Issue

Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020

Copyright (c) 2020 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Controlled Synthesis, Characterization and Magnetic Properties of Unsymmetrical Heterodinuclear CuIIMII (M = Co, Mn and Cd) Complexes in Alkoxo Bridged Acyclic Ligand Environment

https://doi.org/10.14233/ajchem.2020.22787
Dipesh Ghosh
Department of Chemistry, Vivekananda Mission Mahavidyalaya, Chaitanyapur, Haldia-721645, India

Corresponding Author(s) : Dipesh Ghosh

dipesh105@hotmail.com

Asian Journal of Chemistry, Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020

Abstract

This work reports the syntheses of heterodinuclear Cu(II)-Co(II), Cu(II)-Mn(II) and Cu(II)-Cd(II) complexes following a convenient single-pot synthetic procedure using the two asymmetric binucleating ligands. Site-specificity offered by one of the ligands' arms towards Cu(I) center has been successfully exploited here, avoiding all sorts of impending scrambling reactions. X-ray crystallography and ESI-mass spectral studies have been used to prove the exclusivity of these products. Magnetic studies at variable temperatures (4-300 K) have been proved inadequate to assign any spin-ground state for Cu(II)-Co(II) and Cu(II)-Mn(II) compounds.

Keywords

Heterodinuclear complexes Crystal structure ESR spectra Magnetic studies
Ghosh, D. (2020). Controlled Synthesis, Characterization and Magnetic Properties of Unsymmetrical Heterodinuclear CuIIMII (M = Co, Mn and Cd) Complexes in Alkoxo Bridged Acyclic Ligand Environment. Asian Journal of Chemistry, 32(9), 2284–2292. https://doi.org/10.14233/ajchem.2020.22787
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. O. Kahn, ed.: A.G. Sykes, In Advances in Inorganic Chemistry, vol. 43, Academic Press; San Diego, p. 179 (1995).
  2. K.S. Murray, In Advances in Inorganic Chemistry, Vol. 43, A.G. Sykes, Ed.; Academic Press; San Diego, p. 261 (1995).
  3. D.M. Rudkevich, J.D. Mercer-Chalmers, W. Verboom, R. Ungaro, F.de Jong and D.N. Reinhoudt, J. Am. Chem. Soc., 117, 6124 (1995); https://doi.org/10.1021/ja00127a027
  4. D.M. Rudkevich, W. Verboom, Z. Brzozka, W.P.R.V. Stauthamer, M.J. Palys, G.J. van Hummel, S.M. Franken, S. Harkema, J.F.J. Engbersen and D.N. Reinhoudt, J. Am. Chem. Soc., 116, 4341 (1994); https://doi.org/10.1021/ja00089a023
  5. P.A. Vigato, S. Tamburini and D.E. Fenton, Coord. Chem. Rev., 106, 25 (1990); https://doi.org/10.1016/0010-8545(60)80002-1
  6. J.A. Tainer, E.D. Getzoff, K.M. Beem, J.S. Richardson and D.C. Richardson, J. Mol. Biol., 160, 181 (1982); https://doi.org/10.1016/0022-2836(82)90174-7
  7. J.A. Tainer, E.D. Getzoff, J.S. Richardson and D.C. Richardson, Nature, 306, 284 (1983); https://doi.org/10.1038/306284a0
  8. N. Sträter, T. Klabunde, P. Tucker, H. Witzel and B. Krebs, Science, 268, 1489 (1995); https://doi.org/10.1126/science.7770774
  9. C.R. Kissinger, H.E. Parge, D.R. Knighton, C.T. Lewis, L.A. Pelletier, A. Tempczyk, V.J. Kalish, K.D. Tucker, R.E. Showalter, E.W. Moomaw, L.N. Gastinel, N. Habuka, X. Chen, F. Maldonado, J.E. Barker, R.Bacquet and J.E. Villafranca, Nature, 378, 641 (1995); https://doi.org/10.1038/378641a0
  10. I. Bertini, L. Banci and C. Luchinat, ed.: L. Que, Jr., Metal Clusters in Proteins; ACS Symposium Series 372; American Chemical Society: Washington, DC, pp. 71-84 (1988).
  11. L. Que Jr. and A.E. True, Prog. Inorg. Chem., 38, 97 (1990); https://doi.org/10.1002/9780470166390.ch3
