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Vol. 35 No. 7 (2023): Vol 35 Issue 7 (2023)

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Gas Chromatographic Technique Employed for Catalytic Investigation of Novel Phthalocyanines

https://doi.org/10.14233/ajchem.2023.27961
T.M. Sharanakumar
Department of Chemistry, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India
https://orcid.org/0000-0002-6427-9130
A. Sunilkumar
Department of Physics, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India
https://orcid.org/0000-0002-3996-8313
M.N. Somashekar
Department of Chemistry, S.S. Margol Degree College of Arts, Science and Commerce, Shahabad Rural-585228, India
https://orcid.org/0000-0002-9882-2920
B. Chethan
Department of Physics, Indian Institute of Science, Bengaluru-560012, India
https://orcid.org/0000-0002-8280-252X
T. Naveen Kumar
Department of PG Chemistry, Surana College (Autonomous Institute), Bangalore-560004, India
https://orcid.org/0000-0002-0722-8636
C.R. Ravikumar
Research Centre, Department of Chemistry, East-West Institute of Technology (Affiliated to Visvesvaraya Technological University) Bangalore-560091, India
https://orcid.org/0000-0002-4692-444X

Corresponding Author(s) : C.R. Ravikumar

ravicr128@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 7 (2023): Vol 35 Issue 7 (2023)

Abstract

The primaquine substituted Fe(II) phthalocyanine (PQFePc) and Co(II) phthalocyanine (PQCoPc) catalysts were prepared by using amide linkage method. The physical and chemical properties have been investigated by FTIR, mass, UV-Vis, TGA, XRD and elemental analysis. The catalytic oxidation of benzyl alcohol was determined by PQFePc and PQCoPc complexes by varying parameters like temperature, oxidant/catalytic ratio and substance/catalyst ratio. The optimization of catalytic oxidation reaction has been effectively achieved for the determination of benzyl alcohol (Bzalc) to benzaldehyde (Bzald). The PQCoPc and PQFePc exhibited excellent catalytic behaviour for the oxidation of benzyl alcohol obtaining high yield and good selectivity.

Keywords

Primaquine Catalytic oxidation Benzyl alcohol Phthalocyanines
Sharanakumar, T., Sunilkumar, A., Somashekar, M., Chethan, B., Kumar, T. N., & Ravikumar, C. (2023). Gas Chromatographic Technique Employed for Catalytic Investigation of Novel Phthalocyanines. Asian Journal of Chemistry, 35(7), 1719–1726. https://doi.org/10.14233/ajchem.2023.27961
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