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Anticorrosive Activity of Schreabera swietenioids Leaves as Green Inhibitor for Mild Steel in Acidic Solution
Corresponding Author(s) : A.P. Srikanth
Asian Journal of Chemistry,
Vol. 29 No. 2 (2017): Vol 29 Issue 2
Abstract
The corrosion inhibitive effect of Schreabera swietenioids plant leaves extracts on mild steel in 1 N HCl was studied by using mass loss method, polarization measurements and electrochemical impedance spectroscopy at room temperature. Polarization studies showed that the Schreabera swietenioids plant extracts behaved as mixed type inhibitor. Nyquist plot revealed that the addition of extracts increases the charge transfer resistance and hence increases the inhibition efficiency. Photochemical constituents and organic moieties that were adsorbed on the metal surface were also found responsible for the effective performance of the inhibitor, which was well supported by FTIR studies. Protective film formation against corrosion was confirmed by SEM analysis.
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- Gerengi, H. Sahin and H. Ibrahim, J. Ind. Eng. Chem., 836 (2012).
- D. Kesavan, M. Gopiraman and N. Sulochana, Chem. Sci. Rev. Lett., 1, 1 (2012).
- S. Deng and X. Li, Corros. Sci., 55, 407 (2012).
- F.S. De Souza and A. Spinelli, Corros. Sci., 51, 642 (2009).
- S. Ambrish, A. Ishtiaque, A.Q. Mumtaz, Arab. J. Chem., (2012).
- M.S. Al-Otaibi, A.M. Al-Mayouf, M. Khan, A.A. Mousa, S.A. Al-Mazroa and H.Z. Alkhathlan, Arab. J. Chem., 7, 340 (2012).
- S.A. Umoren and U.M. Eduok, Carbohydr. Polym., 140, 314 (2016).
- V.S. Sastri, Green Corrosion Inhibitor: Theory and Practice, John Wiley & Sons, Inc.: Canada, edn 1, pp. 328 (2011).
- L.R. Chauhan and G. Gunasekaran, Corros. Sci., 49, 1143 (2007).
- M.H. Hussin and M.J. Kassim, Mater. Chem. Phys., 125, 461 (2011).
- M. Gopiraman, P. Sakunthala, D. Kesavan, V. Alexramani, I.S. Kim and N. Sulochana, J. Coat. Technol. Res., 9, 15 (2012).
- A.Y. El-Etre, Mater. Chem. Phys., 108, 278 (2008).
- P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpe and S.A. Umoren, Corros. Sci., 50, 2310 (2008).
- H. Cang, Z. Fei, H. Xiao, J. Huang and Q. Xu, Int. J. Electrochem. Sci., 7, 8869 (2012).
- P. Sakunthala, S.S. Vivekananthan, M. Gopiraman, N. Sulochana and A.R. Vincent, J. Surfactants Deterg., 16, 251 (2013).
- M. Ferry, C.W. Mohd Noor, F. Gaspersz and M. Manuputty, J. Eng. Comp. Appl. Sci., 2, 3 (2013).
- E.E. Ebenso and S.A. Hailemichael, Int. J. Electrochem. Sci., 3, 1325 (2008).
- R.A. Prabhu, T.V. Venkatesha, A.V. Shanbhag, B.M. Praveen, G.M. Kulkarni and R.G. Kalkhambkar, Mater. Chem. Phys., 108, 283 (2008).
- R.A. Sanghvi, Bull. Electrochem., 13, 358 (1999).
- Y. Li, P. Zhao, Q. Liang and B. Hou, Appl. Surf. Sci., 252, 1245 (2005).
- J.B. Harborne, Phytochemical Methods. A Guide to Modern Techniques of Plant Analysis, Chapman and Hall, London (1998).
- E.E. Ebenso, N.O. Eddy and O.A. Odiongenyi, Afr. J. Pure Appl. Chem., 2, 107 (2008).
References
Gerengi, H. Sahin and H. Ibrahim, J. Ind. Eng. Chem., 836 (2012).
D. Kesavan, M. Gopiraman and N. Sulochana, Chem. Sci. Rev. Lett., 1, 1 (2012).
S. Deng and X. Li, Corros. Sci., 55, 407 (2012).
F.S. De Souza and A. Spinelli, Corros. Sci., 51, 642 (2009).
S. Ambrish, A. Ishtiaque, A.Q. Mumtaz, Arab. J. Chem., (2012).
M.S. Al-Otaibi, A.M. Al-Mayouf, M. Khan, A.A. Mousa, S.A. Al-Mazroa and H.Z. Alkhathlan, Arab. J. Chem., 7, 340 (2012).
S.A. Umoren and U.M. Eduok, Carbohydr. Polym., 140, 314 (2016).
V.S. Sastri, Green Corrosion Inhibitor: Theory and Practice, John Wiley & Sons, Inc.: Canada, edn 1, pp. 328 (2011).
L.R. Chauhan and G. Gunasekaran, Corros. Sci., 49, 1143 (2007).
M.H. Hussin and M.J. Kassim, Mater. Chem. Phys., 125, 461 (2011).
M. Gopiraman, P. Sakunthala, D. Kesavan, V. Alexramani, I.S. Kim and N. Sulochana, J. Coat. Technol. Res., 9, 15 (2012).
A.Y. El-Etre, Mater. Chem. Phys., 108, 278 (2008).
P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpe and S.A. Umoren, Corros. Sci., 50, 2310 (2008).
H. Cang, Z. Fei, H. Xiao, J. Huang and Q. Xu, Int. J. Electrochem. Sci., 7, 8869 (2012).
P. Sakunthala, S.S. Vivekananthan, M. Gopiraman, N. Sulochana and A.R. Vincent, J. Surfactants Deterg., 16, 251 (2013).
M. Ferry, C.W. Mohd Noor, F. Gaspersz and M. Manuputty, J. Eng. Comp. Appl. Sci., 2, 3 (2013).
E.E. Ebenso and S.A. Hailemichael, Int. J. Electrochem. Sci., 3, 1325 (2008).
R.A. Prabhu, T.V. Venkatesha, A.V. Shanbhag, B.M. Praveen, G.M. Kulkarni and R.G. Kalkhambkar, Mater. Chem. Phys., 108, 283 (2008).
R.A. Sanghvi, Bull. Electrochem., 13, 358 (1999).
Y. Li, P. Zhao, Q. Liang and B. Hou, Appl. Surf. Sci., 252, 1245 (2005).
J.B. Harborne, Phytochemical Methods. A Guide to Modern Techniques of Plant Analysis, Chapman and Hall, London (1998).
E.E. Ebenso, N.O. Eddy and O.A. Odiongenyi, Afr. J. Pure Appl. Chem., 2, 107 (2008).