Article Sidebar

Download
PDF

Main Article Content

Abstract

Two metal-organic coordination polymers e.g., Ca2(BTEC)(DMF)(H2O)3 (1) and Ba2(BTEC)(H2O) (2) based on BTEC ligands have been solvothermally synthesized and characterized (DMF = N,Ndimethylformamide, H4BTEC = 1,2,4,5-benzene tetracarboxylate). Compound 1 crystallizes in the chiral space group P-1 and features an 2D 4, 4-connected square grid constructed by calcium-dimmer square  Secondary building units (SBUs) [Ca2(C2O4)4(CO2)2] and 4- connected square BTEC ligand. Compound 2 is a 3D 4, 8-connected framework built from tetrahedron secondary building units [Ba(C2O4)4] and 8-connected cubic BTEC ligand. Moreover, the influences of the starting reagents and synthesis methods on the structures of these two compounds have been studied. Solid state luminescent properties of the two compounds have also been studied.

Keywords

1,2,4,5-Benzene tetracarboxylate Solvothermal synthesis Luminescence properties Metal-organic coordination polymers

Article Details

License

Copyright (c) 2016 Helong Bai, Daojun Zhang, Xuemin Jing, Renchun Zhang, Shuangli Zeng, Yong Fan, Ping Zhang

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

References

  1. D.J. Tranchemontagne, J.L. Mendoza-Cortés, M. O’Keeffe and O.M. Yaghi, Chem. Soc. Rev., 38, 1257 (2009); https://doi.org/10.1039/b817735j.
  2. H. Furukawa, K.E. Cordova, M. O’Keeffe and O.M. Yaghi, Science, 341, 1230444 (2013); https://doi.org/10.1126/science.1230444.
  3. V. Stavila, A.A. Talin and M.D. Allendorf, Chem. Soc. Rev., 43, 5994 (2014); https://doi.org/10.1039/C4CS00096J.
  4. Y. Cui, Y. Yue, D. Qian and B. Chen, Chem. Rev., 112, 1126 (2012); https://doi.org/10.1021/cr200101d.
  5. S. Horike, D. Umeyama and S. Kitagawa, Acc. Chem. Res., 46, 2376 (2013); https://doi.org/10.1021/ar300291s.
  6. P. Ramaswamy, N.E. Wong and G.K.H. Shimizu, Chem. Soc. Rev., 43, 5913 (2014); https://doi.org/10.1039/C4CS00093E.
  7. J.W. Liu, L.F. Chen, H. Cui, J.Y. Zhang, L. Zhang and C.Y. Su, Chem. Soc. Rev., 43, 6011 (2014); https://doi.org/10.1039/C4CS00094C.
  8. Z.C. Hu, B.J. Deibert and J. Li, Chem. Soc. Rev., 43, 5815 (2014); https://doi.org/10.1039/C4CS00010B.
  9. S.L. Li and Q. Xu, Energy Environ. Sci., 6, 1656 (2013); https://doi.org/10.1039/c3ee40507a.
  10. J.D. Rocca, D. Liu and W. Lin, Acc. Chem. Res., 44, 957 (2011); https://doi.org/10.1021/ar200028a.
  11. C.Y. Sun, C. Qin, X.L. Wang and Z.M. Su, Expert Opin. Drug Deliv., 10, 89 (2013); https://doi.org/10.1517/17425247.2013.741583.
  12. Y. Yan, S.H. Yang, A.J. Blake and M. Schröder, Acc. Chem. Res., 47, 296 (2014); https://doi.org/10.1021/ar400049h.
  13. D. Zhao, D.J. Timmons, D.Q. Yuan and H.C. Zhou, Acc. Chem. Res., 44, 123 (2011); https://doi.org/10.1021/ar100112y.
  14. Y.B. He, B. Li, M. O’Keeffe and B. Chen, Chem. Soc. Rev., 43, 5618 (2014); https://doi.org/10.1039/C4CS00041B.
  15. J.Y. Wu, S.L. Yang, T.T. Luo, Y.H. Liu, Y.W. Cheng, Y.F. Chen, Y.S. Wen, L.G. Lin and K.L. Lu, Chemistry, 14, 7136 (2008); https://doi.org/10.1002/chem.200800758.
  16. J.D. Lin, J.W. Cheng and S.W. Du, Cryst. Growth Des., 8, 3345 (2008); https://doi.org/10.1021/cg8002614.
  17. A. Majumder, V. Gramlich, G.M. Rosair, S.R. Batten, J.D. Masuda, M.S. El Fallah, J. Ribas, J.P. Sutter, C. Desplanches and S. Mitra, Cryst. Growth Des., 6, 2355 (2006); https://doi.org/10.1021/cg060337y.
