TY - JOUR AU - Gao, Wei AU - Yuan Jing Yang, Juan PY - 2013/11/12 Y2 - 2024/03/29 TI - Synthesis and Crystal Structure of Complex (μ-S2)Fe2(CO)4(PPh3)2 JF - Asian Journal of Chemistry JA - ajc VL - 25 IS - 17 SE - Articles DO - 10.14233/ajchem.2013.15310A UR - https://asianpubs.org/index.php/ajchem/article/view/25_18_72 SP - 9755-9757 AB - <p style="text-align: justify;">The title complex (μ-S<sub>2</sub>)Fe<sub>2</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>2</sub> was prepared by reaction of (μ-S<sub>2</sub>)Fe<sub>2</sub>(CO)<sub>6</sub> and PPh<sub>3</sub> at reflux in toluene. Its structure was determined by single crystal X-ray diffraction analysis. The crystals are monoclinic, space group C2/c with a = 19.203(7), b = 10.199(3), c = 19.403(7) Å, <span style="font-family: Symbol;">a</span>&nbsp;= 90.00,&nbsp;<span style="font-family: Symbol;">b</span> = 102.386(5),&nbsp;<span style="font-family: Symbol;">g</span> = 90.00º, V = 3712(2) Å<sup>3</sup>, Z = 4, F<sub>(000)</sub> = 1664, D<sub>c</sub> = 1.454 g/cm<sup>3</sup>, μ = 1.021 cm<sup>-1</sup>, the final R = 0.0395 and wR = 0.0944. A total of 18901 reflections were collected, of which 4437 were independent (R<sub>int</sub> = 0.0545).</p> ER -