Issue

Vol. 35 No. 5 (2023): Vol 35 Issue 5, 2023

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Electrochemical, Morphological, Computational and Corrosion Inhibition Studies of 3-(5-Naphthalen-2-yl-[1,3,4]oxadiazol-2-yl)-pyridine against Mild Steel in 1 M HCl

https://doi.org/10.14233/ajchem.2023.27711
Deepak Sharma
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
https://orcid.org/0000-0002-7233-6959
Abhinay Thakur
Department of Chemistry, School of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara-144402, India
https://orcid.org/0000-0002-7186-1639
Manish Kumar Sharma
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
https://orcid.org/0000-0002-2843-8966
Kranti Jakhar
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
https://orcid.org/0000-0001-7991-8348
Ashish Kumar
Department of Science and Technology, Nalanda College of Engineering, Nalanda-803101, India
https://orcid.org/0000-0002-2003-6209
Ashok Kumar Sharma
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
https://orcid.org/0000-0002-5898-9523
Hari Om
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
https://orcid.org/0000-0002-7026-148X

Corresponding Author(s) : Ashok Kumar Sharma

draksharma.chem@dcrustm.org

Asian Journal of Chemistry, Vol. 35 No. 5 (2023): Vol 35 Issue 5, 2023

Abstract

1,3,4-Oxadiazole derivative, namely, 3-(5-naphthalen-2-yl-[1,3,4]oxadiazol-2-yl)pyridine (NOP) as a corrosion inhibitor against mild steel in 1M HCl has been evaluated using the weight-loss technique (303-323 K), electrochemical analysis [potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS)], as well as surface morphology investigations (SEM). Additionally the computational studies such as density functional theory (DFT), the synthesized molecule (NOP) were utilized to better insight into molecular structure and electronic aspects relating to the anti-corrosion activities of the examined inhibitors and to envisage the interaction between designed inhibitors with the mild steel surface. The synthesized molecule (NOP) expressed high inhibition efficiency of 88.62% at an optimal concentration of 500 ppm at 298 K. A mixed-type inhibition mechanism is suggested by potentiodynamic polarization (PDP) analysis. The DFT calculations complement well with the experimental outcomes. This article provides in-depth insights to comprehend the mild steel inhibitor interactions mode and can be very helpful in accentuating the approach to mitigate the metal dissolution occurring in acidic corrosive media.