  12. J.B. Vincent, G.L. Olivier-Lilley and B.A. Averill, Chem. Rev., 90, 1447 (1990); https://doi.org/10.1021/cr00106a004
  13. A.L. Feig and S.J. Lippard, Chem. Rev., 94, 759 (1994); https://doi.org/10.1021/cr00027a011
  14. K.A. Magnus, H. Ton-That and J.E. Carpenter, Chem. Rev., 94, 727 (1994); https://doi.org/10.1021/cr00027a009
  15. E.I. Solomon, M.J. Baldwin and M.D. Lowery, Chem. Rev., 92, 521 (1992); https://doi.org/10.1021/cr00012a003
  16. W.H. Lang and K.E. van Holde, Proc. Natl. Acad. Sci. USA, 88, 244 (1991); https://doi.org/10.1073/pnas.88.1.244
  17. D.E. Fenton and H. Ôkawa, Chem. Ber., 130, 433 (1997); https://doi.org/10.1002/cber.19971300402
  18. H. Ôkawa, H. Furutachi and D.E. Fenton, Coord. Chem. Rev., 174, 51 (1998); https://doi.org/10.1016/S0010-8545(97)00082-9
  19. D.E. Fenton, In Advances in Inorganic and Bioinorganic Mechanism, Vol. 43, A.G. Sykes, Ed.; Academic Press; London, p. 187 (1983).
  20. H. Furutachi and H. Ôkawa, Inorg. Chem., 36, 3911 (1997); https://doi.org/10.1021/ic9700563
  21. J.D. Crane, D.E. Fenton, J.M. Latour and A.J. Smith, J. Chem. Soc., Dalton Trans., 2979 (1991); https://doi.org/10.1039/dt9910002979
  22. C. Fraser, L. Johnston, A.L. Rheingold, B.S. Haggerty, G.K. Williams, J. Whelan and B. Bosnich, Inorg. Chem., 31, 1835 (1992); https://doi.org/10.1021/ic00036a022
  23. D.G. McCollum, G.P.A. Yap, A.L. Rheingold and B. Bosnich, J. Am. Chem. Soc., 118, 1365 (1996); https://doi.org/10.1021/ja952873c
  24. P. Kamaras, M.C. Cajulis, M. Rapta, G.A. Brewer and G.B. Jameson, J. Am. Chem. Soc., 116, 10334 (1994); https://doi.org/10.1021/ja00101a077
  25. Y. Hayashi, T. Kayatani, H. Sugimoto, M. Suzuki, K. Inomata, A. Uehara, Y. Mizutani, T. Kitagawa and Y. Maeda, J. Am. Chem. Soc., 117, 11220 (1995); https://doi.org/10.1021/ja00150a020
  26. J.H. Satcher Jr., M.W. Droege, T.J.R. Weakley and R.T. Taylor, Inorg. Chem., 34, 3317 (1995); https://doi.org/10.1021/ic00116a026
  27. B. Eulering, M. Schmidt, U. Pinkernell, U. Karst and B. Krebs, Angew. Chem. Int. Ed. Engl., 35, 1973 (1996); https://doi.org/10.1002/anie.199619731
  28. D. Volkmer, A. Hörstmann, K. Griesar, W. Haase and B. Krebs, Inorg. Chem., 35, 1132 (1996); https://doi.org/10.1021/ic950368a
  29. D. Volkmer, B. Hommerich, K. Griesar, W. Haase and B. Krebs, Inorg. Chem., 35, 3792 (1996); https://doi.org/10.1021/ic951567x
  30. M. Konrad, F. Meyer, K. Heinze and L. Zsolnai, J. Chem. Soc., Dalton Trans., 199 (1998); https://doi.org/10.1039/a705543i
  31. M. Konrad, S. Wuthe, F. Meyer and E. Kaifer, Eur. J. Inorg. Chem., 2233 (2001); https://doi.org/10.1002/1099-0682(200109)2001:9<2233::AIDEJIC2233>3.0.CO;2-4
  32. Q.Y. Chen, Q.-H. Luo, Z.-L. Wang and J.-T. Chen, Chem. Commun., 1033 (2000); https://doi.org/10.1039/a909926n
  33. H. He, A.E. Martell, R.J. Motekaitis and J.H. Reibenspies, Inorg. Chem., 39, 1586 (2000); https://doi.org/10.1021/ic9911264
  34. N.C. Gianneschi, C.A. Mirkin, L.N. Zakharov and A.L. Rheingold, Inorg. Chem., 41, 5326 (2002); https://doi.org/10.1021/ic025875o
  35. M. Botta, U. Casellato, C. Scalco, S. Tamburini, P. Tomasin, P.A. Vigato, S. Aime and A. Barge, Chem. Eur. J., 8, 3917 (2002); https://doi.org/10.1002/1521-3765(20020902)8:17<3917::AIDCHEM3917>3.0.CO;2-D
  36. S. Bhattacharyya, D. Ghosh, S. Mukhopadhyay, W.P. Jensen, E.R.T. Tiekink and M. Chaudhury, J. Chem. Soc., Dalton Trans., 4677 (2000); https://doi.org/10.1039/b005906o
