Copyright (c) 2013 AJC
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Retention Mechanism Based on Linear Solvation Energy Relationships to RP-HPLC: A Review
Corresponding Author(s) : K.H. Row
Asian Journal of Chemistry,
Vol. 25 No. 2 (2013): Vol 25 Issue 2
Abstract
Linear solvation energy relationships (LSERs) have been used to correlate many complex chemical and biochemical properties with small sets of descriptors of molecular structure and chemistry. The interactions between solutes and solid sorbents are important factors. These interactions are governed by the nature and accessibility of the chemical sites at the material's surface. Characteristics, such as mobile phase modifiers and the type of stationary phase, have been established to detect the retention factors. The descriptors' properties can change as the environmental conditions varied. Comparing predicted and experimental retention factors suggests that the linear solvation energy relationships formalism is able to reproduce adequately the experimental retention factors of the solutes studied in different experimental conditions and evaluate retention characteristics.
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- Y. Wang, M. Tian and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 33, 202 (2010).
- C. Horváth, W. Melander and I. Molnár, J. Chromatogr. A, 125, 129 (1976).
- P.W. Carr, L.C. Tan and J.H. Park, J. Chromatogr. A, 724, 1 (1996).
- P.W. Carr, R.M. Doherty, M.J. Kamlet, R.W. Taft, W. Melander and C. Horvath, Anal. Chem., 58, 2674 (1986).
- I.W. Li and P.W. Carr, Anal. Chem., 69, 2202 (1997).
- M.H. Abraham and M. Rosés, J. Phys. Org. Chem., 7, 672 (1994).
- L.C. Tan and P.W. Carr, J. Chromatogr. A, 799, 1 (1998).
- K. Valko, L.R. Snyder and J.L. Glajch, J. Chromatogr. A, 656, 501 (1993).
- C.H. Lochmüller, R. Charles, J.A. Allison and J.B. Steven, J. Chromatogr. A, 656, 3 (1993).
- M. Vitha and P.W. Carr, J. Chromatogr. A, 1126, 143 (2006).
- A.H. Lowrey, C.J. Cramer, J.J. Urban and G.R. Famini, Computers Chem., 19, 209 (1995).
- P.R. Fields, Y. Sun and A.M. Stalcup, J. Chromatogr. A, 1218, 467 (2011).
- B.L. Karger, L.R. Snyder and C. Horvath, An Introduction to Separation Science, Wiley, New York (1972).
- P.W. Carr, Microchem. J., 48, 4 (1993).
- M.J. Kamlet and R.W. Taft, J. Am. Chem. Soc., 98, 377 (1976).
- M.J. Kamlet and R.W. Taft, J. Am. Chem. Soc., 98, 2886 (1976).
- M.J. Kamlet, J.L. Abboud and R.W. Taft, J. Am. Chem. Soc., 99, 6027 (1977).
- M.J. Kamlet, J.L. Abboud and R.W. Taft, J. Org. Chem., 48, 2877 (1983).
- M.J. Kamlet, R.M. Doherty, M.H. Abraham, Y. Marcus and R.W. Taft, J. Phys. Chem., 92, 5244 (1988).
- J. Zheng, S.K. Han and K.H. Row, Bull. Korean Chem. Soc., 26, 629 (2005).
- Y. Polyakova, L.M. Jin and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 29, 533 (2006).
- J. Zheng, Y. Polyakova and K.H. Row, Chromatographia, 64, 129 (2006).
- Y. Polyakova, L.M. Jin and K.H. Row, Bull. Korean Chem. Soc., 27, 211 (2006).
- N. Chen, Y. Zhang, S. Terabe and T. Nakagawa, J. Chromatogr., 678, 327 (1994).
- S. Yang and M.G. Khaledi, Anal. Chem., 67, 499 (1995).
- P.W. Carr, R.M. Doherty, M.J. Kamlet, R.W. Taft, W. Malender and C. Horvath, Anal. Chem., 58, 2674 (1986).
- P.W. Carr, Microchem. J., 48, 4 (1993).
- M.H. Abraham, G.S. Whiting, R.M. Doherty and W.J. Shuely, J. Chem. Soc., Perkin Trans. II, 1451 (1990).
- M.H. Abraham, H.S. Chadha, G.S. Whiting and R.C. Mitchell, J. Pharm. Sci., 83, 1085 (1994).
