Synthesis, Spectral Investigation, Reinforced Bio-potential Enhancement and Structure Property Correlation of Mixed Ligand Pyridine-4-carbaldehyde Metal Complexes
C. Surendra Dilip1
1Department of Chemistry, University College of Engineering, BIT Campus, Tiruchirappalli- 620 024, India
2Department of Physics, University College of Engineering, BIT Campus, Tiruchirappalli-620 024, India
*Corresponding author: E-mail: cs_dilip@yahoo.co.in
G. Senguttuvan2
1Department of Chemistry, University College of Engineering, BIT Campus, Tiruchirappalli- 620 024, India
2Department of Physics, University College of Engineering, BIT Campus, Tiruchirappalli-620 024, India
*Corresponding author: E-mail: cs_dilip@yahoo.co.in
V. Sivakumar2
1Department of Chemistry, University College of Engineering, BIT Campus, Tiruchirappalli- 620 024, India
2Department of Physics, University College of Engineering, BIT Campus, Tiruchirappalli-620 024, India
*Corresponding author: E-mail: cs_dilip@yahoo.co.in
K. Manik
1Department of Chemistry, University College of Engineering, BIT Campus, Tiruchirappalli- 620 024, India
2Department of Physics, University College of Engineering, BIT Campus, Tiruchirappalli-620 024, India
*Corresponding author: E-mail: cs_dilip@yahoo.co.in
R. Thiruneelak
1Department of Chemistry, University College of Engineering, BIT Campus, Tiruchirappalli- 620 024, India
2Department of Physics, University College of Engineering, BIT Campus, Tiruchirappalli-620 024, India
*Corresponding author: E-mail: cs_dilip@yahoo.co.in
Corresponding Author(s) : C. Surendra Dilip1
Asian Journal of Chemistry,
Vol 25 No Supplementary Issue
Mixed ligand M(II/III) complexes of pyridine-4-carbaldehyde as primary ligand and chloride as secondary ligand have been microwave synthesized and characterized by various physical, analytical and spectral studies viz., FTIR, UV-visible, TG-DTA-DTG and XRD. The molar conductance, magnetic moment values and the electronic spectral data gives a general formula as [M(PA)4Cl2] where M = Mn(II), Co(II), Ni(II), Cu(II) and Cd(II) and [M(PA)3Cl3] where M = Cr(III) and Fe(III) with a distorted octahedral structure. Thermal analyses show that the complexes initially lose molecules of hydration and subsequently expel anionic and organic ligands in continuous steps.
Surendra Dilip1, C., Senguttuvan2, G., Sivakumar2, V., Manik, K., & Thiruneelak, R. (2013). Synthesis, Spectral Investigation, Reinforced Bio-potential Enhancement and Structure Property Correlation of Mixed Ligand Pyridine-4-carbaldehyde Metal Complexes. Asian Journal of Chemistry, 25(20), 73–75. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25_Supplementary%20Issue_19
