Main Article Content

Abstract

Nitrogen-doped activated carbon was synthesized by protein source from biomass soybean. Soybean is a significant and cheap source of protein which is nitrogen base compound. This work is intended to new carbonaceous adsorbents with nitrogen content in the carbon framework that applying CO2 capture. The activated carbon was characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and Fourier-transform infrared spectroscopy. Characterization results show nitrogen and oxygen functional group in activated carbon. This adsorbent has sufficient porosity whit high content of nitrogen (12 % wt.) makes it one of suggestion for COcapture. The experimental value of adsorption modeled by Langmuir adsorption isotherm and good agreement capacity. The synthesized activated carbon demonstrates high CO2 capture with 3.21 mmol/g at 25 ºC and 2 mmol/g at 50 ºC. The results showed that nitrogen doped of carbons can be used as potential adsorbent for CO2 capture.

Keywords

Activated carbon Carbon dioxide Nitrogen Soybean Adsorption

Article Details

References

  1. D. Saha, S.E. Van Bramer, G. Orkoulas, H.-C. Ho, J. Chen and D.K. Henley, CO2 Capture in Lignin-derived and Nitrogen-Doped Hierarchical Porous Carbons, Carbon, 121, 257 (2017); https://doi.org/10.1016/j.carbon.2017.05.088.
  2. L. Wang and R.T. Yang, Significantly Increased CO2 Adsorption Performance of Nanostructured Templated Carbon by Tuning Surface Area and Nitrogen Doping, J. Phys. Chem. C, 116, 1099 (2012); https://doi.org/10.1021/jp2100446.
  3. G. Sethia and A. Sayari, Comprehensive Study of Ultra-Microporous Nitrogen-Doped Activated Carbon for CO2 Capture, Carbon, 93, 68 (2015); https://doi.org/10.1016/j.carbon.2015.05.017.
  4. Y. Ma, C. Ma, J. Sheng, H. Zhang, R. Wang, Z. Xie and J. Shi, Nitrogen-Doped Hierarchical Porous Carbon with High Surface Area Derived from Graphene Oxide/Pitch Oxide Composite for Supercapacitors, J. Colloid Interface Sci., 461, 96 (2016); https://doi.org/10.1016/j.jcis.2015.08.065.
  5. C. Zhang, W. Song, G. Sun, L. Xie, J. Wang, K. Li, C. Sun, H. Liu, C.E. Snape and T. Drage, CO2 Capture with Activated Carbon Grafted by Nitrogenous Functional Groups, Energy Fuels, 27, 4818 (2013); https://doi.org/10.1021/ef400499k.
  6. B. Guo, L. Chang and K. Xie, Adsorption of Carbon Dioxide on Activated Carbon, J. Nat. Gas Chem., 15, 223 (2006);
  7. https://doi.org/10.1016/S1003-9953(06)60030-3.
  8. X.Y. Chen, D.H. Xie, C. Chen and J.W. Liu, High-Performance Super-capacitor Based on Nitrogen-Doped Porous Carbon Derived from Zinc (II)-bis(8-hydroxyquinoline) CoordinationPolymer, J. Colloid Interface Sci., 393, 241 (2013); https://doi.org/10.1016/j.jcis.2012.10.024.
  9. P. Fu, L. Zhou, L. Sun, B. Huang and Y. Yuan, Nitrogen-Doped Porous Activated Carbon Derived from Cocoon Silk as a Highly Efficient Metal-Free Electrocatalyst for the Oxygen Reduction Reaction, RSC Adv., 7, 13383 (2017); https://doi.org/10.1039/C7RA00433H.
  10. M.S. Shafeeyan, W.M.A.W. Daud, A. Houshmand and A. Shamiri, A Review on Surface Modification of Activated Carbon for Carbon Dioxide Adsorption, J. Anal. Appl. Pyrolysis, 89, 143 (2010); https://doi.org/10.1016/j.jaap.2010.07.006.
  11. G.I. Danmaliki and T.A. Saleh, Effects of Bimetallic Ce/Fe Nanoparticles on the Desulfurization of Thiophenes using Activated Carbon, Chem. Eng. J., 307, 914 (2017); https://doi.org/10.1016/j.cej.2016.08.143.
  12. Y. Hou, Y. Cheng, T. Hobson and J. Liu, Design and Synthesis of Hierarchical MnO2 Nanospheres/Carbon Nanotubes/Conducting Polymer Ternary Composite for High Performance Electrochemical Electrodes, Nano Lett., 10, 2727 (2010); https://doi.org/10.1021/nl101723g.
  13. Q. Miao,Y. Tang, J. Xu, X. Liu, L. Xiao and Q. Chen, Activated Carbon Prepared from Soybean Straw for Phenol Adsorption, J. Taiwan Instit. Chem. Eng., 44, 458 (2013); https://doi.org/10.1016/j.jtice.2012.12.006.
  14. M. Montazerolghaem, S.F. Aghamiri, S. Tangestaninejad and M.R. Talaie, A Metal-Organic Framework MIL-101 Doped with Metal Nanoparticles (Ni & Cu) and its Effect on CO2 Adsorption Properties, RSC Adv., 6, 632 (2016); https://doi.org/10.1039/C5RA22450K.
  15. M. Peyravi, Synthesis of Nitrogen Doped Activated Carbon/Polyaniline Material for CO2 Adsorption, Polym. Adv. Technol., 29, 319 (2018); https://doi.org/10.1002/pat.4117.
  16. J. Song, W. Shen, J. Wang and W. Fan, Superior Carbon-Based CO2 Adsorbents Prepared from Poplar anthers, Carbon, 69, 255 (2014); https://doi.org/10.1016/j.carbon.2013.12.024.
  17. C.-G. Lee, H. Hur and M.-B. Song, Oxidation Behavior of Carbon in a Coin-Type Direct Carbon Fuel Cell, J. Electrochem. Soc., 158, B410 (2011); https://doi.org/10.1149/1.3544941.
  18. Y. Zhang, Y. Zhang, J. Huang, D. Du, W. Xing and Z. Yan, Enhanced Capacitive Performance of N-Doped Activated Carbon from Petroleum Coke by Combining Ammoxidation with KOH Activation, Nanoscale Res. Lett., 11, 245 (2016); https://doi.org/10.1186/s11671-016-1460-3.
  19. C. Liu, W. Xing, J. Zhou and S. Zhuo, N-Containing Activated Carbons for CO2 Capture, Int. J. Smart Nano Mater., 4, 55 (2013); https://doi.org/10.1080/19475411.2012.668861.
  20. M. Li and J. Xue, Integrated Synthesis of Nitrogen-Doped Mesoporous Carbon from Melamine Resins with Superior Performance in Super-capacitors, J. Phys. Chem. C, 118, 2507 (2014); https://doi.org/10.1021/jp410198r.