Issue

Vol. 28 No. 8 (2016): Vol 28 Issue 8

Copyright (c) 2016 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Rheology Behaviours of Miscible Amorphous Poly(3-hydroxybutyrate)/Poly(ethylene oxide)/Poly(p-vinylphenol) Blends

https://doi.org/10.14233/ajchem.2016.19812
Q.Q. Jin
College of Chemistry and Materials Science, Huaibei Normal University, Anhui, P.R. China; Collaborative Innovation Center of Advanced Functional Composites, Anhui, P.R. China
Q. Chen
College of Chemistry and Materials Science, Huaibei Normal University, Anhui, P.R. China; Collaborative Innovation Center of Advanced Functional Composites, Anhui, P.R. China
K.X. Wang
College of Chemistry and Materials Science, Huaibei Normal University, Anhui, P.R. China; Collaborative Innovation Center of Advanced Functional Composites, Anhui, P.R. China
G.Z. Ding
College of Chemistry and Materials Science, Huaibei Normal University, Anhui, P.R. China; Collaborative Innovation Center of Advanced Functional Composites, Anhui, P.R. China
J.P. Liu
College of Chemistry and Materials Science, Huaibei Normal University, Anhui, P.R. China; Collaborative Innovation Center of Advanced Functional Composites, Anhui, P.R. China

Corresponding Author(s) : G.Z. Ding

dinggz@chnu.edu.cn

Asian Journal of Chemistry, Vol. 28 No. 8 (2016): Vol 28 Issue 8

Abstract

Much attention has been focused on the development and investigation of polymer blends in previous years. The miscibility and rheology behaviours of poly(3-hydroxybutyrate) (PHB), poly(ethylene oxide) (PEO) and poly(p-vinylphenol) (PVPh) blends are studied in this work. The linear dynamic viscoelasticity of PHB/PEO/PVPh blends with miscible amorphous composition are investigated by the oscillatory shear measurements. It shows that time-temperature superposition principle (TTS) is applicable for blends. The Han plot (log G' vs. log G") is temperature independent, however, the slopes in the terminal region are much less than 2 and become smaller with the addition of poly(ethylene oxide) content. It is considered that this phenomenon might be resulted from the presence of whole hydrogen bonding change (the self-associated interaction and the hydrogen bonding with hydroxyl group, ether group and ester group) in the blends. This conclusion is supported by the Fourier transform infrared spectroscopy analysis.

