Main Article Content

Abstract

The main objective of this study is to investigate the corrosion inhibition properties of Gardenia aqualla leaf extract on mild steel using weight loss method. The corrosion of mild steel was investigated at different concentrations of G. aqualla and also at different temperatures (303, 313 and 323 K). G. aqualla inhibits the corrosion rate of mild steel from 62.4 mm/yr to 6.5mm/yr, 91.6 mm/yr to 16.6 mm/yr and 113.8 mm/yr to 28.4 mm/yr at 303, 313 and 323 K, respectively, which yielded an optimum result in the values of inhibition efficiency from 63.8 to 89.5 %, 52.5 to 81.9 % and 39 to 75 % for the various temperatures after an interval of 3 days after being in  contact with its respective environment. The Langmuir isotherm confirmed that physisorption occurred. It was found that inhibition occurred through adsorption of constituents present in the leaf of G. aqualla obtained by the phytochemical screening.

Keywords

Adsorption Phytochemical screening Mild steel Corrosion inhibition Gardenia aqualla

Article Details

References

  1. E. Kusmierek and E. Chrzescijanska, Atmospheric Corrosion of Metals in Industrial City Environment, Data Brief, 3, 149 (2015); https://doi.org/10.1016/j.dib.2015.02.017.
  2. Y. Hou, D. Lei, S. Li, W. Yang and C.-Q. Li, Experimental Investigation on Corrosion Effect on Mechanical Properties of Buried Metal Pipes, Int. J. Corros., Article ID 5808372 (2016); https://doi.org/10.1155/2016/5808372.
  3. M. Taghavikish, N.K. Dutta and N.R. Choudhury, Emerging Corrosion Inhibitors for Interfacial Coating, Coatings, 7, 217 (2017); https://doi.org/10.3390/coatings7120217.
  4. S.A. Umoren, Polymers as Corrosion Inhibitors for Metals in Different Media - A Review, The Open Corros. J., 2, 175 (2009); https://doi.org/10.2174/1876503300902010175.
  5. V. Sivakumara, K. Velumania and S. Rameshkumara, Colocid Dye - A Potential Corrosion Inhibitor for the Corrosion of Mild Steel in Acid Media, Mater. Res., 21, e20170167 (2018); https://doi.org/10.1590/1980-5373-MR-2017-0167.
  6. L. Hamadi, S. Mansouri, K. Oulmi and A. Kareche, The Use of Amino Acids as Corrosion Inhibitors for Metals: A Review, Egypt. J. Petrol.; https://doi.org/10.1016/j.ejpe.2018.04.004.
  7. S.K. Shukla and E.E. Ebenso, Corrosion Inhibition, Adsorption Behavior and Thermodynamic Properties of Streptomycin on Mild Steel in Hydrochloric Acid Medium, Int. J. Electrochem. Sci., 6, 3277 (2011).
  8. M. Abdallah, A.Y. El-Etre, M.G. Soliman and E.M. Mabrouk, Some Organic and Inorganic Compounds as Inhibitors for Carbon Steel Corrosion in 3.5 Percent NaCl Solution, Anti-Corros. Methods Mater., 53, 118 (2006); https://doi.org/10.1108/00035590610650820.
  9. A. Bouoidina, M. Chaouch, A. Abdellaoui, A. Lahkimi, B. Hammouti, F. El-Hajjaji, M. Taleb, A. Nahle, Essential oil of Foeniculum vulgare: Antioxidant and Corrosion Inhibitor on Mild Steel Immersed in Hydro-chloric Medium, Anti-Corros. Methods Mater., 64, 563 (2017); https://doi.org/10.1108/ACMM-10-2016-1716.
  10. P.C. Okafor, E.E. Ebenso and U.J. Ekpe, Azadirachta indica Extracts as Corrosion Inhibitor for Mild Steel in Acid Medium, Int. J. Electrochem. Sci., 5, 978 (2010).
  11. D.B. Patil and A.R. Sharma, Study on the Corrosion Kinetics of Iron in Acid and Base Medium, E-J. Chem., 8, S358 (2011); https://doi.org/10.1155/2011/294792.
  12. I.O. Arukalam, I.C. Madufor, O. Ogbobe and I. Oguzie, Experimental and Theoretical Studies of Hydroxyethyl Cellulose as Inhibitor for Acid Corrosion Inhibition of Mild Steel and Aluminium, The Open Corros. J., 6, 1 (2014); https://doi.org/10.2174/1876503301406010001.
  13. N. Lahhit, A. Bouyanzer, J. Desjobert, B. Hammouti and R. Salghi, Fennel (Foeniculum vulgare) Essential Oil as Green Corrosion Inhibitor of Carbon Steel in Hydrochloric Acid Solution, Port. Electrochem. Acta, 29, 127 (2011); https://doi.org/10.4152/pea.201102127.
  14. A.O. Odiongenyi, S.A. Odoemelam and N.O. Eddy, Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia amygdalina for the Corrosion of Mild Steel in H2SO4, Port. Electrochem. Acta, 27, 33 (2009); https://doi.org/10.4152/pea.200901033.
  15. G.M. Al-Senani, Corrosion Inhibition of Carbon Steel in Acidic Chloride Medium by Cucumis sativus (Cucumber) Peel Extract, Int. J. Electrochem. Sci., 11, 291 (2016).
  16. R. Lopes-Sesenes, G.F. Dominguez-Patiño, J.G. Gonzalez-Rodriguez and J. Uruchurtu-Chavarin, Effect of Flowing Conditions on the Corrosion Inhibition of Carbon Steel by Extract of Buddleia perfoliata, Int. J. Electrochem. Sci., 8, 477 (2013).
  17. A. Nithya, P. Shanthy, N. Vijaya, R.J. Rathish, S.S. Prabha, R.M. Joany and S. Rajendran, Inhibition of Corrosion of Aluminium by an Aqueous Extract of Beetroot (Betanin), Int. J. Nano. Corros. Sci. Eng., 2, 1 (2015).