Keywords

Corrosion Mild steel 1,3,4-Oxadiazole derivatives Synthesis Adsorption Electrochemical impedance spectroscopy
Sharma, D., Thakur, A., Sharma, M. K., Jakhar, K., Kumar, A., Sharma, A. K., & Om, H. (2023). Synthesis, Electrochemical, Morphological, Computational and Corrosion Inhibition Studies of 3-(5-Naphthalen-2-yl-[1,3,4]oxadiazol-2-yl)-pyridine against Mild Steel in 1 M HCl. Asian Journal of Chemistry, 35(5), 1079–1088. https://doi.org/10.14233/ajchem.2023.27711
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. A.S. Algaber, E.M. El-Nemma and M.M. Saleh, Mater. Chem. Phys., 86, 26 (2004); https://doi.org/10.1016/j.matchemphys.2004.01.040
  2. S.K. Mandal, Steel Metallurgy: Properties, Specifications and Applications, McGraw-Hill Education (2015).
  3. I. Nadi, M. Bouanis, F. Benhiba, K. Nohair, A. Nyassi, A. Zarrouk, C. Jama and F. Bentiss, J. Mol. Liq., 342, 116958 (2021); https://doi.org/10.1016/j.molliq.2021.116958
  4. D. Dwivedi, K. Lepková and T. Becker, RSC Adv., 7, 4580 (2017); https://doi.org/10.1039/C6RA25094G
  5. K. Wan, P. Feng, B. Hou and Y. Li, RSC Adv., 6, 77515 (2016); https://doi.org/10.1039/C6RA12975G
  6. F. Bentiss, M. Lagrenee, M. Traisnel, B. Mernari and H. Elattari, J. Appl. Electrochem., 29, 1073 (1999); https://doi.org/10.1023/A:1003421111890
  7. T.Y. Soror, H.A.E. Dahan and N.G.E. Sayed Ammer, J. Mater. Sci. Technol., 15, 559 (1999).
  8. F.E.-T. Heakal and A.E. Elkholy, J. Mol. Liq., 230, 395 (2017); https://doi.org/10.1016/j.molliq.2017.01.047
  9. R. Ammal P, A. R Prasad, R. K, S. John and A. Joseph, J. Adhes. Sci. Technol., 33, 2227 (2019); https://doi.org/10.1080/01694243.2019.1637169
  10. M. Aliofkhazraei, Developments in Corrosion Protection, pp. 710, Intech Open (2014).
  11. S. Hooshmand Zaferani, M. Sharifi, D. Zaarei and M.R. Shishesaz, J. Environ. Chem. Eng., 1, 652 (2013); https://doi.org/10.1016/j.jece.2013.09.019
  12. B.N. Popov, Corrosion Engineering: Principles and Solved Problems Book, Elsevier (2015).
  13. J.K. Bangia, M. Singh, H. Om, K. Behera and M. Gulia, J. Mol. Liq., 225, 758 (2017); https://doi.org/10.1016/j.molliq.2016.11.002
  14. N. Kumari, M. Singh, H. Om, K.M. Sachin and M. Pal, J. Mol. Liq., 288, 111043 (2019); https://doi.org/10.1016/j.molliq.2019.111043
  15. N. Kumari, M. Singh, H. Om, K.M. Sachin and D. Sharma, J. Mol. Liq., 305, 112744 (2020); https://doi.org/10.1016/j.molliq.2020.112744
  16. A.A. Rahim, E. Rocca, J. Steinmetz, M.J. Kassim, R. Adnan and M.S. Ibrahim, Corros. Sci., 49, 402 (2007); https://doi.org/10.1016/j.corsci.2006.04.013
  17. W. Li, Q. He, C. Pei and B. Hou, Electrochim. Acta, 52, 6386 (2007); https://doi.org/10.1016/j.electacta.2007.04.077
  18. F. Bentiss, M. Traisnel, H. Vezin and M. Lagrenée, Corros. Sci., 45, 371 (2003); https://doi.org/10.1016/S0010-938X(02)00102-6
  19. M. Lagrenée, B. Mernari, N. Chaibi, M. Traisnel, H. Vezin and F. Bentiss, Corros. Sci., 43, 951 (2001); https://doi.org/10.1016/S0010-938X(00)00076-7
  20. D. Sharma, H. Om and A.K. Sharma, Crit. Rev. Anal. Chem., (2022); https://doi.org/10.1080/10408347.2022.2080494
  21. M. Lebrini, F. Bentiss, H. Vezin and M. Lagrenée, Appl. Surf. Sci., 252, 950 (2005); https://doi.org/10.1016/j.apsusc.2005.01.160
  22. A.Y.I. Rubaye, H.T. Abdulsahib and A.A. Abdulwahid, J. Encapsul. Adsorpt. Sci., 5, 155 (2015); https://doi.org/10.4236/jeas.2015.53013
  23. V. Kalia, P. Kumar, S. Kumar, P. Pahuja, G. Jhaa, S. Lata and H. Dahiya, J. Mol. Liq., 313, 113601 (2020); https://doi.org/10.1016/j.molliq.2020.113601
  24. V. Kalia, P. Kumar, S. Kumar, M. Goyal, P. Pahuja, G. Jhaa, S. Lata, H. Dahiya, S. Kumar, A. Kumari and C. Verma, J. Mol. Liq., 348, 118021 (2022); https://doi.org/10.1016/j.molliq.2021.118021