- M.H. Abraham and J.C. McGowan, Chromatographia, 23, 243 (1987).
- L. Szepesy, J. Sep. Sci., 26, 201 (2003).
- A. Wang and P.W. Carr, J. Chromatogr. A, 965, 3 (2002).
- Y.B. He, J.J. Zhu, L.S. Wang and Z. Zhang, Bull. Environ. Contam. Toxicol., 55, 635 (1995).
- L.C. Tan, P.W. Carr and M.H. Abraham, J. Chromatogr. A, 752, 1 (1996).
- P. Burg, M.H. Abraham and D. Cagniant, Carbon, 41, 867 (2003).
- A. Wang, L.C. Tan and P.W. Carr, J. Chromatogr. A, 848, 21 (1999).
- M. Tian and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 32, 772 (2009).
- M.A. Garcia, M.F. Vitha and M.L. Marina, J. Liq. Chromatogr. Rel. Technol., 23, 873 (2000).
- S. Endo and T.C. Schmidt, Fluid Phase Equilib., 246, 143 (2006).
- M.A. García, M.F. Vitha, J. Sandquist, K. Mulville and M.L. Marina, J. Chromatogr. A, 918, 1 (2001).
- H. Bui, T. Perun, T. Masquelin, T. Castle, J. Dage and M.S. Kuo, J. Chromatogr. A, 1206, 186 (2008).
- M. Vitha and P.W. Carr, J. Chromatogr. A, 1126, 143 (2006).
- J.L. Yeatts, R.E. Baynes, X.R. Xia and J.E. Riviere, J. Chromatogr. A, 1188, 108 (2008).
- Y. Sun, B. Cabovska, C.E. Evans, T.H. Ridgway and A.M. Stalcup, Anal. Bioanal. Chem., 382, 728 (2005).
- D.S. Van Meter, Y. Sun, K.M. Parker and A.M. Stalcup, Anal. Bioanal. Chem., 390, 897 (2008).
- M. Tian and K.H. Row, Bull. Korean Chem. Soc., 29, 979 (2008).
- D. Han and K.H. Row, Asian J. Chem., 22, 2717 (2010).
- J.A. Blackwell and P.W. Carr, J. High Resolut. Chromatogr., 21, 427 (1998).
- Y. Wang, D. Han, M. Tian and K.H. Row, Korean J. Chem. Eng., 26, 812 (2009).
- M. Tian and K.H. Row, Chem. Res. Chin. Univ., 25, 306 (2009).
- T. Zhu, M. Tian and K.H. Row, Chem. Res. Chin. Univ., 26, 532 (2010).
References
Y. Wang, M. Tian and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 33, 202 (2010).
C. Horváth, W. Melander and I. Molnár, J. Chromatogr. A, 125, 129 (1976).
P.W. Carr, L.C. Tan and J.H. Park, J. Chromatogr. A, 724, 1 (1996).
P.W. Carr, R.M. Doherty, M.J. Kamlet, R.W. Taft, W. Melander and C. Horvath, Anal. Chem., 58, 2674 (1986).
I.W. Li and P.W. Carr, Anal. Chem., 69, 2202 (1997).
M.H. Abraham and M. Rosés, J. Phys. Org. Chem., 7, 672 (1994).
L.C. Tan and P.W. Carr, J. Chromatogr. A, 799, 1 (1998).
K. Valko, L.R. Snyder and J.L. Glajch, J. Chromatogr. A, 656, 501 (1993).
C.H. Lochmüller, R. Charles, J.A. Allison and J.B. Steven, J. Chromatogr. A, 656, 3 (1993).
M. Vitha and P.W. Carr, J. Chromatogr. A, 1126, 143 (2006).
A.H. Lowrey, C.J. Cramer, J.J. Urban and G.R. Famini, Computers Chem., 19, 209 (1995).
P.R. Fields, Y. Sun and A.M. Stalcup, J. Chromatogr. A, 1218, 467 (2011).
B.L. Karger, L.R. Snyder and C. Horvath, An Introduction to Separation Science, Wiley, New York (1972).
P.W. Carr, Microchem. J., 48, 4 (1993).
M.J. Kamlet and R.W. Taft, J. Am. Chem. Soc., 98, 377 (1976).
