Copyright (c) 2015 AJC
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Study on Hydrothermal Synthesis and Characterization of Ce-Y/SBA-15 Composite Materials
Corresponding Author(s) : Wenyuan Wu
Asian Journal of Chemistry,
Vol. 27 No. 5 (2015): Vol 27 Issue 5
Abstract
Cerium iron was successfully incorporated into an Y/SBA-15 micro-mesoporous molecular sieve via the hydrothermal synthesis method. A series of characterizations were used to characterize the prepared materials such as XRD, N2-adsorption-desorption, SEM-EDS and TEM. The results showed that the prepared composite materials kept the highly ordered mesoporous two-dimension hexagonal structure of SBA-15 and octagonal structure of Y, while the preparation of Ce-Y/SBA-15 composite materials has the advantages of high plentiful cerium iron (2.30 % wt). In the prepared Ce-Y/SBA-15, the frameworks were kept intact, their structures were still kept high ordered and the cerium iron locates inside the pores of Y/SBA-15.
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References
F.J. Shiring, R. Venkatadri and J.G. Goodwin Jr, Can. J. Chem. Eng., 61, 218 (1983); doi:10.1002/cjce.5450610212.
L.P. Liu, G. Xiong, X.S. Wang, J. Cai and Z. Zhao, Micropor. Mesopor. Mater., 123, 221 (2009); doi:10.1016/j.micromeso.2009.04.004.
Y.H. Ma, H.L. Zhao, S.J. Tang, J. Hu and H.-L. Liu, Acta Phys. Chim. Sin., 27, 689 (2011); doi:10.3866/PKU.WHXB20110335.
Z.Y. Feng, X.W. Huang, H.J. Liu, M. Wang, Z.Q. Long, Y. Yu and C. Wang, J. Rare Earths, 30, 903 (2012); doi:10.1016/S1002-0721(12)60152-5.
W.Y. Wu and X. Bian, The Technology of Rare Earths Metallurgy, Science Press, Beijing (2012).
X.H. Vu, N. Steinfeldt, U. Armbruster and A. Martin, Micropor. Mesopor. Mater., 164, 120 (2012); doi:10.1016/j.micromeso.2012.05.036.
Y.-Y. Li, B. Yan, L. Guo and Y.-J. Li, Micropor. Mesopor. Mater., 148, 73 (2012); doi:10.1016/j.micromeso.2011.07.020.
P. Shah, A.V. Ramaswamy, K. Lazar and V. Ramaswamy, Appl. Catal. A, 273, 239 (2004); doi:10.1016/j.apcata.2004.06.039.
O. Olkhovyk, S. Pikus and M. Jaroniec, J. Mater. Chem., 15, 1517 (2005); doi:10.1039/b500058k.
Y.P. Zheng, S.R. Wang, Z.R. Wang, L.W. Wu and Y.M. Sun, J. Rare Earths, 28, 92 (2010); doi:10.1016/S1002-0721(09)60058-2.
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D.Q. Wang, F.M. Sun and P.F. Jia, Refining Technol. Eng., 43, 45 (2013).
D.Y. Zhao, J.L. Feng, Q.S. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); doi:10.1126/science.279.5350.548.