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Vol. 37 No. 1 (2025): Vol 37 Issue 1, 2025

Copyright (c) 2024 Chandana Pramanik

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A Novel Phenolate-Thiadiazolyl Based Carbonate Sensor: Design, Synthesis and Characterization

https://doi.org/10.14233/ajchem.2025.33168
Chandana Pramanik
Department of Chemistry, Dinabandhu Andrews College, 54 Raja S.C. Mallick Road, Kolkata-700084, India
https://orcid.org/0009-0005-8780-7492

Corresponding Author(s) : Chandana Pramanik

pramanikc23@gmail.com

Asian Journal of Chemistry, Vol. 37 No. 1 (2025): Vol 37 Issue 1, 2025

Abstract

A highly selective and sensitive phenolate-thiadiazolyl based colorimetric as well as fluorometric chemosensor (E)-2-(((5-(2-chlorophenyl)-1,3,4-thiadiazol-2-yl)imino)methyl)-6-ethoxy phenol (HL) has been designed and synthesized by Schiff base reaction. This probe has been characterized by spectroscopic techniques such as NMR (1H), ESI-MS and IR spectroscopy. This probe, HL can detect selectively carbonate anion in tris-HCl buffer solution (10 mM, pH 7.2, 1:1 v/v) medium by colorimetric and fluorometric method. The limit of detection of the probe towards carbonate is 0.435 µM. The 1:1 stoichiometry of binding of HL and carbonate was supported by ESI-MS spectra, TGA and Job’s plot analysis.

Keywords

Phenolate Thiadiazolyl Schiff base Carbonate Spectroscopy Chemosensor
Pramanik, C. (2024). A Novel Phenolate-Thiadiazolyl Based Carbonate Sensor: Design, Synthesis and Characterization. Asian Journal of Chemistry, 37(1), 229–236. https://doi.org/10.14233/ajchem.2025.33168
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