org/10.1016/j.matpr.2019.06.419
S. Ben Salah, M. Missaoui, A. Attia, G. Lesage, M. Heran and R. Ben Amar, Front. Membr. Sci. Technol., 3, 1348992. (2024); https://doi.org/10.3389/frmst.2024.1348992
S.N. Eroi, A.S. Ello, D. Diabaté and D.B. Ossonon, S. Afr. J. Chem. Eng., 3, 53 (2021); https://doi.org/10.1016/j.sajce.2021.03.009
S. Somma, E. Reverchon and L. Baldino, ChemEngineering, 5, 47 (2021); https://doi.org/10.3390/chemengineering5030047
M. Munoz, J. Nieto-Sandoval, S. Álvarez-Torrellas, E. Sanz-Santos, B. Calderón, Z.M. de Pedro, M. Larriba, A. Fullana, J. García and J.A. Casas, Sep. Purif. Technol., 257, 117974 (2021); https://doi.org/10.1016/j.seppur.2020.117974
J. Ku, K. Wang, Q. Wang and Z. Lei, Separations, 11, 130 (2024); https://doi.org/10.3390/separations11050130
N. Ghosh, S. Sen, G. Biswas, A. Saxena and P.K. Haldar, Water Air Soil Pollut., 234, 202 (2023); https://doi.org/10.1007/s11270-023-06217-8
I. Ashraf, N.B. Singh and A. Agarwal, Mater. Today Proc., 72, 311 (2023); https://doi.org/10.1016/j.matpr.2022.07.404
S. Bhukal, A. Sharma, Rishi, Divya, S. Kumar, B. Deepak, K. Pal and S. Mona, Top. Catal., 65, 1675 (2022); https://doi.org/10.1007/s11244-022-01640-3
L.M. Mahlaule-Glory, S. Mapetla, A. Makofane, M.M. Mathipa and N.C. Hintsho-Mbita, Heliyon, 8, e10536 (2022); https://doi.org/10.1016/j.heliyon.2022.e10536
M. Haris, A. Zavabeti, M.W. Khan, B.J. Murdoch, J. Paz-Ferreiro, N. Mahmood and N. Eshtiaghi, J. Environ. Chem. Eng., 10, 108968 (2022); https://doi.org/10.1016/j.jece.2022.108968
Y. Qiu, X. Xu, Z. Xu, J. Liang, Y. Yu and X. Cao, Chem. Eng. J., 389, 124471 (2020); https://doi.org/10.1016/j.cej.2020.124471
J. Xie, R. Lin, Z. Liang, Z. Zhao, C. Yang and F. Cui, J. Environ. Chem. Eng., 9, 105744 (2021); https://doi.org/10.1016/j.jece.2021.105744
O.I. Ali, E.R. Zaki, M.S. Abdalla and S.M. Ahmed, Environ. Sci. Pollut. Res. Int., 30, 53548 (2023); https://doi.org/10.1007/s11356-023-26000-w
Y. Zhou, S. Cao, C. Xi, X. Li, L. Zhang, G. Wang and Z. Chen, Bioresour. Technol., 292, 121951 (2019); https://doi.org/10.1016/j.biortech.2019.121951
Y. Kanchanaroek, T. Rattanakaew, P. Kako, O. Meangbua and W. Doungjun, Sustain. Environ. Res., 35, 23 (2025); https://doi.org/10.1186/s42834-025-00261-1
R.P. Na Talang, W. Na Sorn, S. Polruang and S. Sirivithayapakorn, Sci. Rep., 14, 14372 (2024); https://doi.org/10.1038/s41598-024-65389-3
K.N. Aboua, Y.A. Yobouet, K.B. Yao, D.L. Goné and A. Trokourey, J. Environ. Manage., 156, 10 (2015); https://doi.org/10.1016/j.jenvman.2015.03.006
U.Y. Kouakou, A. Dembélé, A.Y. Yobouet and A. Trokourey, Int. J. Adv. Res. Sci. Eng. Technol., 3, 2573 (2016).
P.H.K. Ouattara, M.I. Gouli, U. Kouakou, A. Dembélé, J.Y. Aboua and A. Trokourey, Int. J. Sci. Res., 3, 933 (2014).
K.P.A. N’goran, D. Diabaté, K.M. Yao, N.L.B. Kouassi, U.P. Gnonsoro, K.C. Kinimo and A. Trokourey, Arab. J. Geosci., 11, 498 (2018); https://doi.org/10.1007/s12517-018-3862-2
A.F. Kokora, L.D. Kouadio, D.B. Soro, K.R. N’guettia, A. Dembélé and K.S. Traoré, Rev. Ivoir. Sci. Technol., 31, 39 (2018).
