Issue

Vol. 25 No. 6 (2013): Vol 25 Issue 6

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Densities and Refractive Indices for N-Arylhydroxamic Acids in Dimethylsulphoxide at Various Temperatures

https://doi.org/10.14233/ajchem.2013.13516
V. Verma
Agriculture Processing and Food Engineering, Faculty of Agricultural Engineering, Indira Gandhi Krishi Vishwavidyalaya, Raipur-492 006, India
R. Pande
School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur-492 010, India

Corresponding Author(s) : V. Verma

veenuverma88@gmail.com

Asian Journal of Chemistry, Vol. 25 No. 6 (2013): Vol 25 Issue 6

Abstract

Refractive index deviations (nE), excess volumes (VE) and molar refraction (RM) of two isomeric hydroxamic acids, N-phenyl-2-methylbenzohydroxamic acid, N-phenyl-2-nitrobenzohydroxamic acid and N-phenyl-3-nitrobenzohydroxamic acid have been calculated from experimental data of refractive indices (n) and densities (r) in dimethyl sulphoxide at various temperatures (298.15, 303.15, 308.15 and 313.15) K. Results obtained have been discussed in terms of intermolecular ineteractions and a comprehensive discussion has been provided. The apparent molar volume at infinite dilution and the slope of Masson's equation are computed, to interpret the solute-solvent interaction.

Keywords

Density Molar refraction Hydroxamic acid
Verma, V., & Pande, R. (2013). Densities and Refractive Indices for N-Arylhydroxamic Acids in Dimethylsulphoxide at Various Temperatures. Asian Journal of Chemistry, 25(6), 3055–3059. https://doi.org/10.14233/ajchem.2013.13516
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. S.C.P Hwa and W.T. Ziegler, J. Phys. Chem., 70, 2572 (1966).
  2. H.K. Kehl, Chemistry and Biology of Hydroxamic Acids, Karger, Basel, (1982).
  3. R.D. Wagh, H.S. Mahajan and S.G. Kaskhedikar, Asian J. Chem., 19, 4188 (2007).
  4. S. Hanessian and S. Johnstone, J. Org. Chem., 64, 5896 (1999).
  5. M. Whittaker, C.D. Floyd, P. Brown and A.J.H. Gearing, Chem. Rev., 99, 2735 (1999).
  6. T. Kolasa, A.O. Stewart and C.D.W. Brooks, Tetrahedron:Asym., 7, 729 (1996).
  7. F.A.J. Kerdesky, S.P. Schmidt, J.H. Holms, R.D. Dyer, G.W. Carter and D.W. Brooks, J. Med. Chem., 30, 1177 (1987)
  8. R.K. Dewan, S.P. Gupta and S.K. Mehta, J. Soln. Chem., 18, 13 (1989).
  9. A. Galmes, J. Besalduch, J. Bergay, A. Novo, M. Morey, J.M. Gureria and M.A. Duran, Transfusion, 39, 70 (1999).
  10. T.T. Anchrodoguy. C.A. Cecchini and J.H. Crowe, Cryobiology, 28, 467 (1991).
  11. T.J. Reid, G. Esteban, M. Clear and M. Gorogias, Transfusion, 39, 616 (1999).
  12. R. Pande and S.G. Tandon, J. Chem. Eng. Data, 24, 72 (1979).
  13. J.A. Riddick, W.B. Bunger and T. Sakano, Organic Solvent, Techniques of Chemistry, Wiley Interscience, New York, Vol I, edn. 4 (1986).
  14. P.G. Sears, W.D. Sieqfried and D.E. Sunds, J. Chem. Eng. Data, 9, 261 (1964).
  15. Bhanupriya, R.P. Rajwade and R. Pande, J. Eng. Chem. Data, 53, 1458 (2008).
  16. M.A. Saleh, S. Akhtar, M.S. Ahmed and M.H. Uddin, Phys. Chem. Liq., 40, 621 (2002).
  17. J.F. Casteel and P.G. Sears, J. Chem. Eng. Data, 19, 196 (1974).
  18. S.A. Markarian and A.M. Erzyan, J. Chem. Eng. Data, 52, 1704 (2007).
  19. I. Koltz and R.M. Rosenberg, Chemical Thermodynamics, Basic Theory and Methods, W.A. Benzanin: CA, edn 3 (1972).
  20. D.O. Masson, Philos. Mag., 8, 218 (1929).
  21. P. Brocos, A. Pineiro, R. Bravo and A. Amigo, Phys. Chem. Chem. Phys., 5, 550 (2003).
  22. A. Ali, S. Sabir, A.K. Nain, S. Hyder, S. Ahmad and R. Patel, J. Indian Chem. Soc., 83, 581 (2006).
  23. H. Lorentz, Ann. Phys., 9, 64; L.V. Lorenz, Ann. Phys., 11, 70 (1980).
  24. Y.Y. Fialkov, Russ. J. Phys. Chem., 41, 398 (1967).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 1 Download : 1