Keywords

Hydrogen bonding Miscibility PHB/PEO/PVPh blends Rheology behaviours
Jin, Q., Chen, Q., Wang, K., Ding, G., & Liu, J. (2016). Rheology Behaviours of Miscible Amorphous Poly(3-hydroxybutyrate)/Poly(ethylene oxide)/Poly(p-vinylphenol) Blends. Asian Journal of Chemistry, 28(8), 1747–1753. https://doi.org/10.14233/ajchem.2016.19812
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. S. Viswanathan and M.D. Dadmun, Macromolecules, 36, 3196 (2003); doi:10.1021/ma021520c.
  2. H. Xu, S.W. Kuo, J.S. Lee and F.-C. Chang, Macromolecules, 35, 8788 (2002); doi:10.1021/ma0202843.
  3. J.Y. Noh and J. Kim, Polymer (Korea), 24, 886 (2000).
  4. J.Y. Lee and J.Y. Han, Polymer (Korea), 26, 737 (2002).
  5. S.W. Kuo and F.C. Chang, Macromolecules, 34, 7737 (2001); doi:10.1021/ma010820b.
  6. Y. He, B. Zhu and Y. Inoue, Prog. Polym. Sci., 29, 1021 (2004); doi:10.1016/j.progpolymsci.2004.07.002.
  7. W.P. Hsu, J. Appl. Polym. Sci., 83, 1425 (2002); doi:10.1002/app.2303.
  8. J. Dong and Y. Ozaki, Macromolecules, 30, 286 (1997); doi:10.1021/ma9607168.
  9. C.J.T. Landry and D.M. Teegarden, Macromolecules, 24, 4310 (1991); doi:10.1021/ma00015a012.
  10. J.J. Sotele, V. Soldi and A.T. Nunes Pires, Polymer, 38, 1179 (1997); doi:10.1016/S0032-3861(96)00619-2.
  11. H.J. Cai, A. Ait-Kadi and J. Brisson, Polymer, 44, 1481 (2003); doi:10.1016/S0032-3861(03)00019-3.
  12. X.D. Huang, S.H. Goh and S.Y. Lee, Macromol. Chem. Phys., 201, 2660 (2000); doi:10.1002/1521-3935(20001201)201:18<2660::AID-MACP2660>3.0.CO;2-8.
  13. P. Pedrosa, J.A. Pomposo, E. Calahorra and M. Cortazar, Macromolecules, 27, 102 (1994); doi:10.1021/ma00079a016.
  14. P. Gestoso and J. Brisson, Polymer, 44, 2321 (2003); doi:10.1016/S0032-3861(03)00098-3.
  15. S.H. Zhang, P.C. Painter and J. Runt, Macromolecules, 35, 9403 (2002); doi:10.1021/ma0210832.
  16. Z.Y. Yang and C.D. Han, Macromolecules, 41, 2104 (2008); doi:10.1021/ma7025385.
  17. K.L. Ngai and D.J. Plazek, Macromolecules, 23, 4282 (1990); doi:10.1021/ma00221a014.
  18. J.K. Kim, H.H. Lee, H.W. Son and C.D. Han, Macromolecules, 31, 8566 (1998); doi:10.1021/ma980623l.
  19. J.K. Kim and H.W. Son, Polymer, 40, 6789 (1999); doi:10.1016/S0032-3861(99)00030-0.
  20. Y.J. Aoki and T.S. Tanaka, Macromolecules, 32, 8560 (1999); doi:10.1021/ma990281z.
  21. A. Alegria, C. Elizetxea, I. Cendoya and J. Colmenero, Macromolecules, 28, 8819 (1995); doi:10.1021/ma00130a014.
  22. A. Xu, Y.Y. Lao, Q. Zhang, J.L. Li and J.L. Xia, J. Wuhan Univ. (Nat. Sci. Ed.), 25, 938 (2010).
  23. S.H. Park, S.T. Lim, T.K. Shin, H.J. Choi and M.S. Jhon, Polymer, 42, 5737 (2001); doi:10.1016/S0032-3861(01)00071-4.
  24. A.C. Vieira, R.M. Guedes and V. Tita, J. Polym. Eng., 33, 293 (2013); doi:10.1515/polyeng-2012-0150.
  25. M. Avella and E. Martuscelli, Polymer, 29, 1731 (1988); doi:10.1016/0032-3861(88)90384-9.
  26. J.W. You, H.J. Chiu and T.M. Don, Polymer, 44, 4355 (2003); doi:10.1016/S0032-3861(03)00348-3.
  27. Y. Xu, J. Graf, P.C. Painter and M.M. Coleman, Polymer, 32, 3103 (1991); doi:10.1016/0032-3861(91)90129-7.
  28. L.A. Belfiore, C. Qin, E.J. Ueda and A.T.N. Pires, J. Polym. Sci., Polym. Phys. Ed., 31, 409 (1993); doi:10.1002/polb.1993.090310405.
  29. M.M. Coleman, Y. Xu and P.C. Painter, Macromolecules, 27, 127 (1994); doi:10.1021/ma00079a019.
  30. P. Iriondo, J.J. Iruin and M.J. Fernandez-Berridi, Macromolecules, 29, 5605 (1996); doi:10.1021/ma960286l.
  31. P.X. Xing, L.S. Dong, Y. An, Z. Feng, M. Avella and E. Martuscelli, Macromolecules, 30, 2726 (1997); doi:10.1021/ma960615+.
  32. Y. He, J.C. Li, X.T. Shuai and Y.S. Inoue, Macromolecules, 34, 8166 (2001); doi:10.1021/ma010991g.
  33. J.C. Li, Y. He and Y.S. Inoue, J. Polym. Sci., B, Polym. Phys., 40, 2736 (2002); doi:10.1002/polb.10317.
  34. L.H. Guo, H. Sato, T. Hashimoto and Y. Ozaki, Macromolecules, 43, 3897 (2010); doi:10.1021/ma100307m.
  35. S.W. Kuo and W.C. Liu, J. Appl. Polym. Sci., 119, 300 (2011); doi:10.1002/app.32528.
  36. F. Lapointe, M. Pezolet and J. Brisson, Polymer, 48, 5626 (2007); doi:10.1016/j.polymer.2007.07.034.
  37. P. Pedrosa, J.A. Pomposo, E. Calahorra and M. Cortázar, Polymer, 36, 3889 (1995); doi:10.1016/0032-3861(95)99783-Q.
  38. C. Le Menestrel, D.E. Bhagwagar, P.C. Painter, M.M. Coleman and J.F. Graf, Macromolecules, 25, 7101 (1992); doi:10.1021/ma00052a005.
  39. Y.P. Huang, J.F. Kuo and E. Woo, Polym. Int., 51, 55 (2002); doi:10.1002/pi.796.
  40. H.J. Cai, A. Ait-Kadi and J. Brisson, J. Appl. Polym. Sci., 93, 1623 (2004); doi:10.1002/app.20613.
  41. J.D. Ferry, Viscoelastic Properties of Polymers, edn 3, Wiley: New York (1980).
  42. C.D. Han, D.M. Baek and J.K. Kim, Macromolecules, 23, 561 (1990); doi:10.1021/ma00204a032.
  43. C.D. Han, J. Kim and J.K. Kim, Macromolecules, 22, 383 (1989); doi:10.1021/ma00191a071.
  44. J.H. Lin, E.M. Woo and Y.P. Huang, J. Polym. Sci. B, Polym. Phys., 44, 3357 (2006); doi:10.1002/polb.20985.
  45. S.H. Zhang, X. Jin, P.C. Painter and J. Runt, Polymer, 45, 3933 (2004); doi:10.1016/j.polymer.2004.01.081.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0