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Leaching of Copper Secondary Wastes: Possible Soil Contaminants
Corresponding Author(s) : Zaib Hussain
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
The United Nations Basel convention on the transboundary shipment of hazardous wastes was adopted to control the influx of hazardous materials being shipped from OECD countries to non-OECD countries. The ban allowed for developing countries to control the level of pollution and contamination prevailing in soils, water and the atmosphere. This study aims to look at the hazards posed by the secondary wastes industries, focusing in particular on copper slags, drosses and residues. To establish the levels of heavy metals becoming available in the environment, these wastes were extracted in different leach liquors. The results indicated that copper residue is more drastic toward soil and water contaminations. High amount of Cu from three different samples were leached, 39431.9, 7402.6 and 119301.6 μg/L, under physiological soil pH condition. Other heavy metals Pb and Zn were also calculated in concentration 10.1, 139.57 and 29.48 μg/L respectively. A significant improvement in morphology was also recorded from the scanning electron microscopic analysis.
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- L. Jarup, Br. Med. Bull., 68, 167 (2003).
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References
L. Jarup, Br. Med. Bull., 68, 167 (2003).
V. Martina, E. Vojtech, H. Jiri,A. Thomas and K. Bohdan, Appl. Geochem., 26, S263 (2011).
V. Ettler, O. Sebek, T. Grygar, M. Klementova, P. Bezdicka and H. Slavikova, Environ. Sci. Technol., 42, 7878 (2008).
G.S. Ohmsen, J. Waste Manage. Assoc., 51, 1443 (2001).
T. Astrup, J.J. Dijkstra, R.N.J. Comans, H.A. van der Sloot and T.H. Christensen, Environ. Sci. Technol., 40, 3551 (2006).
V.Z. Lukas, R. Josh, K. Tim, M. Graham and M. Steven, Sci. Total Environ., 329, 29 (2004).
D.J. Spurgeon and S.P. Hopkin, Appl. Soil Ecol., 11, 227 (1999).
A. Cox and T. Sheales, Aust. Commod., 3, 3 (1996).
H. Alter, Resour. Conserv. Recycl., 43, 353 (2005).
D. Singh, K. Nath and K.Y. Sharma, J. Environ. Biol., 28, 409 (2007).
X. Shi, S.N. Dalal and S.K. Kasprzak, Biochem. Biophys. Acta, 302, 294 (1993).
J. Ross and D. de Vries, Mufulira Smelter Upgrade Project - ''Industry'' Smelting on the Zambian Copperbelt. Mopani Copper Mines PLC Int. Rep., Kitwe, Zambia (2005).
B. Kríbek, V. Majer, F. Veselovsky´ and I. Nyambe, J. Geochem. Explor., 104, 69 (2010).
O. Sracek, F. Veselovsky, B. Kríbek, J. Malec and J. Jehlicka, Appl. Geochem., 25, 1815 (2010).
F. Anjum, M. Shahid and A. Akcil, Hydrometallurgy, 117-118, 1 (2012).
F. Anjum, H.N. Bhatti, M. Asgher and M. Shahid, Appl. Clay Sci., 47, 356 (2010)