N.L.B. Kouassi, K.P.D.A. N’goran, L.D. Blonde, D. Diabate and T. Albert, Chem. Afr., 6, 733 (2023); https://doi.org/10.1007/s42250-022-00432-2
Y. Ma, M. Li, P. Li, L. Yang, L. Wu, F. Gao, X. Qi and Z. Zhang, Bioresour. Technol., 319, 124199 (2021); https://doi.org/10.1016/j.biortech.2020.124199
S. Lagergren, K. Sven. Vetensk. Akad. Handl., 24, 1 (1898).
Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999); https://doi.org/10.1016/S0032-9592(98)00112-5
S.A. Dhar, T.U. Sakib and L.N. Hilary, Biomass Convers. Biorefin., 12, 2631 (2022); https://doi.org/10.1007/s13399-020-01116-y
J. Fito, M. Abewaa and T. Nkambule, Appl. Water Sci., 13, 78 (2023); https://doi.org/10.1007/s13201-023-01880-y
T.D. Piluk, G. Faccio, S. Letsiou, R. Liang and M. Freire-Gormaly, Environ. Sci. Nano, 11, 3674 (2024); https://doi.org/10.1039/D4EN00489B
V. Ranjithkumar, S. Sangeetha and S. Vairam, J. Hazard. Mater., 273, 127 (2014); https://doi.org/10.1016/j.jhazmat.2014.03.034
J. Xu, Y. Liu, J. He, R. Zhang, B. Zuo, and X. Wang, Soft Matter, 10, 8992 (2014); https://doi.org/10.1039/C4SM01743A
D. Flores-Cano, N.R. Checca-Huaman, I.L. Castro-Merino, C.N. Pinotti, E.C. Passamani, J.F. Litterst and J.A. Ramos-Guivar, Int. J. Mol. Sci., 23, 8279 (2022); https://doi.org/10.3390/ijms23158279
J.A.A. Abdullah, L. Salah Eddine, B. Abderrhmane, M. Alonso-González, A. Guerrero and A. Romero, Sustain. Chem. Pharm., 17, 100280 (2020); https://doi.org/10.1016/j.scp.2020.100280
D. Bhatia, D. Datta, A. Joshi, S. Gupta and Y. Gote, J. Mol. Liq., 276, 163 (2019); https://doi.org/10.1016/j.molliq.2018.11.127
M. Jain, M. Yadav, T. Kohout, M. Lahtinen, V.K. Garg and M. Sillanpää, Water Resour. Ind., 20, 54 (2018); https://doi.org/10.1016/j.wri.2018.10.001
Y. Xiong, F. Ye, C. Zhang, S. Shen, L. Su and S. Zhao, RSC Adv., 5, 5164 (2015); https://doi.org/10.1039/C4RA12468E
E.R. Monazam, R.W. Breault and R. Siriwardane, Chem. Eng. J., 242, 204 (2014); https://doi.org/10.1016/j.cej.2013.12.040
M. Jayashree, M. Parthibavarman and S. Prabhakaran, Ionics, 25, 3309 (2019); https://doi.org/10.1007/s11581-019-02859-z
H. Liang, C. Zhu, S. Ji, P. Kannan and F. Chen, Biochar, 4, 3 (2022); https://doi.org/10.1007/s42773-021-00130-1
A.A. Oyekanmi, K.K. Katibi, R.C. Omar, A. Ahmad, M. Elbidi, M.B. Alshammari and H.G. Shitu, Appl. Water Sci., 14, 13 (2024); https://doi.org/10.1007/s13201-023-02060-8
M. El-Kammah, E. Elkhatib, S. Gouveia, C. Cameselle and E. Aboukil, Environ. Technol. Innov., 28, 102 (2022); https://doi.org/10.1016/j.eti.2022.102713
R.K. do Nascimento, B.S. Damasceno, A.N. de Melo, P.H.M. de Farias, J.V.F.L. Cavalcanti, D.C.S. Sales, E.H.L. Falcão and A.C.V. de Araújo, Cellulose, 30, 2483 (2023); https://doi.org/10.1007/s10570-022-04978-9
A.N. Odogu, D. Kouotou, L.P. Keilah, A.T. Godwin, N.R. Lekene, J.N. Nsami and J.M. Ketcha, Arab. J. Chem., 13, pp5241 (2020); https://doi.org/10.1016/j.arabjc.2020.03.002
G. Davies and J. McGregor, ACS Omega, 6, 33000 (2021); https://doi.org/10.1021/acsomega.1c05116
R. Paz, H. Viltres, N.K. Gupta and C. Leyva, J. Mol. Liq., 337, 116578 (2021); https://doi.org/10.1016/j.molliq.2021.116578
P. Sirajudheen, P. Karthikeyan, P. Ramkumar, P. Nisheetha and S. Meenakshi, J. Mol. Liq., 327, 114829 (2021); https://doi.org/10.1016/j.molliq.2020.114829
D. Channei, K. Chansaenpak, P. Jannoey, W. Khanitchaidecha, H. Sintuya, A. Nakarukg and S. Phanichphant, Desalination Water Treat., 225, 340 (2021).
S. Hashemian and M. Hidarian, Orient. J. Chem., 30, 1753 (2014); https://doi.org/10.13005/ojc/300434