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Abstract
Tin dioxide thin films were prepared by sol-gel dip coating technique using SnCl2·2H2O and ammonium hydroxide solution. The obtained thin film slides have been annealed at different temperature (200, 400 and 600 °C) in air at constant time (90 min). Structure and surface morphology of SnO2 thin films were investigated and characterized by X-ray diffraction, atomic force microscope, scanning electron microscope, UV/visible and FTIR measurements. The optical properties of SnO2 thin film were studied, such as transmittance, extinction coefficient, absorption coefficient and optical energy gap. The X-ray diffraction indicates a decreasing in crystaline size with increasing of doping concentration. The optical energy band gap was increased with the annealing temperature in range of (3.6 to 3.9) eV.
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References
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References
G.Q. Zhong, S.R. Luan, P. Wang, Y.C. Guo, Y.R. Chen and Y.Q. Jia, J. Therm. Anal. Calorim., 86, 775 (2006); https://doi.org/10.1007/s10973-005-6959-2.
Z.P. Zhang, G.Q. Zhong and Q.Y. Jiang, Prog. Chem., 20, 1315 (2008).
D.C. Reis, M.C.X. Pinto, E.M. Souza-Fagundes, L.F. Rocha, V.R.A. Pereira, C.M.L. Melo and H. Beraldo, Biometals, 24, 595 (2011); https://doi.org/10.1007/s10534-011-9407-8.
J.A. Lessa, D.C. Reis, I.C. Mendes, N.L. Speziali, L.F. Rocha, V.R.A. Pereira, C.M.L. Melo and H. Beraldo, Polyhedron, 30, 372 (2011); https://doi.org/10.1016/j.poly.2010.11.004.
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O.S. Urgut, I.I. Ozturk, C.N. Banti, N. Kourkoumelis, M. Manoli, A.J. Tasiopoulos and S.K. Hadjikakou, Inorg. Chim. Acta, 443, 141 (2016); https://doi.org/10.1016/j.ica.2015.12.028.
I.I. Ozturk, O.S. Urgut, C.N. Banti, N. Kourkoumelis, A.M. Owczarzak, M. Kubicki and S.K. Hadjikakou, Polyhedron, 70, 172 (2014); https://doi.org/10.1016/j.poly.2013.12.025.
A. Han, I.I. Ozturk, C.N. Banti, N. Kourkoumelis, M. Manoli, A.J. Tasiopoulos, A.M. Owczarzak, M. Kubicki and S.K. Hadjikakou, Polyhedron, 79, 151 (2014); https://doi.org/10.1016/j.poly.2014.05.014.
D.C. Reis, M.C.X. Pinto, E.M. Souza-Fagundes, S.M. Wardell, J.L. Wardell and H. Beraldo, Eur. J. Med. Chem., 45, 3904 (2010); https://doi.org/10.1016/j.ejmech.2010.05.044.
I.I. Ozturk, C.N. Banti, N. Kourkoumelis, M.J. Manos, A.J. Tasiopoulos, A.M. Owczarzak, M. Kubicki and S.K. Hadjikakou, Polyhedron, 67, 89 (2014); https://doi.org/10.1016/j.poly.2013.08.052.
S. Timári, R. Cerea and K. Várnagy, J. Inorg. Biochem., 105, 1009 (2011); https://doi.org/10.1016/j.jinorgbio.2011.04.007.
V.M. Manikandamathavan, T. Weyhermüller, R.P. Parameswari, M. Sathishkumar, V. Subramanian and B.U. Nair, Dalton Trans., 43, 13018 (2014); https://doi.org/10.1039/C4DT01378F.
G.Q. Zhong, J. Shen, Q.Y. Jiang, Y.Q. Jia, M.J. Chen and Z.P. Zhang, J. Therm. Anal. Calorim., 92, 607 (2008); https://doi.org/10.1007/s10973-007-8579-5.
G.Q. Zhong, J. Shen, Q.Y. Jiang and K.B. Yu, Chin. J. Chem., 29, 2650 (2011); https://doi.org/10.1002/cjoc.201100394.
J. Shen, B. Jin, Q.Y. Jiang, G.Q. Zhong, Y.M. Hu and J.C. Huo, Inorg. Chim. Acta, 385, 158 (2012); https://doi.org/10.1016/j.ica.2012.01.045.
D. Li and G.Q. Zhong, Bioinorg. Chem. Appl., 2014, 461605 (2014); https://doi.org/10.1155/2014/461605.
Y.C. Guo, S.R. Luan, Y.R. Chen, X.S. Zang, Y.Q. Jia, G.Q. Zhong and S.K. Ruan, J. Therm. Anal. Calorim., 68, 1025 (2002); https://doi.org/10.1023/A:1016163111068.
M.S. Refat, G.G. Mohamed, R.F. de Farias, A.K. Powell, M.S. El-Garib, S.A. El-Korashy and M.A. Hussien, J. Therm. Anal. Calorim., 102, 225 (2010); https://doi.org/10.1007/s10973-009-0404-x.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordi-nation Compounds, Wiley & Sons, New York, edn 4 (1986).
B. Xu and B. Yan, Spectrosc. Lett., 39, 237 (2006); https://doi.org/10.1080/00387010600636965.
G.Q. Zhong and Y. Zhang, Asian J. Chem., 25, 8549 (2013); https://doi.org/10.14233/ajchem.2013.14834.