Main Article Content
Abstract
Nowadays incorporation of few oxygen groups between the layers of graphite have shown potential approach for industrialization of graphene oxide for different potential applications. During the strong oxidation process in modified Hummers method, these oxygen based functional groups may increase the distance, weakening the van der Waals forces and facilitation the exfoliation of graphite layers from. The reduced graphene oxide/copper oxide (rGO-CuO) is highly potentially active and selective catalyst for many environmental applications. Different wt. % of Cu(II) and loaded on rGO surface to form a nanocomposite, which were prepared by hydrothermal method. The influence of hydrothermal temperature, rGO sheet and loaded CuO on structure of graphene was systematically investigated. The structure and optical properties of the obtained hybrid composite was evaluated employing scanning
electron microscope, X-ray diffraction, UV-visible and infrared spectroscopies. The photocatalytic activities of rGO-CuO nanocomposites for the degradation of Eosin B acid red under sunlight were investigated. The results revealed the decrease in percentage photocatalytic degradation rate occurred on rGO-CuO, because a single sheet of rGO can shield the light from reaching the surface of CuO photocatalyst. It is possible to provide a new way to use the host rGO as prepared by hydrothermal method for water remediation applications.
Keywords
Article Details
Copyright (c) 2019 C.C. Vidyasagar, Prakash Kariyajjanavar, Priya Nikkam, Keerti M. Khilari, Veena Mathapati, Megha Madiwalar
This work is licensed under a Creative Commons Attribution 4.0 International License.
References
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References
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K. Ojha, O. Anjaneyulu and A.K. Ganguli, Graphene-Based Hybrid Materials: Synthetic Approaches and Properties, Curr. Sci., 107, 397 (2014).
C.C. Vidyasagar, Y.A. Naik, T.G. Venkatesh and R. Viswanatha, Solid-State Synthesis and Effect of Temperature on Optical Properties of Cu-ZnO, Cu-CdO and CuO Nanoparticles, Powder Technol., 214, 337 (2011); https://doi.org/10.1016/j.powtec.2011.08.025.
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C.C. Vidyasagar, G. Hosamani and P. Kariyajjanavar, One-Pot Micro-wave Synthesis and Effect of Cu2+ Ions on Structural Properties of Cu-ZnO Nano Crystals, Mater. Today Proc., 5, 22171 (2018); https://doi.org/10.1016/j.matpr.2018.06.582.
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E. Murray, S. Sayyar, B.C. Thompson, R. Gorkin III, D.L. Officer and G.G. Wallace, A Bio-friendly, Green Route to Processable, Biocompatible Graphene/Polymer Composites, RSC Adv., 5, 45284 (2015); https://doi.org/10.1039/C5RA07210G.
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C.C. Vidyasagar, Y.A. Naik, T.G. Venkatesha and P. Manjunatha, Sol–Gel Synthesis Using Glacial Acetic Acid and Optical Properties of Anatase Cu–TiO2 Nanoparticles, J. Nanoeng. Nanomanuf., 2, 91 (2012); https://doi.org/10.1166/jnan.2012.1058.
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B. Cao, S. Cao, P. Dong, J. Gao and J. Wang, High Antibacterial Activity of Ultrafine TiO2/Graphene Sheets Nanocomposites under Visible Light Irradiation, Mater. Lett., 93, 349 (2013); https://doi.org/10.1016/j.matlet.2012.11.136.
J. Zhang, Z. Xiong and X.S. Zhao, Graphene–Metal–Oxide Composites for the Degradation of Dyes Under Visible Light Irradiation, J. Mater. Chem., 21, 3634 (2011); https://doi.org/10.1039/c0jm03827j.
A. Chidembo, S.H. Aboutalebi, K. Konstantinov, M. Salari, B. Winton, S.A. Yamini, I.P. Nevirkovets and H.K. Liu, Globular Reduced Graphene Oxide-Metal Oxide Structures for Energy Storage Applications, Energy Environ. Sci., 5, 5236 (2012); https://doi.org/10.1039/C1EE02784K.
L. Richtera, D. Chudobova, M. Kremplova, V. Milosavljevic, P. Kopel, K. Cihalova, I. Blazkova, D. Hynek, V. Adam and R. Kizek, The Composites of Graphene Oxide with Metal or Semimetal Nanoparticles and their Effect on Pathogenic Microorganism, Materials, 8, 2994 (2015); https://doi.org/10.3390/ma8062994.
S. Botta, J. Navìo, M. Hidalgo, G.M. Restrepo and M.I. Litter, Photocatalytic properties of ZrO2 and Fe/ZrO2 semiconductors Prepared by a Sol–Gel Technique, J. Photochem. Photobiol. A Chem., 129, 89 (1999); https://doi.org/10.1016/S1010-6030(99)00150-1.
Y. Hu, J. Jin, P. Wu, H. Zhang and C. Cai, Graphene-Gold Nanostructure Composites Fabricated by Electrodeposition and their Electrocatalytic Activity toward the Oxygen Reduction and Glucose Oxidation, Electrochim. Acta, 56, 491 (2010); https://doi.org/10.1016/j.electacta.2010.09.021.
R. Liu, S. Li, X. Yu, G. Zhang, S. Zhang, J. Yao, B. Keita, L. Nadjo and L. Zhi, Facile Synthesis of Au nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide, Small, 8, 1398 (2012); https://doi.org/10.1002/smll.201102298.
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