  18. K.L. Lu, Y.F. Chen, Y.H. Liu, Y.W. Cheng, R.T. Liao and Y.S. Wen, Cryst. Growth Des., 5, 403 (2005); https://doi.org/10.1021/cg049908h.
  19. N. Snejko, E. Gutiérrez-Puebla, J.L. Martínez, M.A. Monge and C. Ruiz-Valero, Chem. Mater., 14, 1879 (2002); https://doi.org/10.1021/cm011286p.
  20. J.R. Su, K.L. Yin and D.J. Xu, Chinese J. Struct. Chem., 23, 399 (2004).
  21. K. Barthelet, D. Riou, M. Nogues and G. Férey, Inorg. Chem., 42, 1739 (2003); https://doi.org/10.1021/ic026175m.
  22. Y.H. Wen, Q.W. Zhang, Y.H. He and Y.L. Feng, Inorg. Chem. Commun., 10, 543 (2007); https://doi.org/10.1016/j.inoche.2007.01.004.
  23. Y.H. Wen, J. Zhang, Z.J. Li, Y.Y. Qin, Y. Kang, R.F. Hu, J.K. Cheng and Y.G. Yao, Acta Crystallogr., E60, m535 (2004); https://doi.org/10.1107/S1600536804007779.
  24. Y.M. Dai, X.Q. Wang and J.F. Huang, Acta Crystallogr., E61, m2548 (2005); https://doi.org/10.1107/S1600536805036081.
  25. D.F. Sun, R. Cao, Y.C. Liang, Q. Shi and M.C. Hong, Dalton Trans., 1847 (2002); https://doi.org/10.1039/b109985j.
  26. R. Cao, D.F. Sun, Y.C. Liang, M.C. Hong, K. Tatsumi and Q. Shi, Inorg. Chem., 41, 2087 (2002); https://doi.org/10.1021/ic0110124.
  27. D. Banerjee and J.B. Parise, Cryst. Growth Des., 11, 4704 (2011); https://doi.org/10.1021/cg2008304.
  28. H.K. Liu, T.H. Tsao, Y.T. Zhang and C.H. Lin, CrystEngComm, 11, 1462 (2009); https://doi.org/10.1039/b819559e.
  29. H.K. Liu, T.H. Tsao, C.H. Lin and V. Zima, CrystEngComm, 12, 1044 (2010); https://doi.org/10.1039/B915987H.
  30. S.H. Lo, H.K. Liu, J.X. Zhan, W.C. Lin, C.C. Kao, C.H. Lin and V. Zima, Inorg. Chem. Commun., 14, 1602 (2011); https://doi.org/10.1016/j.inoche.2011.06.017.
  31. D.J. Zhang, T.Y. Song, P. Zhang, J. Shi, Y. Wang, L. Wang, K.R. Ma, W.R. Yin, J. Zhao, Y. Fan and J.N. Xu, Inorg. Chem. Commun., 10, 876 (2007); https://doi.org/10.1016/j.inoche.2007.04.017.
  32. S. Wang, R.C. Zhang, J.J. Wang, L.L. Shen, Y. Zeng and D.J. Zhang, Chem. Res. Chin. Univ., 30, 9 (2014); https://doi.org/10.1007/s40242-014-3414-6.
  33. D.J. Zhang, R.C. Zhang, J.P. Li, W.Z. Qiao and S. Wang, Inorg. Chem. Commun., 35, 307 (2013); https://doi.org/10.1016/j.inoche.2013.07.007.
  34. D.J. Zhang, R.C. Zhang, J.J. Wang, W.Z. Qiao and X.M. Jing, Inorg. Chem. Commun., 32, 47 (2013); https://doi.org/10.1016/j.inoche.2013.03.007.
  35. S.R. Miller, E. Alvarez, L. Fradcourt, T. Devic, S. Wuttke, P.S. Wheatley, N. Steunou, C. Bonhomme, C. Gervais, D. Laurencin, R.E. Morris, A. Vimont, M. Daturi, P. Horcajada and C. Serre, Chem. Commun., 49, 7773 (2013); https://doi.org/10.1039/c3cc41987h.
  36. R.K. Vakiti, B.D. Garabato, N.P. Schieber, M.J. Rucks, Y. Cao, C. Webb, J.B. Maddox, A. Celestian, W.P. Pan and B.B. Yan, Cryst. Growth Des., 12, 3937 (2012); https://doi.org/10.1021/cg3003349.
  37. M.L. Foo, S. Horike, Y. Inubushi and S. Kitagawa, Angew. Chem. Int. Ed., 51, 6107 (2012); https://doi.org/10.1002/anie.201202285.
  38. E. Song, G.Y. Wang, Y.L. Wang, D.M. Kong, Y.J. Wang, Y. Li and W.J. Ruan, Chem. Commun., 50, 11177 (2014); https://doi.org/10.1039/C4CC04272G.
  39. A.X.S. Bruker, SAINT Software Reference Manual, Madison, WI, USA (1998).
  40. G.M. Sheldrick, SADABS, Siemens Area Detector Absorption Corrected Software, University of Göttingen, Germany (1996).
  41. G.M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).