M.J. Kamlet and R.W. Taft, J. Am. Chem. Soc., 98, 2886 (1976).
M.J. Kamlet, J.L. Abboud and R.W. Taft, J. Am. Chem. Soc., 99, 6027 (1977).
M.J. Kamlet, J.L. Abboud and R.W. Taft, J. Org. Chem., 48, 2877 (1983).
M.J. Kamlet, R.M. Doherty, M.H. Abraham, Y. Marcus and R.W. Taft, J. Phys. Chem., 92, 5244 (1988).
J. Zheng, S.K. Han and K.H. Row, Bull. Korean Chem. Soc., 26, 629 (2005).
Y. Polyakova, L.M. Jin and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 29, 533 (2006).
J. Zheng, Y. Polyakova and K.H. Row, Chromatographia, 64, 129 (2006).
Y. Polyakova, L.M. Jin and K.H. Row, Bull. Korean Chem. Soc., 27, 211 (2006).
N. Chen, Y. Zhang, S. Terabe and T. Nakagawa, J. Chromatogr., 678, 327 (1994).
S. Yang and M.G. Khaledi, Anal. Chem., 67, 499 (1995).
P.W. Carr, R.M. Doherty, M.J. Kamlet, R.W. Taft, W. Malender and C. Horvath, Anal. Chem., 58, 2674 (1986).
P.W. Carr, Microchem. J., 48, 4 (1993).
M.H. Abraham, G.S. Whiting, R.M. Doherty and W.J. Shuely, J. Chem. Soc., Perkin Trans. II, 1451 (1990).
M.H. Abraham, H.S. Chadha, G.S. Whiting and R.C. Mitchell, J. Pharm. Sci., 83, 1085 (1994).
M.H. Abraham and J.C. McGowan, Chromatographia, 23, 243 (1987).
L. Szepesy, J. Sep. Sci., 26, 201 (2003).
A. Wang and P.W. Carr, J. Chromatogr. A, 965, 3 (2002).
Y.B. He, J.J. Zhu, L.S. Wang and Z. Zhang, Bull. Environ. Contam. Toxicol., 55, 635 (1995).
L.C. Tan, P.W. Carr and M.H. Abraham, J. Chromatogr. A, 752, 1 (1996).
P. Burg, M.H. Abraham and D. Cagniant, Carbon, 41, 867 (2003).
A. Wang, L.C. Tan and P.W. Carr, J. Chromatogr. A, 848, 21 (1999).
M. Tian and K.H. Row, J. Liq. Chromatogr. Rel. Technol., 32, 772 (2009).
M.A. Garcia, M.F. Vitha and M.L. Marina, J. Liq. Chromatogr. Rel. Technol., 23, 873 (2000).
S. Endo and T.C. Schmidt, Fluid Phase Equilib., 246, 143 (2006).
M.A. García, M.F. Vitha, J. Sandquist, K. Mulville and M.L. Marina, J. Chromatogr. A, 918, 1 (2001).
H. Bui, T. Perun, T. Masquelin, T. Castle, J. Dage and M.S. Kuo, J. Chromatogr. A, 1206, 186 (2008).
M. Vitha and P.W. Carr, J. Chromatogr. A, 1126, 143 (2006).
J.L. Yeatts, R.E. Baynes, X.R. Xia and J.E. Riviere, J. Chromatogr. A, 1188, 108 (2008).
Y. Sun, B. Cabovska, C.E. Evans, T.H. Ridgway and A.M. Stalcup, Anal. Bioanal. Chem., 382, 728 (2005).
D.S. Van Meter, Y. Sun, K.M. Parker and A.M. Stalcup, Anal. Bioanal. Chem., 390, 897 (2008).
M. Tian and K.H. Row, Bull. Korean Chem. Soc., 29, 979 (2008).
D. Han and K.H. Row, Asian J. Chem., 22, 2717 (2010).
J.A. Blackwell and P.W. Carr, J. High Resolut. Chromatogr., 21, 427 (1998).
Y. Wang, D. Han, M. Tian and K.H. Row, Korean J. Chem. Eng., 26, 812 (2009).
M. Tian and K.H. Row, Chem. Res. Chin. Univ., 25, 306 (2009).
T. Zhu, M. Tian and K.H. Row, Chem. Res. Chin. Univ., 26, 532 (2010).