  25. W. Yu, G. Huang, Y. Zhang, H. Liu, L. Dong, X. Yu, Y. Li and J. Chang, J. Org. Chem., 78, 10337 (2013); https://doi.org/10.1021/jo401751h
  26. D.K. Singh, S. Kumar, G. Udayabhanu and R.P. John, J. Mol. Liq., 216, 738 (2016); https://doi.org/10.1016/j.molliq.2016.02.012
  27. M.A. Bedair, A.M. Abuelela, M. Alshareef, M. Owda and E.M. Eliwa, RSC Adv., 13, 186 (2022); https://doi.org/10.1039/D2RA05939H
  28. I.B. Obot, E.E. Ebenso and Z.M. Gasem, Int. J. Electrochem. Sci., 7, 1997 (2012).
  29. M.A. Bedair, H.M. Elaryian, E.S. Gad, M. Alshareef, A.H. Bedair, R.M. Aboushahba and A.E.-A.S. Fouda, RSC Adv., 13, 478 (2022); https://doi.org/10.1039/D2RA06574F
  30. H. Rahmani, K.I. Alaoui, K.M. Emran, A. El Hallaoui, M. Taleb, S. El Hajji, B. Labriti, E. Ech-chihbi, B. Hammouti and F. El-Hajjaji, (2019); https://doi.org/10.20944/preprints201803.0116.v1
  31. F. Benhiba, H. Serrar, R. Hsissou, A. Guenbour, A. Bellaouchou, M. Tabyaoui, S. Boukhris, H. Oudda, I. Warad and A. Zarrouk, Chem. Phys. Lett., 743, 137181 (2020); https://doi.org/10.1016/j.cplett.2020.137181
  32. M. El Faydy, F. Benhiba, B. Lakhrissi, M.E. Touhami, I. Warad, F. Bentiss and A. Zarrouk, J. Mol. Liq., 295, 111629 (2019); https://doi.org/10.1016/j.molliq.2019.111629
  33. T. Laabaissi, F. Benhiba, Z. Rouifi, M. Missioui, K. Ourrak, H. Oudda, Y. Ramli, I. Warad, M. Allali and A. Zarrouk, Int. J. Corros. Scale Inhib., 8, 241 (2019); https://doi.org/10.17675/2305-6894-2019-8-2-6
  34. H.C. Andersen, J. Chem. Phys., 72, 2384 (1980); https://doi.org/10.1063/1.439486
  35. F. Bentiss, M. Outirite, M. Traisnel, H. Vezin, M. Lagrenée, B. Hammouti, S.S. Al-Deyab and C. Jama, Int. J. Electrochem. Sci., 7, 1699 (2012).
  36. F. El-Taib Heakal, N.S. Tantawy and O.S. Shehata, Int. J. Hydrogen, 24, 19219 (2012); https://doi.org/10.1016/j.ijhydene.2012.10.037
  37. J. Haque, V. Srivastava, C. Verma and M.A. Quraishi, J. Mol. Liq., 225, 848 (2017); https://doi.org/10.1016/j.molliq.2016.11.011
  38. A. Salhi, S. Tighadouini, M. El-Massaoudi, M. Elbelghiti, S. Radi, A. Bouyanzer, S. El Barkany, F. Bentiss and A. Zarrouk, J. Mol. Liq., 248, 340 (2017); https://doi.org/10.1016/j.molliq.2017.10.040
  39. H. Ouici, M. Tourabi, O. Benali, C. Selles, C. Jama, A. Zarrouk and F. Bentiss, J. Electroanal. Chem., 803, 125 (2017); https://doi.org/10.1016/j.jelechem.2017.09.018
  40. A. Khadiri, A. Ousslim, K. Bekkouche, A. Aouniti, I. Warad, A. Elidrissi, B. Hammouti, F. Bentiss, M. Bouachrine and A. Zarrouk, J. Bio Tribocorros., 4, 64 (2018); https://doi.org/10.1007/s40735-018-0179-3
  41. C. Jeyaprabha, S. Sathiyanarayanan, K.L.N. Phani and G. Venkatachari, Appl. Surf. Sci., 252, 966 (2005); https://doi.org/10.1016/j.apsusc.2005.01.098
  42. C. Pan, Y. Song, W. Jin, Z. Qin, S. Song, W. Hu and D.H. Xia, Trans. Tianjin Univ., 26, 135 (2020); https://doi.org/10.1007/s12209-020-00238-8
  43. F. Zhang, Y. Tang, Z. Cao, W. Jing, Z. Wu and Y. Chen, Corros. Sci., 61, 1 (2012); https://doi.org/10.1016/j.corsci.2012.03.045
  44. D. Daoud, T. Douadi, S. Issaadi and S. Chafaa, Corros. Sci., 79, 50 (2014); https://doi.org/10.1016/j.corsci.2013.10.025
  45. Y. El, J. Mater. Environ. Sci., 7, 371 (2016).
  46. E. McCafferty and N. Hackerman, J. Electrochem. Soc., 119, 146 (1972); https://doi.org/10.1149/1.2404150
  47. F. Growcock and R.J. Jasinski, J. Electrochem. Soc., 136, 2310 (1989); https://doi.org/10.1149/1.2097847
  48. D. Benhmamou, M.R. Aouad, R. Salghi, A. Zarrouk, M. Assouag, O. Benali, M. Messali, H. Zarrok and B. Hammouti, J. Chem. Pharm. Res., 4, 3489 (2012).
  49. H. Om, G.A. Baker, F.V. Bright, K.K. Verma and S. Pandey, Chem. Phys. Lett., 450, 156 (2007); https://doi.org/10.1016/j.cplett.2007.10.101