  37. D.D. Perrin, W.L.F. Armarego and D.R. Perrin, Purification of Laboratory Chemicals, Pergamon: Oxford, England, edn. 2 (1980).
  38. W.R. Robinson, J. Chem. Educ., 62, 1001 (1985); https://doi.org/10.1021/ed062p1001
  39. N. Walker and D. Stuart, Acta Crystallogr. A, 39, 158 (1983); https://doi.org/10.1107/S0108767383000252
  40. SADABS, v 2.01, Bruker AXS Inc., Madison, WI, USA (2000).
  41. P.T. Beurskens, G. Admiraal, G. Beurskens, W.P. Bosman, S. GarcíaGranda, J.M.M. Smits and C. Smykalla, The DIRDIF Program System, Technical Report of the Crystallography Laboratory, University of Nijmegen, Netherlands (1992).
  42. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany (1997).
  43. C.K. Johnson, ‘ORTEP II’, Report ORNL-5138; Oak Ridge National Laboratory, TN, USA (1976).
  44. teXsan: Structure Analysis Software; Molecular Structure Corporation: The Woodlands, TX, USA (1997).
  45. K. Abe, K. Matsufuji, M. Ohba and H. Ôkawa, Inorg. Chem., 41, 4461 (2002); https://doi.org/10.1021/ic020002f
  46. H. Adams, D.E. Fenton, S.R. Haque, S.L. Heath, M. Ohba, H. Ôkawa and S.E. Spey, J. Chem. Soc., Dalton Trans., 1849 (2000); https://doi.org/10.1039/b001395l
  47. C. Juarez-Garcia, M.P. Hendrich, T.R. Holman, L. Que Jr. and E. Münck, J. Am. Chem. Soc., 113, 518 (1991); https://doi.org/10.1021/ja00002a020
  48. T.R. Holman, C. Juarez-Garcia, M.P. Hendrich, L. Que Jr. and E. Münck, J. Am. Chem. Soc., 112, 7611 (1990); https://doi.org/10.1021/ja00177a024
  49. A.S. Borovik, V. Papaefthymiou, L.F. Taylor, O.P. Anderson and L. Que Jr., J. Am. Chem. Soc., 111, 6183 (1989); https://doi.org/10.1021/ja00198a032
  50. M. Suzuki, S. Fujinami, T. Hibino, H. Hori, Y. Maeda, A. Uehara and M. Suzuki, Inorg. Chim. Acta, 283, 124 (1998); https://doi.org/10.1016/S0020-1693(98)00226-6
  51. G. Murphy, P. Nagle, B. Murphy and B. Hathaway, J. Chem. Soc., Dalton Trans., 2645 (1997); https://doi.org/10.1039/a702291c
  52. G. Murphy, C. O’Sullivan, B. Murphy and B. Hathaway, Inorg. Chem., 37, 240 (1998); https://doi.org/10.1021/ic970458a
  53. A.W. Addison, T.N. Rao, J. Reedijk, J. van Rijn and G.C. Verschoor, J. Chem. Soc., Dalton Trans., 1349 (1984); https://doi.org/10.1039/DT9840001349
  54. S. Bhattacharyya, S.B. Kumar, S.K. Dutta, E.R.T. Tiekink and M. Chaudhury, Inorg. Chem., 35, 1967 (1996); https://doi.org/10.1021/ic950594k
  55. S.B. Kumar, S. Bhattacharyya, S.K. Dutta, E.R.T. Tiekink and M. Chaudhury, J. Chem. Soc., Dalton Trans., 2619 (1995); https://doi.org/10.1039/dt9950002619
  56. D. Ghosh, N. Kundu, G. Maity, K.-Y. Choi, A. Caneschi, A. Endo and M. Chaudhury, Inorg. Chem., 43, 6015 (2004); https://doi.org/10.1021/ic049449+
  57. B.J. Hathaway and D.E. Billing, Coord. Chem. Rev., 5, 143 (1970); https://doi.org/10.1016/S0010-8545(00)80135-6
  58. A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier: New York, edn 2 (1984).
  59. M. Ciampolini, Struct. Bonding (Berlin), 6, 52 (1969); https://doi.org/10.1007/BFb0118854
  60. J.S. Wood, Inorg. Chem., 7, 852 (1968); https://doi.org/10.1021/ic50063a002
  61. J.L. Hughey IV, T.G. Fawcett, S.M. Rudich, R.A. Lalancette, J.A. Potenza and H.J. Schugar, J. Am. Chem. Soc., 101, 2617 (1979); https://doi.org/10.1021/ja00504a020
  62. M. Yonemura, Y. Matsumura, H. Furutachi, M. Ohba, H. Ôkawa and D.E. Fenton, Inorg. Chem., 36, 2711 (1997); https://doi.org/10.1021/ic9614430
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0