Copyright (c) 2014 B. Ninwong1, W. Dungchai2
This work is licensed under a Creative Commons Attribution 4.0 International License.
Determination of Fe(II) in Drinking Water by Paper-Based Microfluidic Devices with Colorimetric Sensing
Corresponding Author(s) : B. Ninwong1
Asian Journal of Chemistry,
Vol 26 No Supplementary Issue
Abstract
A colorimetric method has been developed for determination of Fe(II) by paper-based microfluidic devices (μPADs). The analytical device is easily constructed using wax-printing on filter paper with was indicated that hydrophobic zone. Fe(II) was detected by the reaction of Fe(II) and 1,10-phenanthroline which the red/orange ferroin complex [Fe(phen)3]2+ was formed. Under the optimum conditions, the linear range between the color intensity and the concentration were found to be 0.1-3.5 and 3.5-15 mg L-1, but with a different slope. The limits of detection were obtained at the concentrations as low as 0.07 mg L-1. The proposed method can be successfully applied to the determination of Fe(II) in drinking water sample. The recoveries were in the range 86.60-109.80 %. The present procedure provides rapid, sensitive and selective for detection of Fe(II), minimal reagent consumption, low cost, thus it is suitable for on-site environmental monitoring.
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- A. Baysal, N. Ozbek and S. Akman, in eds.: F.S. Garciìa Einschlag and L. Carlos, Determination of Trace Metals in Waste Water and Their Removal Processes, In: Waste Water-Treatment Technologies and Recent Analytical Developments, Intech, Ch. 7 (2013).
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- R.K. Katarina, N. Lenghor and S. Motomizu, Anal. Sci., 23, 343 (2007).
- K. Abe, K. Suzuki and D. Citterio, Anal. Chem., 80, 6928 (2008).
- W. Dungchai, O. Chailapakul and C.S. Henry, Anal. Chem., 81, 5821 (2009).
- A.W. Martinez, S.T. Phillips, G.M. Whitesides and E. Carrilho, Anal. Chem., 82, 3 (2010).
- Y. Lu, W. Shi, J. Qin and B. Lin, Anal. Chem., 82, 329 (2010).
- X. Li, J. Tian, G. Garnier and W. Shen, Colloids Surf. B, 76, 564 (2010).
- D.D. Liana, B. Raguse, J.J. Gooding and E. Chow, Sensors, 12, 11505 (2012).
- A. Apilux, W. Siangproh, N. Praphairaksit and O. Chailapakul, Talanta, 97, 388 (2012).
- M.M. Mentele, J. Cunningham, K. Koehler, J. Volckens and C.S. Henry, Anal. Chem., 84, 4474 (2012).
- N. Ratnarathorn, O. Chailapakul, C.S. Henry and W. Dungchai, Talanta, 99, 552 (2012).
- C.R.T. Tarley, V.S. Santos, B.E.L. Baeta, A.C. Pereira and L.T. Kubota, J. Hazard. Mater., 169, 256 (2009).
- W.W. Brandt, F.P. Dwyer and E.D. Gyarfas, Chem. Rev., 54, 959 (1954).
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References
A. Baysal, N. Ozbek and S. Akman, in eds.: F.S. Garciìa Einschlag and L. Carlos, Determination of Trace Metals in Waste Water and Their Removal Processes, In: Waste Water-Treatment Technologies and Recent Analytical Developments, Intech, Ch. 7 (2013).
World Health Organization, Guidelines for Drinking-Water Quality, Health Criteria and Other Supporting Information, Geneva, edn. 2, vol. 2 (1996).
V.K. Gupta, I. Ali and H.Y. Aboul-Enein, Develop. Environ. Sci., 5, 33 (2007).
K.S. Rao, T. Balaji, T.P. Rao, Y. Babu and G.R.K. Naidu, Spectrochim. Acta, B At. Spectrosc., 57, 1333 (2002).
A.W. Martinez, S.T. Phillips, E. Carrilho, S.W. Thomas, H. Sindi and G.M. Whitesides, Anal. Chem., 80, 3699 (2008).
X. Li, J. Tian, T. Nguyen and W. Shen, Anal. Chem., 80, 9131 (2008).
A. Economou and A. Voulgaropoulos, Talanta, 71, 758 (2007).
R.K. Katarina, N. Lenghor and S. Motomizu, Anal. Sci., 23, 343 (2007).
K. Abe, K. Suzuki and D. Citterio, Anal. Chem., 80, 6928 (2008).
W. Dungchai, O. Chailapakul and C.S. Henry, Anal. Chem., 81, 5821 (2009).
A.W. Martinez, S.T. Phillips, G.M. Whitesides and E. Carrilho, Anal. Chem., 82, 3 (2010).
Y. Lu, W. Shi, J. Qin and B. Lin, Anal. Chem., 82, 329 (2010).
X. Li, J. Tian, G. Garnier and W. Shen, Colloids Surf. B, 76, 564 (2010).
D.D. Liana, B. Raguse, J.J. Gooding and E. Chow, Sensors, 12, 11505 (2012).
A. Apilux, W. Siangproh, N. Praphairaksit and O. Chailapakul, Talanta, 97, 388 (2012).
M.M. Mentele, J. Cunningham, K. Koehler, J. Volckens and C.S. Henry, Anal. Chem., 84, 4474 (2012).
N. Ratnarathorn, O. Chailapakul, C.S. Henry and W. Dungchai, Talanta, 99, 552 (2012).
C.R.T. Tarley, V.S. Santos, B.E.L. Baeta, A.C. Pereira and L.T. Kubota, J. Hazard. Mater., 169, 256 (2009).
W.W. Brandt, F.P. Dwyer and E.D. Gyarfas, Chem. Rev., 54, 959 (1954).
W. Dungchai, O. Chailapakul and C.S. Henry, Anal. Chim. Acta, 674, 227 (2010).