  50. A. Nahle, F. El-Hajjaji, A. Ghazoui, N.E. Benchat, M. Taleb, R. Saddik, A. Elaatiaoui, M. Koudad and B. Hammouti, Anti-Corros. Methods Mater., 65, 87 (2018); https://doi.org/10.1108/ACMM-03-2017-1769
  51. H. Rahmani, K.I. Alaoui, M.E. Azzouzi, F. Benhiba, A.E. Hallaoui, Z. Rais, M. Taleb, A. Saady, B. Labriti, A. Aouniti and A. Zarrouk, Chem. Data Coll., 24, 100302 (2019); https://doi.org/10.1016/j.cdc.2019.100302
  52. E. Garcia-Ochoa, S.J. Guzmán-Jiménez, J.G. Hernández, T. Pandiyan, J.M. Vásquez-Pérez and J. Cruz-Borbolla, J. Mol. Struct., 1119, 314 (2016); https://doi.org/10.1016/j.molstruc.2016.04.057
  53. A. Khadraoui, A. Khelifa, M. Hadjmeliani, R. Mehdaoui, K. Hachama, A. Tidu, Z. Azari, I.B. Obot and A. Zarrouk, J. Mol. Liq., 216, 724 (2016); https://doi.org/10.1016/j.molliq.2016.02.005
  54. M.H. Sliem, M. Afifi, A. Bahgat Radwan, E.M. Fayyad, M.F. Shibl, F.E.T. Heakal and A.M. Abdullah, Sci. Rep., 9, 2319 (2019); https://doi.org/10.1038/s41598-018-37254-7
  55. E.A. Noor, Int. J. Electrochem. Sci., 2, 996 (2007).
  56. M.K. Sharma, S. Parashar, M. Chahal, K. Lal, N.U. Pandya and H. Om, J. Mol. Struct., 1257, 132632 (2022); https://doi.org/10.1016/j.molstruc.2022.132632
  57. S. Abrishami, R. Naderi and B. Ramezanzadeh, Appl. Surf. Sci., 457, 487 (2018); https://doi.org/10.1016/j.apsusc.2018.06.190
  58. H. Zhao, X. Zhang, L. Ji, H. Hu and Q. Li, Corros. Sci., 83, 261 (2014); https://doi.org/10.1016/j.corsci.2014.02.023
  59. A. Thakur, A. Kumar, S. Kaya, R. Marzouki, F. Zhang and L. Guo, Coatings, 12, 1459 (2022); https://doi.org/10.3390/coatings12101459
  60. A. Kumar and A. Thakur, eds.: S. Rajendran, T.A. Nguyen, S. Kakooei, M. Yeganeh, Y. Li, Encapsulated Nanoparticles in Organic Polymers for Corrosion Inhibition, in: Corrosion Protection at the Nanoscale, Chap. 18, pp. 345–362 (2020); https://doi.org/10.1016/B978-0-12-819359-4.00018-0
  61. A. Thakur, S. Kaya, A.S. Abousalem and A. Kumar, Exp. Sustain. Chem. Pharm., 29, 100785 (2022); https://doi.org/10.1016/j.scp.2022.100785
  62. A. Thakur, A. Kumar, S. Sharma, R. Ganjoo and H. Assad, Mater. Today Proc., 66, 609 (2022); https://doi.org/10.1016/j.matpr.2022.06.479
  63. A. Thakur and A. Kumar, J. Bio. Tribocorros., 7, 1 (2021); https://doi.org/10.1007/s40735-021-00501-y
  64. A. Thakur, S. Kaya and A. Kumar, Curr. Nanosci., 18, 203 (2022); https://doi.org/10.2174/1573413717666210216120741
  65. F. Bentiss, B. Mernari, M. Traisnel, H. Vezin and M. Lagrenée, Corros. Sci., 53, 487 (2011); https://doi.org/10.1016/j.corsci.2010.09.063
  66. I.B. Obot and Z.M. Gasem, Corros. Sci., 83, 359 (2014); https://doi.org/10.1016/j.corsci.2014.03.008
  67. D.H. Xia, C. Pan, Z. Qin, B. Fan, S. Song, W. Jin and W. Hu, Prog. Org. Coat., 143, 105638 (2020); https://doi.org/10.1016/j.porgcoat.2020.105638
  68. F. Bentiss, F. Gassama, D. Barbry, L. Gengembre, H. Vezin, M. Lagrenée and M. Traisnel, Appl. Surf. Sci., 252, 2684 (2006); https://doi.org/10.1016/j.apsusc.2005.03.231
  69. I.B. Obot and N.O. Obi-Egbedi, Corros. Sci., 52, 657 (2010); https://doi.org/10.1016/j.corsci.2009.10.017
  70. N. Kumari, M. Singh, H. Om and K.M. Sachin, RSC Adv., 9, 12507 (2019); https://doi.org/10.1039/C9RA00728H
  71. G. Gao and C. Liang, Electrochim. Acta, 52, 4554 (2007); https://doi.org/10.1016/j.electacta.2006.12.058
  72. A. Kokalj, Electrochim. Acta, 56, 745 (2010); https://doi.org/10.1016/j.electacta.2010.09.065
  73. R. Yildiz, T. Dogan and I. Dehri, Corros. Sci., 85, 215 (2014); https://doi.org/10.1016/j.corsci.2014.04.017
Read More
Author biographies is not available.
Download
AJC-35-5-5
Statistic
Read Counter : 0 Download : 0